Antimony(III) Binding to Humic Substances:  Influence of pH and Type of Humic Acid

2004 ◽  
Vol 38 (17) ◽  
pp. 4535-4541 ◽  
Author(s):  
Johanna Buschmann ◽  
Laura Sigg
2004 ◽  
Vol 57 (10) ◽  
pp. 931 ◽  
Author(s):  
Amiel Boullemant ◽  
Bernard Vigneault ◽  
Claude Fortin ◽  
Peter G. C. Campbell

We have examined the influence of pH and a natural humic acid on the short-term uptake (<40 min) of a neutral, lipophilic metal complex by a unicellular freshwater alga, Pseudokirchneriella subcapitata. Cadmium diethyldithiocarbamate ([Cd(DDC)2]0) was used as a model lipophilic metal complex and Suwannee River Humic Acid (SRHA) was chosen as a representative aquatic humic acid (6.5 mg C L−1). Under the experimental conditions virtually all the Cd was expected to be present as the lipophilic complex ([Cd]T = 0.38 nM; [DDC] 1 μM; [Cd2+] <10−15 M; pH 7.0, 6.0, or 5.5). Uptake of [Cd(DDC)2]0 proved to be sensitive to pH changes. It was lower at pH 6.0 and 5.5 than at pH 7.0. To our knowledge, this is the first demonstration of reduced uptake of a lipophilic metal complex at low pH. The presence of SRHA also affected uptake, either by binding the lipophilic complex in solution and reducing its bioavailability (pH 7.0) or by increasing the permeability of the algal membrane (pH 5.5).


Molecules ◽  
2021 ◽  
Vol 26 (10) ◽  
pp. 2995
Author(s):  
Laurynas Jarukas ◽  
Liudas Ivanauskas ◽  
Giedre Kasparaviciene ◽  
Juste Baranauskaite ◽  
Mindaugas Marksa ◽  
...  

Black, brown, and light peat and sapropel were analyzed as natural sources of organic and humic substances. These specific substances are applicable in industry, agriculture, the environment, and biomedicine with well-known and novel approaches. Analysis of the organic compounds fulvic acid, humic acid, and humin in different peat and sapropel extracts from Lithuania was performed in this study. The dominant organic compound was bis(tert-butyldimethylsilyl) carbonate, which varied from 6.90% to 25.68% in peat extracts. The highest mass fraction of malonic acid amide was in the sapropel extract; it varied from 12.44% to 26.84%. Significant amounts of acetohydroxamic, lactic, and glycolic acid derivatives were identified in peat and sapropel extracts. Comparing the two extraction methods, it was concluded that active maceration was more efficient than ultrasound extraction in yielding higher amounts of organic compounds. The highest amounts of fulvic acid (1%) and humic acid and humin (15.3%) were determined in pure brown peat samples. This research on humic substances is useful to characterize the peat of different origins, to develop possible aspects of standardization, and to describe potential of the chemical constituents.


2021 ◽  
Author(s):  
Hemlata Bagla ◽  
Asma Khan

&lt;p&gt;Earth&amp;#8217;s regolith consists of a vital component that is lacking on other planets &amp;#173;&amp;#173;&amp;#8211; the pedosphere or soil body &amp;#8211; that is rich in organic matter, soil fauna, minerals, water, gases, that together support life and is thus essential for plant growth. In stark contrast to our blue planet, Martian regolith is devoid of organic matter and contains crushed volcanic rocks, with high mineral content and toxic chemicals like perchlorates. Nevertheless, Martian and Lunar regolith simulants formulated by NASA, have been experimented for crop growth by addition of organic matter suitable to bind xenobiotics and provide ample nutrients, as an essential step towards expanding our horizon in the extensive field of soil sciences.&lt;/p&gt;&lt;p&gt;Soil is an ecosystem as a whole and acts as a modifier of planet Earth&amp;#8217;s atmosphere. The organic matter present in it originates mainly from plant metabolites with the onset of senescence and humification. Humic substances thus formed in the pedosphere exhibit exceptional characteristics for soil conditioning. Besides providing nutrients and aeration to the soil, they interact and bind with toxic heavy metals, radionuclides, pesticides, industrial dyes, and other xenobiotics that may be present as pollutants in the ecosystem, thus acting as natural sieves. As top soils have maximum organic matter, essential for plant growth, phenomenon like soil erosion leave the soils devoid of humic substances. Another major reason for soil degradation is excessive salinity, leading to osmotic and ionic stress in plants, eventually reducing their growth. Addition of humic acid in soils provides protection against high saline stress and minimizes yield losses. In India, one of the leading agrarian countries, it is a common practice to enrich soils with manure, which is an inexpensive form of humus-boost for the crops. Such practices aid the cyclic flow of organic matter in the environment, against the background of widespread soil degradation.&lt;/p&gt;&lt;p&gt;Another global form of soil degradation is radioactive contamination of soils which occurs mainly due to nuclear accidents and improper practices of radioactive waste disposal. In order to explore such interactions with humic acid following Green technique, batch biosorption studies were performed over a range of parameters, with radionuclides Cs and Sr that are found in low level radioactive wastes. Biosorption percentages of 91&amp;#177;2% and 84&amp;#177;1% were obtained for Cs and Sr respectively. The technique is chemical-free and emphasizes the &amp;#8216;nature for nature&amp;#8217; outlook of solving environmental problems. Humic acid and its various forms thus act as traps for radionuclides and work as excellent restorative soil stimulants that supplement depleted soils, boost plant growth, and play a vital role in sustaining life on Earth.&lt;/p&gt;


