Kinetics of formation and reactions of thiyl radicals in aqueous solution

1992 ◽  
Vol 31 (5) ◽  
pp. 720-722 ◽  
Author(s):  
Patrick Huston ◽  
James H. Espenson ◽  
Andreja Bakac
Keyword(s):  
Aqueous Solution ◽  
Thiyl Radicals ◽  
Kinetics Of Formation ◽  
Kinetics Of

The Kinetics of Formation of Blue Peroxychromic Acid in Aqueous Solution

1966 ◽  
Vol 5 (3) ◽  
pp. 466-467 ◽  
Author(s):  
P. Moore ◽  
S. F. A. Kettle ◽  
R. G. Wilkins
Keyword(s):  
Aqueous Solution ◽  
Kinetics Of Formation ◽  
Kinetics Of

THE KINETICS OF THE FORMATION OF THE MONOSULPHATO COMPLEX OF IRON (III) IN AQUEOUS SOLUTION

1962 ◽  
Vol 40 (9) ◽  
pp. 1836-1845 ◽  
Author(s):  
G. G. Davis ◽  
W. MacF. Smith
Keyword(s):  
Experimental Data ◽  
Aqueous Solution ◽  
Ionic Strength ◽  
Continuous Flow ◽  
Hydrogen Ions ◽  
Kcal Mole ◽  
Forward Reaction ◽  
First Order ◽  
Kinetics Of Formation ◽  
Kinetics Of

The kinetics of formation of the monosulphato complex of iron (III) has been examined spectrophotometrically using a continuous-flow technique over the range of temperatures 15.6 to 34.5 °C in an aqueous medium of ionic strength 0.5 and a range of concentrations of hydrogen ions 0.05 to 0.30 M. The experimental data may be interpreted on the assumption that the significant reactions are a bimolecular association opposed by a first-order dissociation [Formula: see text] For the forward reaction ΔH≠ is 18.0 kcal mole−1 and ΔS≠ is 19.4 cal mole−1 deg−1.

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