scholarly journals Effect of Solar Radiation on the Optical Properties and Molecular Composition of Laboratory Proxies of Atmospheric Brown Carbon

2014 ◽  
Vol 48 (17) ◽  
pp. 10217-10226 ◽  
Author(s):  
Hyun Ji (Julie) Lee ◽  
Paige Kuuipo Aiona ◽  
Alexander Laskin ◽  
Julia Laskin ◽  
Sergey A. Nizkorodov
Keyword(s):  
Optical Properties ◽  
Solar Radiation ◽  
Molecular Composition ◽  
Brown Carbon

Molecular Composition and the Optical Properties of Brown Carbon Generated by the Ethane Flame

2020 ◽  
Vol 4 (7) ◽  
pp. 1090-1103
Author(s):  
Christopher P. West ◽  
Anusha Priyadarshani Silva Hettiyadura ◽  
Andrew Darmody ◽  
Gaurav Mahamuni ◽  
Justin Davis ◽  
...  
Keyword(s):  
Optical Properties ◽  
Molecular Composition ◽  
Brown Carbon

Physical a priori solar radiation pressure models for GNSS satellites with the focus on BDS

2021 ◽  
Author(s):  
Bingbing Duan ◽  
Urs Hugentobler ◽  
Inga Selmke ◽  
Stefan Marz
Keyword(s):  
Optical Properties ◽  
Solar Radiation ◽  
Thermal Radiation ◽  
Radiation Pressure ◽  
Total Mass ◽  
A Priori ◽  
Solar Radiation Pressure ◽  
The Other ◽  
Time Range ◽  
Satellite Attitude

<p>A physical a priori box-wing solar radiation pressure (SRP) model is widely used by most analysis centers for Galileo and QZSS (Quasi-Zenith Satellite System) satellites, complemented by an ECOM or ECOM2 (Empirical CODE Orbit Model) model. For the other constellations, for instance GPS and GLONASS satellites, optical properties of satellite surfaces are not publicly available, especially for GPS Block IIF and GLONASS satellites. By fixing satellite surface areas and total mass to the values from some unpublished documents, we estimate satellite surface optical properties based on true GNSS measurements covering long time periods (typically this should be longer than a full beta angle time range to reduce correlations between parameters). Meanwhile, various physical effects are considered, such as yaw bias, radiator emission and thermal radiation of solar panels. We find that yaw bias of GPS Block IIA and IIR satellites does not dominate the Y-bias, it is likely that heat generated in the satellite is radiated from louvers or heat pipes on the Y side of the satellite. It is also noted that the ECOM Y0 estimates of both GPS and GLONASS satellites show clear anomaly during eclipse seasons. This indicates that the radiator emission is present when the satellite crosses shadows. Since satellite attitude during eclipse seasons could be different from the nominal yaw, potential radiator effect in the –X surface could be wrongly absorbed by the ECOM Y0 as well. By considering all the estimated parameters in an a priori model we observe clear improvement in satellite orbits, especially for GLONASS satellites. China’s Beidou-3 satellites are now providing PNT (positioning, navigation and timing) service globally. Satellite attitude, dimensions and total mass are publicly available. Also, the absorption optical properties of each satellite surface are given. With all this information, we estimate the other optical properties of Beidou satellites considering similar yaw bias, radiator and thermal radiation effects as those in GPS and GLONASS satellites.</p>

Optical properties of aerosol brown carbon (BrC) in the eastern Indo-Gangetic Plain

2020 ◽  
Vol 716 ◽  
pp. 137102 ◽  
Author(s):  
Archita Rana ◽  
Supriya Dey ◽  
Prashant Rawat ◽  
Arya Mukherjee ◽  
Jingying Mao ◽  
...  
Keyword(s):  
Optical Properties ◽  
Gangetic Plain ◽  
Brown Carbon ◽  
Indo Gangetic Plain

Wintertime Optical Properties of Primary and Secondary Brown Carbon at a Regional Site in the North China Plain

2019 ◽  
Vol 53 (21) ◽  
pp. 12389-12397 ◽  
Author(s):  
Qiyuan Wang ◽  
Jianhuai Ye ◽  
Yichen Wang ◽  
Ting Zhang ◽  
Weikang Ran ◽  
...  
Keyword(s):  
Optical Properties ◽  
North China Plain ◽  
North China ◽  
Brown Carbon ◽  
The North ◽  
The North China Plain

Brown Carbon Spheres in East Asian Outflow and Their Optical Properties

Science ◽  
2008 ◽  
Vol 321 (5890) ◽  
pp. 833-836 ◽  
Author(s):  
D. T. L. Alexander ◽  
P. A. Crozier ◽  
J. R. Anderson
Keyword(s):  
Optical Properties ◽  
East Asian ◽  
Carbon Spheres ◽  
Brown Carbon

scholarly journals Attribution of aerosol light absorption to black carbon, brown carbon, and dust in China – interpretations of atmospheric measurements during EAST-AIRE

