Spontaneous fixation of carbon dioxide in air by a nickel diamine complex: synthesis and characterization of a trinuclear nickel(II) complex with a novel hydrogen bonding system around a carbonate ligand

1992 ◽  
Vol 31 (6) ◽  
pp. 1058-1062 ◽  
Author(s):  
Tomoaki Tanase ◽  
Sadao Nitta ◽  
Sadao Yoshikawa ◽  
Kimiko Kobayashi ◽  
Tosio Sakurai ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Hydrogen Bonding ◽  
Synthesis And Characterization ◽  
Bonding System ◽  
Hydrogen Bonding System ◽  
Fixation Of Carbon Dioxide

scholarly journals The Isolation and Characterization of Molecular Complexes Produced from the Reaction of Nitrophenols with Divalent Metal Oxinates

1979 ◽  
Vol 34 (2) ◽  
pp. 230-234 ◽  
Author(s):  
M. M. Aly ◽  
A. M. Shalaby
Keyword(s):  
Hydrogen Bonding ◽  
Charge Transfer ◽  
Charge Transfer Band ◽  
Picric Acid ◽  
Molecular Complexes ◽  
Divalent Metal ◽  
Bonding System ◽  
Isolation And Characterization ◽  
Hydrogen Bonding System

Abstract The reaction of nitrophenols (picric acid, 2,6-dinitrophenol, and 2,4-dinitrophenol) with divalent metal oxinate (metal = Cu, Co, Ni, Mn, and Zn) produced a type of molecular complex, which comprises two molecules of the metal oxinate and one molecule of the nitrophenol. In the case of the Mg complex the ratio is 1:1. A definite charge-transfer band is detected for the Co(II) complex. A hydrogen bonding system O1...H+...O2 is suggested. This includes the proton of the nitrophenol and two oxygen atoms; each is related to a coordinated oxinate of two different metal oxinate molecules. Analytical and spectral evidence are in accordance with the tentatively suggested formulations.

Synthesis and Characterization of a Composite Zeolite-Metglas Carbon Dioxide Sensor

2005 ◽  
Vol 15 (7) ◽  
pp. 1165-1170 ◽  
Author(s):  
I. G. Giannakopoulos ◽  
D. Kouzoudis ◽  
C. A. Grimes ◽  
V. Nikolakis
Keyword(s):  
Carbon Dioxide ◽  
Synthesis And Characterization ◽  
Carbon Dioxide Sensor

Ethylenediammonium thiophene-2,5-dicarboxylate dihydrate, an acid–base complex with a three-dimensional hydrogen-bonding system

2006 ◽  
Vol 62 (7) ◽  
pp. o2951-o2952 ◽  
Author(s):  
Si-Min Wu ◽  
Ming Li ◽  
Jiang-Feng Xiang ◽  
Liang-Jie Yuan ◽  
Ju-Tang Sun
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Three Dimensional ◽  
Water Molecules ◽  
Inversion Center ◽  
Acid Base ◽  
Special Position ◽  
Compound C ◽  
Bonding System ◽  
Hydrogen Bonding System

The crystal structure of the title compound, C2H10N2 2+·C6H2O4S2−·2H2O, is built of ethylenediammonium dications, occupying a special position on an inversion center, thiophene-2,5-dicarboxylate dianions, in a special position on the twofold axis, and water molecules in general positions. All residues are involved in an extensive hydrogen-bonding system, which links them into a three-dimensional supramolecular arrangement.

Synthesis and characterization of clathrate hydrates containing carbon dioxide and ethanol

2010 ◽  
Vol 12 (33) ◽  
pp. 9927 ◽  
Author(s):  
Takeshi Makiya ◽  
Takashi Murakami ◽  
Satoshi Takeya ◽  
Amadeu K. Sum ◽  
Saman Alavi ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Clathrate Hydrates ◽  
Synthesis And Characterization

Structure of Hydrated Copper(II) Colchiceine

1999 ◽  
Vol 52 (4) ◽  
pp. 333 ◽  
Author(s):  
Maureen F. Mackay ◽  
Robert W. Gable ◽  
James D. Morrison ◽  
Lothar O. Satzke
Keyword(s):  
Hydrogen Bonding ◽  
Copper Atom ◽  
Three Dimensional ◽  
Water Molecules ◽  
R Factor ◽  
Bonding System ◽  
Dimensional Network ◽  
Square Planar ◽  
Hydrogen Bonding System ◽  
C 50

Hydrated crystals of copper(II) colchiceine belong to the tetragonal space group P 432I2 with a 13·415(1), c 50·169(8) Å and Z 8. The structure has been refined to a conventional R factor of 0·077 for 4560 observed data. The tropolonic oxygens from two colchiceine molecules are coordinated to the copper atom in this bis-chelated complex to form a square planar arrangement. The sites of three of the waters are clearly defined, but the others are disordered over seven partially occupied sites. An intricate hydrogen-bonding system links the complex and water molecules into a three-dimensional network in the crystal.

Bioinspired catalysis and bromoperoxidase like activity of a multistimuli-responsive supramolecular metallogel: supramolecular assembly triggered by pi–pi stacking and hydrogen bonding interactions

2020 ◽  
Vol 44 (14) ◽  
pp. 5410-5418 ◽  
Author(s):  
Sunshine Dominic Kurbah ◽  
Ram A. Lal
Keyword(s):  
Hydrogen Bonding ◽  
Supramolecular Assembly ◽  
Synthesis And Characterization ◽  
Pi Stacking ◽  
Hydrogen Bonding Interactions ◽  
Bromination Reaction ◽  
Oxidative Bromination ◽  
Self Assembled

We report the synthesis and characterization of a new self-assembled VO2-L metallogel. Multi-responsive properties of the gel were also studied and can be used for sensing OH− anions. Bromoperoxidase-like activity of VO2-L metallogel for oxidative bromination reaction was also reported.

The impact on the ring related vibrational frequencies of pyridine of hydrogen bonds with haloforms – a topology perspective

2019 ◽  
Vol 21 (4) ◽  
pp. 1724-1736 ◽  
Author(s):  
Enrico Benassi ◽  
Kamila Akhmetova ◽  
Haiyan Fan
Keyword(s):  
Hydrogen Bonding ◽  
Hydrogen Bonds ◽  
Ring Structure ◽  
Vibrational Frequencies ◽  
Bonding System ◽  
Hydrogen Bonding System ◽  
The Impact

An intermolecular ring structure is identified for the hydrogen bonding system of pyridine and haloforms.

Synthesis and characterization of a series of novel phenol- and polyphenol-based glycerolipids

2006 ◽  
Vol 84 (10) ◽  
pp. 1411-1415 ◽  
Author(s):  
Rolf Schmidt ◽  
Joseph G Carrigan ◽  
Christine E DeWolf
Keyword(s):  
Hydrogen Bonding ◽  
Chain Length ◽  
Protein Interaction ◽  
Building Block ◽  
Synthesis And Characterization ◽  
Synthetic Route ◽  
Substitution Pattern ◽  
Lipid Protein Interaction ◽  
Block Approach

A building block approach was used to design a modular synthetic route for the preparation of novel glycerolipids with phenolic and polyphenolic headgroups. Based on this scheme, it is possible to vary the substitution pattern of the headgroup, the stereochemistry of the backbone, and the length of the sidechains. Five glycerolipids with different headgroups and identical backbone stereochemistry and chain length have been prepared.Key words: glycerolipid, polyphenol, hydrogen bonding, lipid-protein interaction, self-adhering.

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