Reactions of monoazadienes with metal carbonyl complexes. 6. Synthesis, separation, and structural characterization (x-ray) of the two diastereomers of Ru3(CO)6[CH3C:C(H)C(H):N-iso-Pr]2, an acyclic trinuclear complex that is isolobally related to Cp2Ru.

1991 ◽  
Vol 30 (22) ◽  
pp. 4152-4159 ◽  
Author(s):  
Wilhelmus P. Mul ◽  
Cornelis J. Elsevier ◽  
Wilberth J. J. Smeets ◽  
Anthony L. Spek
Keyword(s):  
Structural Characterization ◽  
Metal Carbonyl ◽  
Trinuclear Complex ◽  
Carbonyl Complexes ◽  
X Ray ◽  
Metal Carbonyl Complexes

Intra- and intermolecular interactions in a series of chlorido-tricarbonyl-diazabutadienerhenium(I) complexes: structural and theoretical studies

2020 ◽  
Vol 76 (3) ◽  
pp. 417-426 ◽  
Author(s):  
Reza Kia ◽  
Azadeh Kalaghchi
Keyword(s):  
Intermolecular Interactions ◽  
Density Functional ◽  
Metal Carbonyl ◽  
Lone Pair ◽  
Carbonyl Complexes ◽  
X Ray Diffraction ◽  
Functional Theory ◽  
X Ray ◽  
Covalent Interaction ◽  
Metal Carbonyl Complexes

A series of new chlorido-tricarbonylrhenium(I) complexes bearing alkyl-substituted diazabutadiene (DAB) ligands, namely N,N′-bis(2,4-dimethylbenzene)-1,4-diazabutadiene (L1), N,N′-bis(2,4-dimethylbenzene)-2,3-dimethyl-1,4-diazabutadiene (L2), N,N′-bis(2,4,6-trimethylbenzene)-2,3-dimethyl-1,4-diazabutadiene (L3) and N,N′-bis(2,6-diisopropylbenzene)-1,4-diazabutadiene (L4), were synthesized and investigated. The crystal structures have been fully characterized by X-ray diffraction and spectroscopic methods. Density functional theory, natural bond orbital and non-covalent interaction index methods have been used to study the optimized geometry in the gas phase and intra- and intermolecular interactions in the complexes, respectively. The most important studied interactions in these metal carbonyl complexes are n→π*, n→σ* and π→π*. Among complexes 1–4, only 2 shows interesting intermolecular n→π* interactions due to lp(C[triple-bond]O)...π* and lp(Cl)...π* (lp = lone pair) contacts.

Synthesis and X-ray structures of some metal carbonyl complexes containing dipyridylformamidine ligands

2003 ◽  
Vol 669 (1-2) ◽  
pp. 182-188 ◽  
Author(s):  
Hsiu-Chi Liang ◽  
Ying-Yann Wu ◽  
Fang-Chu Chang ◽  
Pang-Yen Yang ◽  
Jhy-Der Chen ◽  
...  
Keyword(s):  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
X Ray ◽  
Metal Carbonyl Complexes

Reaction of bromopentacarbonylrhenium(I) with ferrocenylcarbaldehyde thiosemicarbazones: the first X-ray diffraction studies of metal carbonyl complexes containing bidentate thiosemicarbazone ligands

2002 ◽  
Vol 656 (1-2) ◽  
pp. 1-10 ◽  
Author(s):  
Rosa Carballo ◽  
José S Casas ◽  
Emilia Garcı́a-Martı́nez ◽  
Gumersindo Pereiras-Gabián ◽  
Agustı́n Sánchez ◽  
...  
Keyword(s):  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
X Ray Diffraction ◽  
X Ray ◽  
Metal Carbonyl Complexes
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