2009 ◽  
Vol 9 (6) ◽  
pp. 2035-2050 ◽  
Author(s):  
M. Yang ◽  
S. G. Howell ◽  
J. Zhuang ◽  
B. J. Huebert
Keyword(s):  
Optical Properties ◽  
Black Carbon ◽  
Light Absorption ◽  
Northern China ◽  
Wavelength Dependence ◽  
Atmospheric Measurements ◽  
Brown Carbon ◽  
Mass Distributions ◽  
Limit Value ◽  
Light Absorbers

Abstract. Black carbon, brown carbon, and mineral dust are three of the most important light absorbing aerosols. Their optical properties differ greatly and are distinctive functions of the wavelength of light. Most optical instruments that quantify light absorption, however, are unable to distinguish one type of absorbing aerosol from another. It is thus instructive to separate total absorption from these different light absorbers to gain a better understanding of the optical characteristics of each aerosol type. During the EAST-AIRE (East Asian Study of Tropospheric Aerosols: an International Regional Experiment) campaign near Beijing, we measured light scattering using a nephelometer, and light absorption using an aethalometer and a particulate soot absorption photometer. We also measured the total mass concentrations of carbonaceous (elemental and organic carbon) and inorganic particulates, as well as aerosol number and mass distributions. We were able to identify periods during the campaign that were dominated by dust, biomass burning, fresh (industrial) chimney plumes, other coal burning pollution, and relatively clean (background) air for Northern China. Each of these air masses possessed distinct intensive optical properties, including the single scatter albedo and Ångstrom exponents. Based on the wavelength-dependence and particle size distribution, we apportioned total light absorption to black carbon, brown carbon, and dust; their mass absorption efficiencies at 550 nm were estimated to be 9.5, 0.5 (a lower limit value), and 0.03 m2/g, respectively. While agreeing with the common consensus that black carbon is the most important light absorber in the mid-visible, we demonstrated that brown carbon and dust could also cause significant absorption, especially at shorter wavelengths.

scholarly journals Deposition of brown carbon onto snow: changes in snow optical and radiative properties

2020 ◽  
Vol 20 (10) ◽  
pp. 6095-6114 ◽  
Author(s):  
Nicholas D. Beres ◽  
Deep Sengupta ◽  
Vera Samburova ◽  
Andrey Y. Khlystov ◽  
Hans Moosmüller
Keyword(s):  
Optical Properties ◽  
Organic Carbon ◽  
Total Organic Carbon ◽  
Radiative Forcing ◽  
Radiative Properties ◽  
Unit Mass ◽  
Small Scale ◽  
Snow Surface ◽  
Brown Carbon ◽  
Snow Albedo

Abstract. Light-absorbing organic carbon aerosol – colloquially known as brown carbon (BrC) – is emitted from combustion processes and has a brownish or yellowish visual appearance, caused by enhanced light absorption at shorter visible and ultraviolet wavelengths (0.3 µm≲λ≲0.5 µm). Recently, optical properties of atmospheric BrC aerosols have become the topic of intense research, but little is known about how BrC deposition onto snow surfaces affects the spectral snow albedo, which can alter the resulting radiative forcing and in-snow photochemistry. Wildland fires in close proximity to the cryosphere, such as peatland fires that emit large quantities of BrC, are becoming more common at high latitudes, potentially affecting nearby snow and ice surfaces. In this study, we describe the artificial deposition of BrC aerosol with known optical, chemical, and physical properties onto the snow surface, and we monitor its spectral radiative impact and compare it directly to modeled values. First, using small-scale combustion of Alaskan peat, BrC aerosols were artificially deposited onto the snow surface. UV–Vis absorbance and total organic carbon (TOC) concentration of snow samples were measured for samples with and without artificial BrC deposition. These measurements were used to first derive a BrC (mass) specific absorption (m2 g−1) across the UV–Vis spectral range. We then estimate the imaginary part of the refractive index of deposited BrC aerosol using a volume mixing rule. Single-particle optical properties were calculated using Mie theory, and these values were used to show that the measured spectral snow albedo of snow with deposited BrC was in general agreement with modeled spectral snow albedo using calculated BrC optical properties. The instantaneous radiative forcing per unit mass of total organic carbon deposited to the ambient snowpack was found to be 1.23 (+0.14/-0.11) W m−2 per part per million (ppm). We estimate the same deposition onto a pure snowpack without light-absorbing impurities would have resulted in an instantaneous radiative forcing per unit mass of 2.68 (+0.27/-0.22) W m−2 per ppm of BrC deposited.

scholarly journals Chemical and optical properties of carbonaceous aerosols in Nanjing, eastern China: regionally transported biomass burning contribution

2019 ◽  
Vol 19 (17) ◽  
pp. 11213-11233 ◽  
Author(s):  
Xiaoyan Liu ◽  
Yan-Lin Zhang ◽  
Yiran Peng ◽  
Lulu Xu ◽  
Chunmao Zhu ◽  
...  
Keyword(s):  
Optical Properties ◽  
Organic Carbon ◽  
Solar Energy ◽  
Energy Absorption ◽  
Biomass Burning ◽  
Eastern China ◽  
Water Soluble ◽  
Carbonaceous Aerosols ◽  
Southeastern China ◽  
Brown Carbon

