Thermal Stability of Jet-Fuel/Paraffin Blends

1996 ◽  
Vol 10 (6) ◽  
pp. 1176-1180 ◽  
Author(s):  
Lori M. Balster ◽  
Walter J. Balster ◽  
E. Grant Jones
Author(s):  
Gordon L. Dieterle ◽  
Kenneth E. Binns

A single-pass, dual heat exchanger system called the Extended Duration Thermal Stability Test (EDTST) system was developed for evaluating jet fuel thermal stability. Various JP-8 fuels and thermal stability additives have been evaluated in the system. The test results indicate that additives can substantially improve the thermal stability of conventional jet fuels. Relationships of bulk and wetted wall temperatures on coking deposits that form in heated tubes have also been evaluated. To date, tests conducted with EDTST have verified that additives can improve the thermal stability of JP-8 fuels. The goal of operating at wetted wall temperatures of 260°C (500°F) has been achieved. The goal for bulk fuel temperatures of 218°C (425°F) with no deposits has not been achieved. Additional additive candidates are to be evaluated in the EDTST system to identify additives that meet both the wetted wall and bulk fuel temperature goals of this program. However, if the bulk temperature goal cannot be totally achieved, the JP-8 fuel specification will most probably be changed to take advantage of the wetted wall temperature improvement already demonstrated by a JP-8+100 additive candidate.


1989 ◽  
Author(s):  
Semih Eser ◽  
J. Perison ◽  
R. M. Copenhaver ◽  
H. H. Schobert

1989 ◽  
Author(s):  
S. Eser ◽  
J. Perison ◽  
R. Copenhaver ◽  
H. Schobert

Author(s):  
David W. Naegeli

The autoxidation of Jet A, dodecane, and a dodecane-15%-cumene blend doped with sulfur compounds were studied at 433 K. Oxygen, hydro peroxide and soluble gum were monitored during the autoxidation. Dodecane, cumene, and the dodecane-15%-cumene blend autoxidized rapidly, while Jet A had an induction period followed by a relatively slow post autoxidation. The results suggest that an inhibitor formed early in the post autoxidation of Jet A. Gum formed in the autoxidation of Jet A, whereas none was detected in dodecane, cumene, or dodecane-15% cumene. However, gum was detected in dodecane and dodecane-15% cumene doped with thiols and disulfides. Alkyl thiols and disulfides reduced the rate of autoxidation of dodecane, and there was an induction period in the formation of gum. Traces of sulfur (≈4 ppm) inhibited the autoxidation of dodecane-15% cumene in a way that resembled the post autoxidation of Jet A. Adding an organic base increased the rate of post autoxidation in Jet A and prevented formation of the oxidation inhibitor. An inhibition mechanism is proposed in which phenois are formed via acid-catalyzed decomposition of benzylic hydro peroxides.


Author(s):  
Leigh Nash ◽  
Jennifer Klettlinger ◽  
Subith Vasu

Thermal stability is an important characteristic of alternative fuels that must be evaluated before they can be used in aviation engines. This characteristic is of great importance to the effectiveness of the fuel as a coolant and to the engine’s combustion performance. In this work, the thermal stability of Gevo fuel, an alcohol to jet fuel made from plant derived feedstock, was studied. This analysis was used to comment on the effectiveness of the current thermal stability test standard. This work was performed using a spectroscopic ellipsometer to measure the thickness of deposits left on aluminum substrates. It was observed that Gevo deposit thickness increased slowly up to 375 °C and much more rapidly after that point. Similar behavior was observed in JP-8 fuel. Comparisons were also made between color standard ratings and ellipsometric thickness measurements, and it was found that in some cases, darker colors did not indicate thicker deposits. Reference tubes were used to validate the optical models used in this work, and different optical constants were found to best model the results than what are published in the ASTM D3241 test method for thermal stability.


1989 ◽  
Author(s):  
S. Eser ◽  
J. Perison ◽  
R. Copenhaver ◽  
H. Schobert

Author(s):  
Jennifer Lindsey Suder Klettlinger

Fischer-Tropsch (F-T) jet fuel composition differs from petroleum-based, conventional commercial jet fuel because of differences in feedstock and production methodology. Fischer-Tropsch fuel typically has a lower aromatic and sulfur content and consists primarily of iso and normal parafins. The ASTM D3241 specification for Jet Fuel Thermal Oxidation Test (JFTOT) break point testing method was used to test the breakpoint of a baseline commercial grade F-T jet fuel, and various blends of this F-T fuel with an aromatic solution. The goal of this research is to determine the effect of aromatic content on the thermal stability of Fischer-Tropsch fuel. The testing completed in this report was supported by the NASA Fundamental Aeronautics Subsonics Fixed Wing Project.


1988 ◽  
Vol 27 (8) ◽  
pp. 1524-1528 ◽  
Author(s):  
Robert E. Morris ◽  
Robert N. Hazlett ◽  
C. Linden McIlvaine

Author(s):  
Shiro Fujishiro ◽  
Harold L. Gegel

Ordered-alpha titanium alloys having a DO19 type structure have good potential for high temperature (600°C) applications, due to the thermal stability of the ordered phase and the inherent resistance to recrystallization of these alloys. Five different Ti-Al-Ga alloys consisting of equal atomic percents of aluminum and gallium solute additions up to the stoichiometric composition, Ti3(Al, Ga), were used to study the growth kinetics of the ordered phase and the nature of its interface.The alloys were homogenized in the beta region in a vacuum of about 5×10-7 torr, furnace cooled; reheated in air to 50°C below the alpha transus for hot working. The alloys were subsequently acid cleaned, annealed in vacuo, and cold rolled to about. 050 inch prior to additional homogenization


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