Role of osmium in the reaction of the hydrazinium cation with chlorate in acid solution

Simeen. Sattar; Kenneth. Kustin

doi:10.1021/ic00007a047

Role of osmium in the reaction of the hydrazinium cation with chlorate in acid solution

Inorganic Chemistry ◽

10.1021/ic00007a047 ◽

1991 ◽

Vol 30 (7) ◽

pp. 1668-1670 ◽

Cited By ~ 8

Author(s):

Simeen. Sattar ◽

Kenneth. Kustin

Keyword(s):

Acid Solution ◽

Hydrazinium Cation

Download Full-text

ChemInform Abstract: Systematic Design of Chemical Oscillators. Part 71. Role of Osmium in the Reaction of the Hydrazinium Cation with Chlorate in Acid Solution.

ChemInform ◽

10.1002/chin.199128022 ◽

2010 ◽

Vol 22 (28) ◽

pp. no-no

Author(s):

S. SATTAR ◽

K. KUSTIN

Keyword(s):

Acid Solution ◽

Systematic Design ◽

Chemical Oscillators ◽

Hydrazinium Cation

Download Full-text

Exploring the potential role of pyrazoline derivatives in corrosion inhibition of mild steel in hydrochloric acid solution: Insights from experimental and computational studies

Construction and Building Materials ◽

10.1016/j.conbuildmat.2019.117320 ◽

2020 ◽

Vol 233 ◽

pp. 117320 ◽

Cited By ~ 31

Author(s):

Hassane Lgaz ◽

Sourav Kr. Saha ◽

Abdelkarim Chaouiki ◽

K. Subrahmanya Bhat ◽

Rachid Salghi ◽

...

Keyword(s):

Hydrochloric Acid ◽

Acid Solution ◽

Mild Steel ◽

Corrosion Inhibition ◽

Hydrochloric Acid Solution ◽

Potential Role ◽

Computational Studies

Download Full-text

Electrodeposition of tin oxide thin film from nitric acid solution: the role of pH

Journal of Materials Science Materials in Electronics ◽

10.1007/s10854-017-6511-8 ◽

2017 ◽

Vol 28 (11) ◽

pp. 8051-8060

Author(s):

K. Daideche ◽

A. Azizi

Keyword(s):

Thin Film ◽

Nitric Acid ◽

Acid Solution ◽

Nitric Acid Solution ◽

Tin Oxide ◽

Oxide Thin Film

Download Full-text

The role of protein content on the steady and oscillatory shear rheology of model synovial fluids

Soft Matter ◽

10.1039/c4sm00716f ◽

2014 ◽

Vol 10 (32) ◽

pp. 5965-5973 ◽

Cited By ~ 14

Author(s):

Z. Zhang ◽

S. Barman ◽

G. F. Christopher

Keyword(s):

Hyaluronic Acid ◽

Synovial Fluid ◽

Acid Solution ◽

Protein Content ◽

Shear Viscosity ◽

Steady Shear ◽

Interfacial Rheology ◽

Steady Shear Viscosity ◽

Synovial Fluids

Model synovial fluid steady shear viscosity to hyaluronic acid solution are identical when interfacial rheology effects are removed.

Download Full-text

Migration of hydroxyl in secondary systems during solvolysis in acid solution

Canadian Journal of Chemistry ◽

10.1139/v77-532 ◽

1977 ◽

Vol 55 (21) ◽

pp. 3774-3785 ◽

Cited By ~ 1

Author(s):

Robert C. Cathcart ◽

John W. Bovenkamp ◽

Robert Y. Moir ◽

Robert A. B. Bannard ◽

Alfred A. Casselman

Keyword(s):

Acid Solution ◽

Reverse Reaction ◽

Secondary Hydroxyl ◽

Secondary Systems ◽

Acid Catalyzed ◽

Decisive Evidence

A system of compounds has been prepared which is well adapted for displaying the role of trans vicinal, secondary hydroxyl in solvolysis. On methanolysis in acid solution, compounds 5, 7a, and 8a all gave the same products, 9a and 10a, and in practically the same proportions, suggesting that at least one intermediate was common to all three reactions. These intermediates were such that 7a and 8a were not interconverted during the solvolysis, a fact in support of 6 as a common intermediate. Several alternative explanations were shown to be untenable, largely by taking advantage of the remarkable differences between hydroxyl and methoxyl. The work provides the most decisive evidence available for the covalent participation of hydroxyl as a neighbor group in the solvolysis of secondary systems, and contributes also to the study of the reverse reaction, the acid-catalyzed scission of epoxides.

Download Full-text