Assignment of electronic transitions in mixed-valence complexes by resonance Raman spectroscopy

1992 ◽  
Vol 31 (15) ◽  
pp. 3185-3186 ◽  
Author(s):  
Jon R. Schoonover ◽  
Cliff J. Timpson ◽  
Thomas J. Meyer ◽  
Carlo A. Bignozzi
Keyword(s):  
Raman Spectroscopy ◽  
Resonance Raman Spectroscopy ◽  
Mixed Valence ◽  
Resonance Raman ◽  
Electronic Transitions ◽  
Assignment Of Electronic Transitions

Intervalence Involvement of Bridging Ligand Vibrations in Hexaruthenium Mixed-Valence Clusters Probed by Resonance Raman Spectroscopy

2003 ◽  
Vol 125 (46) ◽  
pp. 13912-13913 ◽  
Author(s):  
Casey H. Londergan ◽  
Reginaldo C. Rocha ◽  
Mac G. Brown ◽  
Andrew P. Shreve ◽  
Clifford P. Kubiak
Keyword(s):  
Raman Spectroscopy ◽  
Resonance Raman Spectroscopy ◽  
Mixed Valence ◽  
Resonance Raman ◽  
Bridging Ligand

Insights into the charge-transfer character of electronic transitions in RCp2Ti(C2Fc)2 complexes using solvatochromism, resonance Raman spectroscopy, and TDDFT

2021 ◽  
Vol 50 (6) ◽  
pp. 2233-2242
Author(s):  
Elizabeth S. Carlton ◽  
Joshua J. Sutton ◽  
Ariel G. Gale ◽  
George C. Shields ◽  
Keith C. Gordon ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Charge Transfer ◽  
Electronic Transition ◽  
Resonance Raman Spectroscopy ◽  
Resonance Raman ◽  
Electronic Transitions

Augmented with TDDFT, solvatochromism and resonance Raman spectroscopy of RCp2Ti(C2Fc)2 complexes are consistent with the characterization of the lowest-energy electronic transition as a delocalized ethynylferrocene to TiIV charge transfer.

Electronic and Resonance Raman Spectra of the Linear Chain Mixed Valence Compound Pt(NH3)2(SCN)2I

1980 ◽  
Vol 35 (10) ◽  
pp. 1272-1273 ◽  
Author(s):  
Robin J. H. Clark ◽  
Mohamedally Kurmoo ◽  
K. D. Buse ◽  
H. J. Keller
Keyword(s):  
Raman Spectroscopy ◽  
Raman Spectra ◽  
Resonance Raman Spectroscopy ◽  
Linear Chain ◽  
Mixed Valence ◽  
Resonance Raman ◽  
Mixed Valence Compound ◽  
Resonance Raman Spectra

Abstract The partially oxidized cis-Pt(NH3)2(SCN)2I has been studied by resonance Raman spectroscopy. A progression in the symmetric I-PtIV-I vibration (v1 = 120.1 cm-1), reaching as far as 8 v1, has been observed. The compound Pt(NH3)2(SCN)2I could be identified as a mixed valence solid with neutral, linear PtII···I-PtIV chains.

Flow-flash, time-resolved resonance Raman spectroscopy of the oxidation of reduced and of mixed valence cytochrome oxidase by dioxygen

1985 ◽  
Vol 23 (3-4) ◽  
pp. 243-251 ◽  
Author(s):  
Gerald T. Babcock ◽  
John M. Jean ◽  
Leah N. Johnston ◽  
William H. Woodruff ◽  
Graham Palmer
Keyword(s):  
Raman Spectroscopy ◽  
Cytochrome Oxidase ◽  
Resonance Raman Spectroscopy ◽  
Mixed Valence ◽  
Resonance Raman ◽  
Time Resolved
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