Abstract. Biomass burning can significantly impact the chemical and optical properties of carbonaceous aerosols. Here, the biomass burning impacts were studied during wintertime in a megacity of Nanjing, eastern China. The high abundance of biomass burning tracers such as levoglucosan (lev), mannosan (man), galactosan (gal) and non-sea-salt potassium (nss-K+) was found during the studied period with the concentration ranges of 22.4–1476 ng m−3, 2.1–56.2 ng m−3, 1.4–32.2 ng m−3 and 0.2–3.8 µg m−3, respectively. The significant contribution of biomass burning to water-soluble organic carbon (WSOC; 22.3±9.9 %) and organic carbon (OC; 20.9±9.3 %) was observed in this study. Backward air mass origin analysis, potential emission sensitivity of elemental carbon (EC) and MODIS fire spot information indicated that the elevations of the carbonaceous aerosols were due to the transported biomass-burning aerosols from southeastern China. The characteristic mass ratio maps of lev∕man and lev∕nss-K+ suggested that the biomass fuels were mainly crop residuals. Furthermore, the strong correlation (p < 0.01) between biomass burning tracers (such as lev) and light absorption coefficient (babs) for water-soluble brown carbon (BrC) revealed that biomass burning emissions played a significant role in the light-absorption properties of carbonaceous aerosols. The solar energy absorption due to water-soluble brown carbon and EC was estimated by a calculation based on measured light-absorbing parameters and a simulation based on a radiative transfer model (RRTMG_SW). The solar energy absorption of water-soluble BrC in short wavelengths (300–400 nm) was 0.8±0.4 (0.2–2.3) W m−2 (figures in parentheses represent the variation range of each parameter) from the calculation and 1.2±0.5 (0.3–1.9) W m−2 from the RRTMG_SW model. The absorption capacity of water-soluble BrC accounted for about 20 %–30 % of the total absorption of EC aerosols. The solar energy absorption of water-soluble BrC due to biomass burning was estimated as 0.2±0.1 (0.0–0.9) W m−2, considering the biomass burning contribution to carbonaceous aerosols. Potential source contribution function model simulations showed that the solar energy absorption induced by water-soluble BrC and EC aerosols was mostly due to the regionally transported carbonaceous aerosols from source regions such as southeastern China. Our results illustrate the importance of the absorbing water-soluble brown carbon aerosols in trapping additional solar energy in the low-level atmosphere, heating the surface and inhibiting the energy from escaping the atmosphere.

scholarly journals Aerosol–Cloud Closure Study on Cloud Optical Properties using Remotely Piloted Aircraft Measurements during a BACCHUS Field Campaign in Cyprus

2019 ◽  
Author(s):  
Radiance Calmer ◽  
Gregory C. Roberts ◽  
Kevin J. Sanchez ◽  
Jean Sciare ◽  
Karine Sellegri ◽  
...  
Keyword(s):  
Optical Properties ◽  
Solar Radiation ◽  
Shortwave Radiation ◽  
Cloud Base ◽  
Field Campaign ◽  
Aerosol Cloud ◽  
Remotely Piloted Aircraft ◽  
Aerosol Cloud Interactions ◽  
The Impact ◽  
Adiabatic Case

Abstract. In the framework of the EU-FP7 BACCHUS project, an intensive field campaign was performed in Cyprus (2015/03). Remotely Piloted Aircraft System (RPAS), ground-based instruments, and remote-sensing observations were operating in parallel to provide an integrated characterization of aerosol-cloud interactions. Remotely Piloted Aircraft (RPA) were equipped with a 5-hole probe, pyranometers, pressure, temperature and humidity sensors, and measured updraft velocity at cloud base and cloud optical properties of a stratocumulus layer. Ground-based measurements of dry aerosol size distributions and cloud condensation nuclei spectra, and RPA observations of vertical wind velocity and meteorological state parameters are used here to initialize an Aerosol–Cloud Parcel Model (ACPM) and compare the in situ observations of cloud optical properties measured by the RPA to those simulated in the ACPM. Two different cases are studied with the ACPM, including an adiabatic case and an entrainment case, in which the in-cloud temperature profile from RPA is taken into account. Adiabatic ACPM simulation yields cloud droplet number concentrations at cloud base (ca. 400 cm−3) that are similar to those derived from a Hoppel minimum analysis. Cloud optical properties have been inferred using the transmitted fraction of shortwave radiation profile measured by downwelling and upwelling pyranometers mounted on a RPA, and the observed transmitted fraction of solar radiation is then compared to simulations from the ACPM. ACPM simulations and RPA observations show better agreement when associated with entrainment compared to that of an adiabatic case. The mean difference between observed and adiabatic profiles of transmitted fraction of solar radiation is 0.12, while this difference is only 0.03 between observed and entrainment profiles. A sensitivity calculation is then conducted to quantify the relative impacts of two-fold changes in aerosol concentration, and updraft velocity to highlight the importance of accounting for the impact of entrainment in deriving cloud optical properties, as well as the ability of RPAs to leverage ground-based observations for studying aerosol–cloud interactions.

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