Kinetics and Mechanisms of Heterogeneous Reaction of Gaseous Hydrogen Peroxide on Mineral Oxide Particles

2011 ◽  
Vol 45 (8) ◽  
pp. 3317-3324 ◽  
Author(s):  
Yue Zhao ◽  
Zhongming Chen ◽  
Xiaoli Shen ◽  
Xuan Zhang
2021 ◽  
pp. 149707
Author(s):  
Shideng Yuan ◽  
Shasha Liu ◽  
Xueyu Wang ◽  
Heng Zhang ◽  
Shiling Yuan

2016 ◽  
Vol 57 (4) ◽  
pp. 45-51 ◽  
Author(s):  
Zbigniew Dąbrowiecki ◽  
Małgorzata Dąbrowiecka ◽  
Romuald Olszański ◽  
Piotr Siermontowski

AbstractWhen working in chemical or biological environments, contamination is an extremely dangerous issue for the rescue services of the fire department, police and the army.Modern protective overalls worn by fire fighters or dry “Viking” diving suits made from neoprene or nylon covered with polyurethane, have been proven to ensure sufficient protection. However, once the contaminated area is left, there is a need to perform decontamination of the external and internal surfaces of the protective overalls; in order to ensure the clothing continues to offer a high level of comfort and to retain the durability of said protective clothing, it is of course also necessary to perform a drying procedure.Moreover, there is a risk of a transfer of pathogenic micro-organisms between persons utilising the same protective clothes, particularly in the case of expensive specialist suits. Micro-organisms which may potentially spread through clothing include intestinal bacteria, such as: Salmonella, Shigella, Campylobacter, E. coli (including E. coli O157), C. difficile, viruses inducing infections of the upper respiratory tract and alimentary tract (noraviruses, rotaviruses, adeno and astroviruses). The risk of infection also involves the presence of the flu viruses, herpesviruses and pathogens transferred through skin, such as S. aureus (including MRSA), yeast-like fungi (Candida albicans), fungal strains inducing Tinea pedis and Tinea corporis [1]. Pathogenic micro-organisms can easily transfer from fabric surface onto the body of a person wearing protective clothing.From the numerous available techniques of decontamination of surfaces, equipment and protective clothing we propose to use for this purpose gaseous hydrogen peroxide (H2O2), a very effective biocidal agent. In field conditions, typical for the activities of rescue crews of the fire department, police and army we assume utilisation of a portable decontamination chamber enabling performance of a complete decontamination process.The process lasting approximately 3 hours encompasses 3 phases:• Drying phase;• Decontamination with gaseous hydrogen peroxide;• Catalytic combustion phase of hydrogen peroxide residues to a level safe for the environment.The integrated humidity and H2O2level sensors ensure automatic control of the entire process and the unique distribution system of gaseous H2O2secures full accessibility of the biocidal agent to the external surface of protective clothing as well as its interior. Moreover, the container allows for the conduction of the complete decontamination of the rescue equipment, night vision devices, binoculars, field telephones, radio stations, etc. Upon decontamination cycle completion, we obtain a completely dried suit which can be safely used by another crew member.


1971 ◽  
Vol 24 (6) ◽  
pp. 1193 ◽  
Author(s):  
DR Dixon ◽  
TW Healy

When aqueous ZnO suspensions, saturated with oxygen, are irradiated with u.v. light, hydrogen peroxide is formed and a decrease in pH is observed. The effects of different gases (O2, N2, and N2O) on the course of this heterogeneous reaction and also the pH dependence of the reaction have been examined. On the basis of the results obtained, the mechanism which had been previously suggested was modified to allow for the hydrolysis of the zinc(II) ions removed from the crystal lattice during irradiation. A general reaction mechanism proposed to account for H2O2 production in systems with various additives present is extended to additive-free systems where interstitial zinc (Zn1+) is the effective reductant.


1937 ◽  
Vol 59 (2) ◽  
pp. 422-422 ◽  
Author(s):  
G. B. Kistiakowsky ◽  
S. L. Rosenberg

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