Automatic Baseline Correction by Wavelet Transform for Quantitative Open-Path Fourier Transform Infrared Spectroscopy

2007 ◽  
Vol 41 (20) ◽  
pp. 7054-7059 ◽  
Author(s):  
Limin Shao ◽  
Peter R. Griffiths
Keyword(s):  
Fourier Transform ◽  
Infrared Spectroscopy ◽  
Wavelet Transform ◽  
Fourier Transform Infrared Spectroscopy ◽  
Fourier Transform Infrared ◽  
Baseline Correction ◽  
Open Path

scholarly journals Applying open-path Fourier transform infrared spectroscopy for measuring aerosols

2007 ◽  
Vol 42 (8) ◽  
pp. 1131-1140 ◽  
Author(s):  
Chang-Fu Wu ◽  
Yen-Ling Chen ◽  
Chih-Chieh Chen ◽  
Tzu-Ting Yang ◽  
Pao-Erh Chang
Keyword(s):  
Fourier Transform ◽  
Infrared Spectroscopy ◽  
Fourier Transform Infrared Spectroscopy ◽  
Fourier Transform Infrared ◽  
Open Path

scholarly journals Open-path Fourier transform infrared spectroscopy of SO2: An empirical error budget analysis, with implications for volcano monitoring

2001 ◽  
Vol 106 (D21) ◽  
pp. 27647-27659 ◽  
Author(s):  
Lisa A. Horrocks ◽  
Clive Oppenheimer ◽  
Michael R. Burton ◽  
Hayley J. Duffell ◽  
Nicholas M. Davies ◽  
...  
Keyword(s):  
Fourier Transform ◽  
Infrared Spectroscopy ◽  
Fourier Transform Infrared Spectroscopy ◽  
Fourier Transform Infrared ◽  
Volcano Monitoring ◽  
Error Budget ◽  
Budget Analysis ◽  
Open Path

scholarly journals Application of open-path Fourier transform infrared spectroscopy (OP-FTIR) to measure greenhouse gas concentrations from agricultural fields

2019 ◽  
Vol 12 (6) ◽  
pp. 3403-3415 ◽  
Author(s):  
Cheng-Hsien Lin ◽  
Richard H. Grant ◽  
Albert J. Heber ◽  
Cliff T. Johnston
Keyword(s):  
Fourier Transform ◽  
Infrared Spectroscopy ◽  
Least Squares ◽  
Fourier Transform Infrared Spectroscopy ◽  
Fourier Transform Infrared ◽  
Point Sources ◽  
Ftir Spectra ◽  
Diurnal Changes ◽  
Open Path ◽  
Co2 Concentrations

Abstract. Open-path Fourier transform infrared spectroscopy (OP-FTIR) has often been used to measure hazardous or trace gases from hot point sources (e.g. volcano, industrial, or agricultural facilities) but seldom used to measure greenhouse gases (GHGs) from field-scale sources (e.g. agricultural soils). Closed-path mid-IR laser-based N2O, nondispersive-IR CO2 analysers, and OP-FTIR were used to measure concentrations of N2O and CO2 at a maize cropping system during 9–19 June 2014. To measure N2O and CO2 concentrations accurately, we developed a quantitative method of N2O∕CO2 analysis that minimized interferences from diurnal changes of humidity and temperature. Two chemometric multivariate models, classical least squares (CLS) and partial least squares (PLS), were developed. This study evaluated various methods to generate the single-beam background spectra and different spectral regions for determining N2O and CO2 concentrations from OP-FTIR spectra. A standard extractive method was used to measure the actual path-averaged concentrations along an OP-FTIR optical path in situ, as a benchmark to assess the feasibilities of these quantitative methods. Within an absolute humidity range of 5000–20 000 ppmv and a temperature range of 10–35 ∘C, we found that the CLS model underestimated N2O concentrations (bias =-4.9±3.1 %) calculated from OP-FTIR spectra, and the PLS model improved the accuracy of calculated N2O concentrations (bias =1.4±2.3 %). The bias of calculated CO2 concentrations was -1.0±2.8 % using the CLS model. These methods suggested that environmental variables potentially lead to biases in N2O and CO2 estimations from OP-FTIR spectra and may help OP-FTIR users avoid dependency on extractive methods of calibrations.

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