Electronic spectra and photophysics of platinum(II) complexes with .alpha.-diimine ligands solid-state effects. 2. Metal-metal interaction in double salts and linear chains

1991 ◽  
Vol 30 (23) ◽  
pp. 4446-4452 ◽  
Author(s):  
Vincent M. Miskowski ◽  
Virginia H. Houlding
Keyword(s):  
Solid State ◽  
Electronic Spectra ◽  
Metal Interaction ◽  
Diimine Ligands ◽  
Double Salts ◽  
Linear Chains ◽  
Metal Metal

Kinetic analysis and alloy designs for metal/metal fluorides toward high rate capability for all-solid-state fluoride-ion batteries

2021 ◽  
Vol 9 (11) ◽  
pp. 7018-7024
Author(s):  
Takahiro Yoshinari ◽  
Datong Zhang ◽  
Kentaro Yamamoto ◽  
Yuya Kitaguchi ◽  
Aika Ochi ◽  
...  
Keyword(s):  
Solid State ◽  
Rate Capability ◽  
High Rate ◽  
Fluoride Ion ◽  
Li Ion Batteries ◽  
High Rate Capability ◽  
Metal Fluorides ◽  
New Concepts ◽  
Metal Metal ◽  
Li Ion

A Cu–Au cathode material for all-solid-state fluoride-ion batteries with high rate-capability was designed as new concepts for electrochemical energy storage to handle the physicochemical energy density limit that Li-ion batteries are approaching.

Main-group metal complexes of α-diimine ligands: structure, bonding and reactivity

2021 ◽  
Author(s):  
Rong Zhang ◽  
Yanchao Wang ◽  
Yanxia Zhao ◽  
Carl Redshaw ◽  
Igor L. Fedushkin ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Small Molecule ◽  
Main Group ◽  
Group Metal ◽  
Diimine Ligands ◽  
Main Group Metal ◽  
Metal Metal ◽  
Low Valent

The use of dad (and bian) ligands in the stabilization of main-group complexes, in particular metal–metal-bonded compounds, as well as the small molecule reactivity of these (low-valent) metal complexes, is summarized.

Bis[μ-3,3′-dimethyl-3,3′-methylenebis(2,3-dihydro-1H-imidazole)]disilver(I)(Ag—Ag) dichloride hemihydrate

2006 ◽  
Vol 62 (7) ◽  
pp. m1565-m1566 ◽  
Author(s):  
Da-Qi Wang
Keyword(s):  
Title Compound ◽  
Carbene Ligands ◽  
Metal Interaction ◽  
Metal Metal ◽  
Linear Geometry

In the title compound, [Ag2(C9H12N4)2]Cl2·0.5H2O, each AgI atom is coordinated by two C atoms of two heterocyclic carbene ligands, displaying a nearly linear geometry. The Ag—Ag separation is quite long, indicating a very weak metal–metal interaction.

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