Rearrangement of a phosphorus-carbon-phosphorus bridge to a phosphorus-nitrogen-phosphorus bridge via organogermanium- or organotin-assisted cleavage of a phosphorus-carbon bond. Crystal and molecular structure of the imine salt (CH3)Ph2PNPPh2(NH2)+Cl-

1991 ◽  
Vol 30 (12) ◽  
pp. 2631-2633 ◽  
Author(s):  
Kattesh V. Katti ◽  
A. A. Pinkerton ◽  
Ronald G. Cavell
1991 ◽  
Vol 46 (3) ◽  
pp. 285-288 ◽  
Author(s):  
Dallas L. Wilkinson ◽  
Jürgen Riede ◽  
Gerhard Müller

The crystal and molecular structure of Bis(pentafluorophenyl)mercury, Hg(C6F5)2, was redetermined from diffractometer data yielding greatly improved structural parameters. The geometry at mercury is virtually linear (C—Hg—C 178.8(3)°), with mercury carbon bond lengths of 2.047(6) and 2.052(6) Å.


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