scholarly journals Real-Time X-ray Absorption Spectroscopy of Uranium, Iron, and Manganese in Contaminated Sediments During Bioreduction

2008 ◽  
Vol 42 (8) ◽  
pp. 2839-2844 ◽  
Author(s):  
Tetsu K. Tokunaga ◽  
Jiamin Wan ◽  
Yongman Kim ◽  
Steve R. Sutton ◽  
Matthew Newville ◽  
...  
2012 ◽  
Vol 1480 ◽  
Author(s):  
Christina M. Gonzalez ◽  
Jason G. Parsons ◽  
Jeffrey Hernandez ◽  
Jorge L. Gardea-Torresdey

ABSTRACTIncreasing concentrations of selenium oxoanions in the environment are placing many animals at risk for reproduction failure and deformities. The understanding of binding mechanisms of selenium oxoanions to iron and manganese based oxide minerals could lead to enhanced understanding of selenium mobility in the environment. In this study, the binding mechanisms of selenium oxoanions, selenite and selenate, to non microwave-assisted and microwave-assisted synthetic Fe3O4, Mn3O4, and MnFe2O4 nanomaterials were investigated through the use of X-ray absorption spectroscopy. The X-ray absorption near-edge structure (XANES) spectroscopy studies revealed the oxidation state of selenite and selenate remains the same after binding occurs to all nanomaterials in pH 2, 4, or 6 environments. The binding modes of selenite and selenate were determined to be bidentate binuclear through use of Extended x-ray absorption fine structure (EXAFS) and were independent of nanomaterials, synthetic technique, and pH.


ChemPhysChem ◽  
2009 ◽  
Vol 10 (13) ◽  
pp. 2197-2200 ◽  
Author(s):  
Matthias Bauer ◽  
Helmut Bertagnolli

2014 ◽  
Vol 142 ◽  
pp. 299-313 ◽  
Author(s):  
Julia H. Jamieson-Hanes ◽  
Adam M. Lentz ◽  
Richard T. Amos ◽  
Carol J. Ptacek ◽  
David W. Blowes

2016 ◽  
Vol 52 (19) ◽  
pp. 3734-3749 ◽  
Author(s):  
Jeongho Kim ◽  
Kyung Hwan Kim ◽  
Key Young Oang ◽  
Jae Hyuk Lee ◽  
Kiryong Hong ◽  
...  

TRXL and TRXAS are powerful techniques for real-time probing of structural and electronic dynamics of photoinduced reactions in solution phase.


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