Kinetics of donor-solvent liquefaction of bituminous coals in nonisothermal experiments

1981 ◽  
Vol 20 (2) ◽  
pp. 349-358 ◽  
Author(s):  
Govindan Mohan ◽  
Harry Silla
1990 ◽  
Vol 4 (5) ◽  
pp. 448-452 ◽  
Author(s):  
Ramin Abhari ◽  
Leslie L. Isaacs

2021 ◽  
Vol 46 (2) ◽  
Author(s):  
A. D. Adesina ◽  
I. A Babatunde

The kinetics of the reaction of 2,4-dinitrofluorobenzene with cyclohexylamine were studied at different concentrations in toluene and toluene-alkanol mixtures. The reaction was not base-catalysed in toluene. Addition of small amounts of hydrogen-bond donor solvent, alkanol (ranging from methanol to hexanol) to the toluene medium of the reactions produced a different effect in comparison to uncatalysed reactions — slight increase in rate of reaction. The results are rationalized in terms of the effect of amine-solvent interaction on the nucleophilicity of the amine in addition to some other factors operating through cyclic transition states leading to products. It is also attributed to the peculiar nature of fluoride ion as a leaving group.


2015 ◽  
Vol 130 ◽  
pp. 282-291 ◽  
Author(s):  
Stanisław Porada ◽  
Grzegorz Czerski ◽  
Tadeusz Dziok ◽  
Przemysław Grzywacz ◽  
Dorota Makowska

Fuel ◽  
1989 ◽  
Vol 68 (11) ◽  
pp. 1434-1438 ◽  
Author(s):  
Gergina Angelova ◽  
Dimitar Kamenski ◽  
Nedialka Dimova
Keyword(s):  

2001 ◽  
Vol 15 (6) ◽  
pp. 1387-1395 ◽  
Author(s):  
A. L. McCutcheon ◽  
W. A. Barton ◽  
M. A. Wilson

2016 ◽  
Vol 154 ◽  
pp. 147-155 ◽  
Author(s):  
Lei Zhang ◽  
James C. Hower ◽  
Wen-li Liu
Keyword(s):  

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