2004 ◽  
Vol 50 (5) ◽  
pp. 277-283 ◽  
Author(s):  
R. Vinken ◽  
A. Höllrigl-Rosta ◽  
B. Schmidt ◽  
A. Schäffer ◽  
P.F.-X. Corvini

Humic substances are important environmental components since they represent a very large part of organic compounds on earth. According to many reports, dissolved humic substances are a determinant parameter for the bioavailability of xenobiotic compounds. For the present bioavailability studies, two kinds of dissolved humic substances, a commercially available humic acid and fulvic acids isolated from peat were used. As the relevant xenobiotic, a defined branched nonylphenol isomer, 4(3′,5′-dimethyl-3′-heptyl)-phenol (p353NP) was synthesised according to Friedel-Crafts alkylation. Equilibrium dialysis studies were implemented in order to investigate the association between 14C-labelled p353NP and dissolved humic substances. The biodegradability in the presence of dissolved humic substances was examined in experiments with the nonylphenol degrading bacterium strain Sphingomonas TTNP3 and with p353NP as sole carbon source. The results showed that p353NP-humic acid associates were formed in high amounts, whereas no adducts with fulvic acids occurred. In the degradation studies with Sphingomonas TTNP3, no effects of dissolved humic substances on the bioavailability of p353NP could be observed. It was assumed that the association between nonylphenol and humic acids occurs rapidly and is reversible. Thus, the formation of "labile" complexes did not influence biodegradation rates, which were quite low.


2021 ◽  
Author(s):  
Milanka Radulovic ◽  
◽  
Svetlana Mitrovski

Peat is a natural substrate for growth of microorganisms because it is rich in compounds that microorganisms can use as sources of carbon, nitrogen and growth factors. Peat originating from Vlasina lake in Eastern Serbia is especially rich in organic matter. The content of humic substances (humic acid, fulvic acid and humine) is almost twice that found in other peat-rich regions of similar origin and geochemical age. Humic and fluvic acids are known to promote microbial growth. In this work, humic and fulvic acids were first extracted from Vlasina lake peat and then added to minimal medium (synthetic, low ionic strength medium). The humic substances were added separately and combined in a 1:1 ratio by mass to study their individual and combined effect on microbial growth of Escherichia coli ATCC 25922 (Gr–), Staphyloccocus aureus (Gr+) i Aureobasidium pullulans, strain CH-1. The microbial growth was measured microspectrophotometrically over a 24-hour period and growth curves were obtained for a range of acid concentrations between 25 µg cm-3 and 100 µg cm-3. It was found that both humic and fulvic acids promote the growth of all three microorganisms by up to a maximum of 40%-80% the extent of which varied with the concentration of the acid and the identity of the microorganism. In general, humic acid was found to result in higher microbial growth (at highest concentrations, up to ~80% for all three microbial species).


2017 ◽  
Vol 30 (1) ◽  
pp. 149-154 ◽  
Author(s):  
LENNIS AFRAIRE RODRIGUES ◽  
◽  
CHARLINE ZARATIN ALVES ◽  
CARLOS HENRIQUE QUEIROZ REGO ◽  
TIAGO ROQUE BENETOLI DA SILVA ◽  
...  

ABSTRACT The development of technologies to increase stand establishment efficiency and seed vigor, as well as to maximize profits, is of fundamental importance for the sustainability of agriculture. Products based on humic substances, such as humic acids, have been recently used in Brazilian agriculture to produce seedlings with high vigor, which positively influences the establishment of the initial stand. Thus, this study aimed to evaluate the effect of treatment of corn seeds with a commercial humic acid-based product, Humykos® (18% of humic acid content), on germination and seedling vigor. The treatments consisted of six doses (0, 100, 200, 300, 400, and 500 mL 100 kg-1 seed) of Humykos®, and the treated seeds were analyzed for germination and vigor (first count, emergence, emergence speed index, length, and dry mass of shoots and roots). Our results show that humic acid promotes greater seedling growth and increased shoot dry mass in corn; in addition, it has a positive influence on the emergence speed index up to a dose 158 mL 100 kg -1 seeds.


2018 ◽  
Vol 316 (3) ◽  
pp. 981-991 ◽  
Author(s):  
Liqiang Tan ◽  
Xiaoli Tan ◽  
Xuemei Ren ◽  
Huiyang Mei ◽  
Xiangke Wang

2004 ◽  
Vol 92 (9-11) ◽  
Author(s):  
Tadao Tanaka ◽  
Y. Sakamoto ◽  
M. Mukai ◽  
T. Maeda ◽  
S. Nakayama

SummaryColumn experiments were performed to study effects of humic acid on the mobility of


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