Fluctuations of Dissolved Organic Matter in River Used for Drinking Water and Impacts on Conventional Treatment Plant Performance

2005 ◽  
Vol 39 (11) ◽  
pp. 4258-4264 ◽  
Author(s):  
Christian Volk ◽  
Louis A. Kaplan ◽  
Jeff Robinson ◽  
Bruce Johnson ◽  
Larry Wood ◽  
...  
2013 ◽  
Vol 13 (1) ◽  
pp. 89-95 ◽  
Author(s):  
I. Jo ◽  
S. Echigo ◽  
S. Itoh

A comprehensive fractionation technique was applied to a set of water samples obtained along a real drinking water treatment plant with ozonation and granular activated carbon (GAC) treatment to obtain detailed profiles of dissolved organic matter (DOM) and to evaluate the haloacetic acid (HAA) formation potentials of these DOM fractions. The results indicated that ozonation and GAC treatment showed limited ability to remove hydrophilic fractions (23%), while removal of hydrophobic fractions was 72%. The contribution of hydrophilic fractions to HAA formation increased from 30 to 61% along the treatment train because of better removal for hydrophobic fractions both in concentration and reactivity. Similar trends were also found for trihalomethanes.


2013 ◽  
Vol 5 (3) ◽  
pp. 177-184

A pilot-plant study was carried out with the water supply to Athens water works filtered through a granular activated carbon (GAC) filter- adsorber. The objective of this study was to evaluate the performance of GAC for the removal from drinking water of the two main groups of disinfection by -products (DBPs), trihalomethanes (THMs) and haloacetic acids (HAAs), as well as of dissolved organic matter. The pilot treatment facility is located at the Water Treatment Plant of EYDAP in Galatsi, Athens, and was operated as a rapid gravity filter - adsorber. It was fed with chlorinated water, coming from the overflow of the sedimentation tanks, and operated continuously in parallel with a full-scale sand filter. At regular time intervals water samples were taken from both filters and analysed for THMs, HAAs and DOC. Other parameters were measured too. The operation of the GAC filter-adsorber continued until the GAC adsorption capacity for THMs and HAAs was almost exhausted. The results of the analyses showed that GAC was more effective in removing the dissolved organic matter than the smaller molecules of THMs and HAAs, fact which is in agreement with the relevant literature. GAC was also proved more effective in removing HAAs than removing THMs. The removal of THMs and the most part of the removal of HAAs and DOC must be attributed to adsorption by GAC, while that of a smaller part of DOC and HAAs may be attributed to biological activity in the filter bed, where chlorine had been totally removed by the catalytic action of the activated carbon surface.


2019 ◽  
Vol 19 (7) ◽  
pp. 2098-2106
Author(s):  
Chelsea W. Neil ◽  
Yingying Zhao ◽  
Amy Zhao ◽  
Jill Neal ◽  
Maria Meyer ◽  
...  

Abstract Source water quality can significantly impact the efficacy of water treatment unit processes and the formation of chlorinated and brominated trihalomethanes (THMs). Current water treatment plant performance models may not accurately capture how source water quality variations, such as organic matter variability, can impact treatment unit processes. To investigate these impacts, a field study was conducted wherein water samples were collected along the treatment train for 72 hours during a storm event. Systematic sampling and detailed analyses of water quality parameters, including non-purgeable organic carbon (NPOC), UV absorbance, and THM concentrations, as well as chlorine spiking experiments, reveal how the THM formation potential changes in response to treatment unit processes. Results show that the NPOC remaining after treatment has an increased reactivity towards forming THMs, and that brominated THMs form more readily than chlorinated counterparts in a competitive reaction. Thus both the reactivity and quantity of THM precursors must be considered to maintain compliance with drinking water standards, a finding that should be incorporated into the development of model-assisted treatment operation and optimization. Advanced granular activated carbon (GAC) treatment beyond conventional coagulation–flocculation–sedimentation processes may also be necessary to remove the surge loading of THM-formation precursors during a storm event.


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