Spectral Induced Polarization Signatures of Hydroxide Adsorption and Mineral Precipitation in Porous Media

2012 ◽  
Vol 46 (8) ◽  
pp. 4357-4364 ◽  
Author(s):  
Chi Zhang ◽  
Lee Slater ◽  
George Redden ◽  
Yoshiko Fujita ◽  
Timothy Johnson ◽  
...  
2012 ◽  
Author(s):  
Chi Zhang ◽  
Lee Slater ◽  
George Redden ◽  
Yoshiko Fujita ◽  
Timothy Johnson ◽  
...  

Geophysics ◽  
2012 ◽  
Vol 77 (2) ◽  
pp. E159-E170 ◽  
Author(s):  
John Keery ◽  
Andrew Binley ◽  
Ahmed Elshenawy ◽  
Jeremy Clifford

There is growing interest in the link between electrical polarization and physical properties of geologic porous media. In particular, spectral characteristics may be controlled by the same pore geometric properties that influence fluid permeability of such media. Various models have been proposed to describe the spectral-induced-polarization (SIP) response of permeable rocks, and the links between these models and hydraulic properties have been explored, albeit empirically. Computation of the uncertainties in the parameters of such electrical models is essential for effective use of these relationships. The formulation of an electrical dispersion model in terms of a distribution of relaxation times and associated chargeabilities has been demonstrated to be an effective generalized approach; however, thus far, such an approach has only been considered in a deterministic framework. Here, we formulate a spectral model based on a distribution of polarizations. By using a simple polynomial descriptor of such a distribution, we are able to cast the model in a stochastic manner and solve it using a Markov-chain Monte Carlo (McMC) sampler, thus allowing the computation of model-parameter uncertainties. We apply the model to synthetic data and demonstrate that the stochastic method can provide posterior distributions of model parameters with narrow bounds around the true values when little or no noise is added to the synthetic data, with posterior distributions that broaden with increasing noise. We also apply our model to experimental measurements of six sandstone samples and compare physical properties of a number of samples of porous media with stochastic estimates of characteristic relaxation times. We demonstrate the utility of our method on electrical spectra with different response characteristics and show that a single metric of relaxation time for the SIP response is not sufficient to provide clear insight into the physical characteristics of a sample.


Minerals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 769 ◽  
Author(s):  
Fouzan A. Alfouzan ◽  
Abdulrahman M. Alotaibi ◽  
Leif H. Cox ◽  
Michael S. Zhdanov

The Saudi Arabian Glass Earth Pilot Project is a geophysical exploration program to explore the upper crust of the Kingdom for minerals, groundwater, and geothermal resources as well as strictly academic investigations. The project began with over 8000 km2 of green-field area. Airborne geophysics including electromagnetic (EM), magnetics, and gravity were used to develop several high priority targets for ground follow-up. Based on the results of airborne survey, a spectral induced polarization (SIP) survey was completed over one of the prospective targets. The field data were collected with a distributed array system, which has the potential for strong inductive coupling. This was examined in a synthetic study, and it was determined that with the geometries and conductivities in the field survey, the inductive coupling effect may be visible in the data. In this study, we also confirmed that time domain is vastly superior to frequency domain for avoiding inductive coupling, that measuring decays from 50 ms to 2 s allow discrimination of time constants from 1 ms to 5 s, and the relaxation parameter C is strongly coupled to intrinsic chargeability. We developed a method to fully include all 3D EM effects in the inversion of induced polarization (IP) data. The field SIP data were inverted using the generalized effective-medium theory of induced polarization (GEMTIP) in conjunction with an integral equation-based modeling and inversion methods. These methods can replicate all inductive coupling and EM effects, which removes one significant barrier to inversion of large bandwidth spectral IP data. The results of this inversion were interpreted and compared with results of drill hole set up in the survey area. The drill hole intersected significant mineralization which is currently being further investigated. The project can be considered a technical success, validating the methods and effective-medium inversion technique used for the project.


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