Three-Component Competitive Adsorption Model for Fixed-Bed and Moving-Bed Granular Activated Carbon Adsorbers. Part II. Model Parameterization and Verification

2006 ◽  
Vol 40 (21) ◽  
pp. 6812-6817 ◽  
Author(s):  
Lance C. Schideman ◽  
Benito J. Mariñas ◽  
Vernon L. Snoeyink ◽  
Carlos Campos
2007 ◽  
Vol 41 (15) ◽  
pp. 3289-3298 ◽  
Author(s):  
Lance C. Schideman ◽  
Vernon L. Snoeyink ◽  
Benito J. Mariñas ◽  
Li Ding ◽  
Carlos Campos

2003 ◽  
Vol 47 (1) ◽  
pp. 113-120 ◽  
Author(s):  
D.S. Chaudhary ◽  
S. Vigneswaran ◽  
V. Jegatheesan ◽  
H.H. Ngo ◽  
H. Moon ◽  
...  

Wastewater treatment has always been a major concern in the developed countries. Over the last few decades, activated carbon adsorption has gained importance as an alternative tertiary wastewater treatment and purification process. In this study, granular activated carbon (GAC) adsorption was evaluated in terms of total organic carbon (TOC) removal from low strength synthetic wastewater. This paper provides details on adsorption experiments conducted on synthetic wastewater to develop suitable adsorption isotherms. Although the inorganics used in the synthetic wastewater solution had an overall unfavourable effect on adsorption of organics, the GAC adsorption system was found to be effective in removing TOC from the wastewater. This study showed that equation of state (EOS) theory was able to fit the adsorption isotherm results more precisely than the most commonly used Freundlich isotherm. Biodegradation of the organics with time was the most crucial and important aspect of the system and it was taken into account in determining the isotherm parameters. Initial organic concentration of the wastewater was the determining factor of the model parameters, and hence the isotherm parameters were determined covering a wide range of initial organic concentrations of the wastewater. As such, the isotherm parameters derived using the EOS theory could predict the batch adsorption and fixed bed adsorption results of the multi-component system successfully. The isotherm parameters showed a significant effect on the determination of the mass transfer coefficients in batch and fixed bed systems.


1986 ◽  
Vol 18 (1) ◽  
pp. 31-42 ◽  
Author(s):  
E. A. Shpirt ◽  
K. T. Alben

The particle size distribution at different bed depths of a fixed bed of granular activated carbon (GAC) has been monitored during 50 weeks of a pilot column run at the Waterford, New York potable water treatment plant. Initial backwashing resulted in significant stratification of GAC in the column: larger particles (average diameter 1.18 mm) settled in the bottom of the column (105 cm), and smaller particles (average diameter 0.97 mm) were concentrated near the top (24 cm), compared to samples of unstratified virgin Calgon F400 (average diameter 1.09 mm). During column loading and initial backwashing, more fines were created than were present in the virgin GAC (average 6.5% of GAC fines in the > 40 mesh fraction, compared to only 0.3% in the > 40 mesh fraction for virgin Calgon F400). After 50 weeks of service there was an overall trend toward a smaller average particle size (0.9 mm) with development of a more regular pattern of bed stratification (1.08 mm at the bottom and 0.75 mm at the top). These changes are attributed to breaking of large particles (12-20 mesh) and creation of intermediate size particles (20-30 and 30-40 mesh).


2019 ◽  
Vol 54 (3) ◽  
pp. 168-178 ◽  
Author(s):  
Jasmina Nikić ◽  
Jasmina Agbaba ◽  
Malcolm A. Watson ◽  
Aleksandra Tubić ◽  
Marko Šolić ◽  
...  

LWT ◽  
2014 ◽  
Vol 59 (2) ◽  
pp. 1025-1032 ◽  
Author(s):  
Anderson Marcos Dias Canteli ◽  
Danielle Carpiné ◽  
Agnes de Paula Scheer ◽  
Marcos R. Mafra ◽  
Luciana Igarashi-Mafra

2011 ◽  
Vol 9 (3) ◽  
pp. 437-445 ◽  
Author(s):  
Marek Šváb ◽  
Kateřina Sukdolová ◽  
Martina Švábová

AbstractCompetitive adsorption of zinc and copper on activated carbon is studied in this article. Main aim was to suggest an advanced model for competitive adsorption of both metals considering pH influence and precipitation. A surface-complexation approach was employed for the modeling. Two models were considered: simple adsorption and ion exchange. System “The Geochemists Workbench” was used for calculation of both static and dynamic adsorption tasks. From the batch experiments, concentration of four types of sorbing sites on the carbon surface and its protonation and sorption constants were deduced. Then, batch competitive adsorption experiments were compared with the models’ results. Finally, a column experiment (fixed bed adsorption) was carried out. It was observed that the model of ion exchange can satisfyingly predict both chromatographic effect and increase of zinc concentration in effluent over its initial value, although a quantitative agreement between the model and the experiment was not totally precise.


2016 ◽  
Vol 18 (1) ◽  
pp. 1
Author(s):  
Md Golam Rasul ◽  
Imtiaz Ahmed ◽  
Md Iqbal Hossain

<p>Tuning the characteristics of granular activated carbon bed (GAC-bed) in household water-filters would be a technique to maintain iron at the required-level in drinking water. In the present study the individual effects of the depth of GAC-bed and the size and porosity of GAC particles on the iron removing capacity are investigated experimentally. A spectrophotometer is used to measure iron-content in water. It is observed that iron removing capacity increases monotonically with the increase in bed-depth regardless of the size of GAC particles. It is also observed that the iron removing capacity decreases drastically with the increase in the size of GAC particles for any fixed bed-depth. Finally the porosity of GAC particles is found to affect the iron removing capacity. The higher the GAC porosity the higher is the iron removing capacity over the considered porosity-range. It is believed that the observations of present study would be useful in adjusting GAC-bed characteristics at the time of designing household water-filters to maintain iron at the required-level.</p><p>Chemical Engineering Research Bulletin 18(2015) 1-5</p>


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