Synthesis of the tetraphenylphosphonium and tetraethylammonium salts of tetrakis(benzeneselenolato)metalate(2-) [M(SePh)42], (M = manganese, iron, cobalt, nickel) and the structure of [NEt4]2[Fe(SePh)4].MeCN

1991 ◽  
Vol 30 (8) ◽  
pp. 1770-1773 ◽  
Author(s):  
Jonathan M. McConnachie ◽  
James A. Ibers
Keyword(s):  
Iron Cobalt ◽  
Cobalt Nickel ◽  
Tetraethylammonium Salts

Extraction of iron, cobalt, nickel and copper with dibenzyl sulfoxide solution in toluene

1979 ◽  
Vol 44 (7) ◽  
pp. 2024-2031 ◽  
Author(s):  
František Vláčil ◽  
Huynh Dang Khanh
Keyword(s):  
Nitric Acid ◽  
Hydrochloric Acid ◽  
Distribution Ratio ◽  
Separation Factor ◽  
Chromatographic Separation ◽  
The Other ◽  
Iron Cobalt ◽  
Cobalt Nickel ◽  
Factor Α

The dependence of the distribution ratio of the metal on the concentration of hydrochloric of nitric acid was examined for Fe, Co, Ni and Cu extraction with 0.05M solution of dibenzylsulfoxide in toluene. Iron is extracted considerably more than the other metals, and is better extracted from hydrochloric acid than from nitric acid. The separation factor αFe/M (for 8M-HCl) is of the order of 104; this is not sufficient for a separation of trace quantities of iron from Co, Ni and Cu, but even at lower concentrations of HCl (e.g., 5M) the values is high enough for extraction chromatographic separation. The composition of the iron solvate extracted from HCl or LiCl medium was determined to be HFeCl4.2 B (B = dibenzyl sulfoxide).

scholarly journals On the Dissolution of Metals in Ionic Liquids 1. Iron, Cobalt, Nickel, Copper, and Zinc

2021 ◽  
Vol 2 (1) ◽  
pp. 63-73
Author(s):  
Jéssica D. S. Vicente ◽  
Domingas C. Miguel ◽  
Afonso M. P. Gonçalves ◽  
Diogo M. Cabrita ◽  
José M. Carretas ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Redox Potential ◽  
Final State ◽  
Iron Cobalt ◽  
Influence Of Temperature ◽  
Dissolution Reaction ◽  
Cobalt Nickel ◽  
Iron Metal ◽  
Copper And Zinc ◽  
Nickel Copper

Ionic liquids are critical reagents for science and technical processes nowadays. Metals are the most used reagents in the industry. It is crucial to have a deeper understanding of how ionic liquids and metals could interact. In this article the interaction of those two families of compounds is accessed. The dissolution (reaction) of metals with ionic liquids is studied, namely the influence of temperature, redox potential, and availability of an oxidant in the process. The final state achieved by the iron metal samples was also addressed by Mössbauer spectroscopy.

Polarization phenomena in the electrodeposition of a finely divided iron-cobalt-nickel alloy

1971 ◽  
Vol 10 (5) ◽  
pp. 347-350
Author(s):  
�. M. Natanson ◽  
T. M. Shvets ◽  
Z. M. Mel'nichenko ◽  
V. S. Sperkach
Keyword(s):  
Nickel Alloy ◽  
Iron Cobalt ◽  
Cobalt Nickel ◽  
Polarization Phenomena

DIFFUSION OF Ni63 IN IRON, COBALT, NICKEL, AND TWO IRON–NICKEL ALLOYS

1959 ◽  
Vol 37 (10) ◽  
pp. 1629-1636 ◽  
Author(s):  
J. R. MacEwan ◽  
J. U. MacEwan ◽  
L. Yaffe
Keyword(s):  
Surface Activity ◽  
Nickel Alloys ◽  
Nickel Content ◽  
The Self ◽  
Iron Cobalt ◽  
Self Diffusion ◽  
Cobalt Nickel ◽  
Iron Nickel ◽  
Iron Nickel Alloys ◽  
Cobalt And Nickel

The self-diffusion of nickel and the diffusion of Ni63 into iron, cobalt, and two iron–nickel alloys was studied using the technique of decrease in surface activity, The nickel self-diffusion results are compared to previously reported values. Nickel is found to diffuse more slowly than iron in the iron-rich portion of the iron–nickel system. The rate of nickel diffusion increases with increasing nickel content. A comparison is made between the present results for diffusion of Ni63 into iron, cobalt, and nickel with reported values for diffusion of Co60 and Fe59 in the same metals. In each solvent, the magnitudes of the activation energies, Q, are such that QNi > QCo > QFe.

Graphite Furnace Atomic Absorption Spectrometric Determination of Iron, Cobalt, Nickel, and Copper at Parts-Per-Billion Level in High-Purity Lanthanum Fluoride

1993 ◽  
Vol 47 (8) ◽  
pp. 1169-1170 ◽  
Author(s):  
James Jaganathan ◽  
Ishwar Aggarwal
Keyword(s):  
Atomic Absorption ◽  
Graphite Furnace ◽  
Absorption Spectrometry ◽  
Lanthanum Fluoride ◽  
Matrix Modifier ◽  
Iron Cobalt ◽  
Cobalt Nickel ◽  
Graphite Furnace Atomic Absorption ◽  
Atomic Absorption Spectrometric

This paper describes an analytical method for the quantitation of iron, cobalt, nickel, and copper in lanthanum fluoride at trace levels with graphite furnace atomic absorption spectrometry (GFAAS) without using any matrix modifier. These metals were preconcentrated in HNO3 and analyzed directly. The detection limits for iron, cobalt, nickel, and copper were found to be 3, 1, 2, and 2 ppb, respectively. The average precision of measurements (°/o RSD) for all the elements was <10%.

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