Catalyst Activity and Performance of Stability-Limited Fixed-Bed Reactors

1971 ◽  
Vol 10 (4) ◽  
pp. 483-489 ◽  
Author(s):  
K. P. Williams ◽  
J. C. Matthews
1981 ◽  
Vol 34 (6) ◽  
pp. 1325 ◽  
Author(s):  
NR Foster ◽  
MS Wainwright ◽  
DWB Westerman

The oxidation of naphthalene over vanadia catalysts promoted by alkali- metal sulfates was studied in the temperature range 400-440°C. The effects of SO3 levels and alkali-metal sulfate promoter type on catalyst activity and selectivity were investigated in laboratory fixed-bed reactors employing integral conversions. ��� The relative promoting abilities of the alkali metals sodium, potassium, rubidium and caesium were investigated with laboratory catalyst preparations. Alkali metals of higher atomic number favoured selectivity to partial oxidation products with an associated loss in overall activity.


1972 ◽  
Vol 27 (2) ◽  
pp. 329-338 ◽  
Author(s):  
G.R. Gavalas ◽  
G.C. Hsu ◽  
J.H. Seinfeld

2017 ◽  
Vol 37 (1) ◽  
pp. 160-172 ◽  
Author(s):  
Douglas G. B. Torres ◽  
Shaiane Dal' Maso Lucas ◽  
Cristiane L. Andreani ◽  
Karina Q. de Carvalho ◽  
Silvia R. M. Coelho ◽  
...  

1993 ◽  
Vol 106 (2) ◽  
pp. 193-199 ◽  
Author(s):  
Ying-Sheng Cheng ◽  
Felipe López-Isunza ◽  
Tharathon Mongkhonsi ◽  
Lester Kershenbaum

2006 ◽  
Vol 27 (1) ◽  
pp. 85-93 ◽  
Author(s):  
E. Sánchez ◽  
R. Borja ◽  
L. Travieso ◽  
A. Martín ◽  
M.F. Colmenarejo ◽  
...  

2017 ◽  
Vol 10 ◽  
pp. S2806-S2828 ◽  
Author(s):  
Piyapong Hunpinyo ◽  
Phavanee Narataruksa ◽  
Sabaithip Tungkamani ◽  
Karn Pana-Suppamassadu ◽  
Nuwong Chollacoop ◽  
...  

1990 ◽  
Vol 22 (1-2) ◽  
pp. 347-352 ◽  
Author(s):  
C. Paffoni ◽  
B. Védry ◽  
M. Gousailles

The Paris Metropolitan area, which contains over eight million inhabitants, has a daily output of about 3 M cu.meters of wastewater, the purification of which is achieved by SIAAP (Paris Metropolitan Area Sewage Service) in both Achères and Valenton plants. The carbon pollution is eliminated from over 2 M cu.m/day at Achères. In order to improve the quality of output water, its tertiary nitrification in fixed-bed reactors has been contemplated. The BIOFOR (Degremont) and BIOCARBONE (OTV) processes could be tested in semi-industrial pilot reactors at the CRITER research center of SIAAP. At a reference temperature of 13°C, the removed load is approximately 0.5 kg N NH4/m3.day. From a practical point of view, it may be asserted that in such operating conditions as should be at the Achères plant, one cubic meter of filter can handle the tertiary nitification of one cubic meter of purified water per hour at an effluent temperature of 13°C.


1995 ◽  
Vol 31 (9) ◽  
pp. 137-144 ◽  
Author(s):  
T. Miyahara ◽  
M. Takano ◽  
T. Noike

The relationship between the filter media and the behaviour of anaerobic bacteria was studied using anaerobic fixed-bed reactors. At an HRT of 48 hours, the number of suspended acidogenic bacteria was higher than those attached to the filter media. On the other hand, the number of attached methanogenic bacteria was more than ten times as higher than that of suspended ones. The numbers of suspended and deposited acidogenic and methanogenic bacteria in the reactor operated at an HRT of 3 hours were almost the same as those in the reactor operated at an HRT of 48 hours. Accumulation of attached bacteria was promoted by decreasing the HRT of the reactor. The number of acidogenic bacteria in the reactor packed sparsely with the filter media was higher than that in the closely packed reactor. The number of methanogenic bacteria in the sparsely packed reactor was lower than that in the closely packed reactor.


1999 ◽  
Vol 39 (4) ◽  
pp. 85-92 ◽  
Author(s):  
J. Behrendt

A mathematical model for nitrification in an aerated fixed bed reactor has been developed. This model is based on material balances in the bulk liquid, gas phase and in the biofilm area. The fixed bed is divided into a number of cells according to the reduced remixing behaviour. A fixed bed cell consists of 4 compartments: the support, the gas phase, the bulk liquid phase and the stagnant volume containing the biofilm. In the stagnant volume the biological transmutation of the ammonia is located. The transport phenomena are modelled with mass transfer formulations so that the balances could be formulated as an initial value problem. The results of the simulation and experiments are compared.


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