Voltammetric methods for distinguishing between dissolved and particulate metal ion concentrations in the presence of hydrous oxides. A case study on lead(II)

1985 ◽  
Vol 19 (2) ◽  
pp. 141-146 ◽  
Author(s):  
Maria de Lurdes Simoes. Goncalves ◽  
Laura. Sigg ◽  
Werner. Stumm
Keyword(s):  
Metal Ion ◽  
Ion Concentrations ◽  
Hydrous Oxides ◽  
Particulate Metal ◽  
Voltammetric Methods

Prediction of Soluble Nickel Removal by Activated Sludge Using Free Metal Ion Concentrations

1987 ◽  
Vol 19 (3-4) ◽  
pp. 439-448 ◽  
Author(s):  
Jeppe S. Nielsen ◽  
Steve E. Hrudey ◽  
Frederick F. Cantwell
Keyword(s):  
Activated Sludge ◽  
Metal Ion ◽  
Municipal Sewage ◽  
Nickel Ion ◽  
Ion Concentrations ◽  
Untreated Sewage ◽  
Nickel Uptake ◽  
Nickel Removal ◽  
Free Metal ◽  
Free Metal Ion

Batch isotherm studies using spiked sewage samples containing a range of total soluble nickel concentrations typical of municipal sewage strongly suggested that it is the free (i.e. uncomplexed) nickel ion that is sorbed by activated sludge. Equations relating nickel uptake by activated sludge to free nickel ion concentrations and the extent of complexation in untreated sewage were developed and applied. Predicted and measured nickel removals generally agreed to within ± 30%.

Ligand Influence Versus Electronic Configuration of d-metal Ion in Determining the Fate of NIR Emission from LnIII Ions: A Case Study with CuII, NiII and ZnII Complexes.

2021 ◽  
Author(s):  
Abhineet Verma ◽  
Sk Saddam Hossain ◽  
Sailaja S Sunkari ◽  
Joseph Reibenspies ◽  
Satyen Saha
Keyword(s):  
Metal Ion ◽  
Selection Rule ◽  
Near Infrared ◽  
Electronic Configuration ◽  
Infrared Region ◽  
Direct Excitation ◽  
Characteristic Emission ◽  
Nir Emission ◽  
Near Infrared Region

Lanthanides (LnIII) are well known for their characteristic emission in the Near-Infrared Region (NIR). However, direct excitation of lanthanides is not feasible as described by Laporte’s parity selection rule. Here,...

scholarly journals Uncommon biphasic behaviour induced by very high metal ion concentrations in HCl/H2O/[P44414]Cl and HCl/H2O/PEG-600 systems

2020 ◽  
Vol 22 (40) ◽  
pp. 23226-23236
Author(s):  
Eris Sinoimeri ◽  
Victor Maia Fernandes ◽  
Jérôme Cognard ◽  
Jorge Fernando Brandão Pereira ◽  
Lenka Svecova ◽  
...  
Keyword(s):  
Metal Ion ◽  
Ion Concentrations ◽  
System P ◽  
High Metal ◽  
Very High ◽  
Peg 600

Large amounts of Fe(iii) or Fe(ii) strongly modify the biphasic behavior of the system P44414Cl/HCl/H2O while large amounts of Fe(iii) induce a biphasic regime for the mixture PEG-600/HCl/H2O.

scholarly journals Pre-treatment of desalination feed seawater by Jordanian Tripoli, Pozzolana, and Feldspar: Batch experiments

2011 ◽  
Vol 17 (2) ◽  
pp. 163-171 ◽  
Author(s):  
Aiman Al-Rawajfeh ◽  
Khaldoon Al-Whoosh ◽  
Dwairi Al ◽  
Ahmad Al-Maaberah ◽  
Amer Tarawneh
Keyword(s):  
Layered Double Hydroxide ◽  
Metal Ion ◽  
Raw Materials ◽  
Batch Experiments ◽  
Initial Concentration ◽  
Considerable Potential ◽  
Ion Concentrations ◽  
Pre Treatment ◽  
Co Precipitation ◽  
Double Hydroxide

In this research, composites of layered double hydroxide (LDH) with three Jordanian natural raw materials; Tripoli (T), Pozzolana (P) and Feldspar (F) were prepared by co-precipitation and have been used for feed seawater pre-treatment. The data reveals that percent adsorption decreased with increase in initial concentration, but the actual amount of adsorbed ions per unit mass of LDH/T-P-F increased with increase in metal ion concentrations. The values of ?Go were negative and within 21 to 26 KJ/mol, while the values of ?Ho and ?So were positive and within the range of 0.1 to 25 KJ/mol. The values of ?H?, ?S?, and ?G? indicate the favorability of physisorption and show that the LDH/T-P-F composites have a considerable potential as adsorbents for the removal of ions from seawater.

