Methanation of Low Levels of Carbon Monoxide over Nickel Catalyst

1969 ◽  
Vol 8 (4) ◽  
pp. 347-352 ◽  
Author(s):  
S. S. Randhava ◽  
E. H. Camara ◽  
Amirali Rehmat
2010 ◽  
Vol 30 (4) ◽  
pp. 437-447 ◽  
Author(s):  
Y. S. Mok ◽  
H.-C. Kang ◽  
H.-J. Lee ◽  
D. J. Koh ◽  
D. N. Shin

One of the most interesting cases of promoter action is that in which a mixture of two substances, each of which functions as a catalyst for the same action, shows greater activity than either constituent alone. Thus in the synthesis of ammonia an iron-molybdenum catalyst is stated to afford greater yields of ammonia than is given by either of the metals alone. Again, the production of formaldehyde from methyl alcohol and air was found by Hochstetter to be more effectively performed in presence of a silver-copper alloy than by either silver or copper alone. Carbon monoxide is oxidised more efficiently in presence of certain mixtures of oxides, for example “hopcalite,” than in presence of the constituent oxides (manganese and copper oxides).


Author(s):  
Stephen G. Pothier ◽  
David Chichka

This paper describes a theoretical device called a Petroleum Synthesizer, which absorbs the greenhouse gas carbon dioxide from the atmosphere and converts it into a synthetic petroleum fuel. The device has four parts: First, a CO2 Scrubber using sodium carbonate reversibly absorbs CO2 from the atmosphere. Simultaneously, a Hydrogen Generator separates water electrolytically to produce hydrogen (H2). Third, a Carbon Monoxide Generator mixes the H2 and the CO2 over a nickel catalyst, changing the constituents into carbon monoxide (CO) and water. Finally, the CO and additional H2 are combined in a cobalt-catalyst Fischer-Tropsch (F-T) Processor to produce gaseous and liquid petroleum products. Calculations show that one watt of electricity supplied for one year would allow the Synthesizer to create 0.420 kg of petroleum products, and absorb 1.314 kg of CO2 from the atmosphere. An acre of solar voltaic panels powering Synthesizers could produce 46,000 kg, or about 14,000 gallons, of petroleum products per acre per year, and absorb 140,000 kg of CO2. By contrast, an acre of corn produces less than 400 gallons of ethanol per year.


1982 ◽  
Vol 2 (6) ◽  
pp. 347-358
Author(s):  
Albert C. Frost ◽  
Louis F. Elek ◽  
Chang-Lee Yang ◽  
Alan P. Risch ◽  
Jule A. Rabo

2011 ◽  
Vol 2011 ◽  
pp. 1-4 ◽  
Author(s):  
Anne M. Henstra ◽  
Alfons J. M. Stams

Carboxydothermus hydrogenoformansis a thermophilic strictly anaerobic bacterium that catalyses the water gas shift reaction, the conversion of carbon monoxide with water to molecular hydrogen and carbon dioxide. The thermodynamically favorable growth temperature, compared to existing industrial catalytic processes, makes this organism an interesting alternative for production of cheap hydrogen gas suitable to fuel CO-sensitive fuel cells in a future hydrogen economy, provided sufficiently low levels of CO are reached. Here we study CO conversion and final CO levels in cultures ofC. hydrogenoformansgrown in batch cultures that were started with a 100% CO gas phase with and without removal of formed CO2. Final CO levels were 117 ppm without CO2removal and below 2 ppm with CO2removal. The Gibbs free energy change calculated with measured end concentrations and the detection of acetate suggest thatC. hydrogenoformansshifted from a hydrogenogenic to an acetogenic metabolism.


1977 ◽  
Vol 45 (3) ◽  
pp. 1007-1014 ◽  
Author(s):  
Vernon A. Benignus ◽  
David A. Otto ◽  
James D. Prah ◽  
Gayla Benignus

Previous publications on the effects of low levels of carbon monoxide (CO) on human vigilance performance have found conflicting results. While several studies have found statistically reliable effects, none have gone unchallenged. This article presents a critical review of the literature and the results of a study employing 52 human male subjects performing a numeric monitoring task. CO levels were 0, 100, and 200 ppm which produced mean carboxyhemoglobin levels 0.01, 4.61 and 12.62 percent respectively. No CO-exposure levels produced any effect on vigilance performance. The power of the statistical test for CO effects was shown to be quite high, even for fairly trivial possible decrements of performance.


1987 ◽  
Vol 33 (1) ◽  
pp. 179-184 ◽  
Author(s):  
S. Fujita ◽  
H. Terunuma ◽  
H. Kobayashi ◽  
N. Takezawa

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