scholarly journals Voltammetric Methods in Metallothionein Research

2005 ◽  
Vol 3 (1-2) ◽  
pp. 43-53 ◽  
Author(s):  
Ivana Šestáková ◽  
Tomáš Navrátil
Keyword(s):  
Metal Ion ◽  
Composite Electrode ◽  
Differential Pulse ◽  
Carbon Composite ◽  
Ion Transfer ◽  
Adsorbed State ◽  
Carbon Composite Electrode ◽  
Pulse Voltammetry ◽  
Voltammetric Methods

The application of voltammetric methods using different rates of polarisation on HMDE reveal inert or labile behaviour of Cd- or Zn- complexes in the presence of excessive cadmium or zinc ions in solution. This phenomenon was demonstrated first on the simplest phytochelatin – complex of peptide(γ-Glu-Cys)2Glywith cadmium, later on rabbit liver metallothioneins –Cd7MTin the presence of cadmium andCd5Zn2MTin the presence of zinc. Voltammetric methods can distinguish between labile and inert complexes present simultaneously and therefore could elucidate their role in reactions of metal ion transfer.Another method using different rates of polarisation – elimination voltammetry with linear scan – proved that S-tetracoordinated complexes of Cd(II) or Zn(II) in the above-mentioned metallothioneins on HMDE are reduced in the adsorbed state. This implies the possibility of increasing the sensitivity of identification or determination of the above complexes. On carbon composite electrode, similar behaviour of Cd-complexes as on HMDE was observed using differential pulse voltammetry.

Influence of implant design on blood metal ion concentrations in metal-on-metal total hip replacement patients

2015 ◽  
Vol 39 (9) ◽  
pp. 1803-1811 ◽  
Author(s):  
Gulraj S. Matharu ◽  
Fiona Berryman ◽  
Lesley Brash ◽  
Paul B. Pynsent ◽  
Ronan B. Treacy ◽  
...  
Keyword(s):  
Total Hip Replacement ◽  
Hip Replacement ◽  
Metal Ion ◽  
Implant Design ◽  
Ion Concentrations ◽  
Total Hip ◽  
Metal On Metal

scholarly journals Utilization of Waste Leaves Biomass of Myrica Esculenta for the Removal of Pb (II), Cd (II) and Zn (II) Ions from Waste Waters

2018 ◽  
Vol 34 (5) ◽  
pp. 2548-2553 ◽  
Author(s):  
Naveen Chandra Joshi ◽  
Ajay Singh ◽  
Himanshu Rajput
Keyword(s):  
Contact Time ◽  
Metal Ion ◽  
Isotherm Models ◽  
Waste Waters ◽  
Ion Concentrations ◽  
Batch System ◽  
Langmuir Isotherm Model ◽  
Myrica Esculenta ◽  
Optimized Conditions ◽  
Maximum Removal

In the present study, we have used the waste leaves of Myrica esculenta for the removal of Pb2+, Cd2+ and Zn2+ ions from the synthetically prepared waste water. The adsorption based removal process has been carried out under the batch system. The batch system was included pH, contact time, dosage, concentration and temperature. The maximum removal efficiency was achieved at optimized conditions i.e. higher contact time, higher pH, lower metal ion concentrations and moderate temperatures. The presence of various organic binding groups was characterized by FTIR spectroscopy. The percentage adsorption of Pb2+, Cd2+ and Zn2+ ions was found 97.02%, 92.52% and 81.99% at pH 6 after contact time 25 minutes. The data of adsorption were tested with Langmuir, Freundlich and Temkin isotherm models. The adsorption capacity of Pb2+, Cd2+ and Zn2+ ions was evaluated as 8.264, 5.617 and 7.751mgg-1 by Langmuir isotherm model.

Do Hardened Femoral Heads Reduce Blood Metal Ion Concentrations after Hip Resurfacing?

2014 ◽  
Vol 24 (4) ◽  
pp. 327-332 ◽  
Author(s):  
Michel J. Le Duff ◽  
Alicia J. Johnson ◽  
Harlan C. Amstutz
Keyword(s):  
Metal Ion ◽  
Hip Resurfacing ◽  
Ion Concentrations ◽  
Femoral Heads
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