Demulsification of Oleic-Acid-Coated Magnetite Nanoparticles for Cyclohexane-in-Water Nanoemulsions

2014 ◽  
Vol 28 (9) ◽  
pp. 6172-6178 ◽  
Author(s):  
Jiling Liang ◽  
Haiping Li ◽  
Jingen Yan ◽  
Wanguo Hou
2019 ◽  
Vol 35 (2) ◽  
pp. 516-522 ◽  
Author(s):  
Jittaya Sadchaiyaphum ◽  
Pongsathon Phapugrangkul ◽  
Preeyporn Chaiyasat ◽  
Amorn Chaiyasat

High encapsulation efficiency of magnetite nanoparticles (MNPs; Fe3O4) in microcapsules using PDVB as a hydrophobic polymer shell was successfully achieved by microsuspension conventional radical polymerization (ms CRP). MNPs were initially synthesized by co-precipitation of Fe2+/Fe3+ in a binary phase. During the nucleation of MNPs in alkaline aqueous solution existing oleic acid (OA), MNPs were coated with OA (MNPs-OA) before moving to the toluene phase with the addition of salt. At OA concentration of 0.3 wt%, most of the nucleated MNPs were hydrophobic and well dispersed in the toluene phase. Using DVB as a monomer for ms CRP, high encapsulation efficiency (92 %EE) of MNPs-OA was obtained, with low free polymer particle formation. By contrast, large amounts of free polymer particles were observed at low %EE (32%) of MNPs. The main driving force for high %EE was obtained by coating the surface of the MNPs by OA which increased hydrophobicity.


2019 ◽  
Vol 1 (2) ◽  
Author(s):  
Eupídio Scopel ◽  
Patrick Pires Conti ◽  
Daniel Grando Stroppa ◽  
Cleocir José Dalmaschio

2018 ◽  
Vol 25 (35) ◽  
pp. 35672-35681
Author(s):  
Hector Aguilar Vitorino ◽  
Priscila Ortega ◽  
Roxana Y. Pastrana Alta ◽  
Flavia Pinheiro Zanotto ◽  
Breno Pannia Espósito

2010 ◽  
Vol 25 (5) ◽  
pp. 810-813 ◽  
Author(s):  
Ling Li ◽  
Jun Ding ◽  
Junmin Xue

The synthesis of monodisperse magnetite nanoparticles (Fe3O4 NPs) has been widely investigated over the last decade. Among the various synthetic methods, thermal decomposition of iron acetylacetonate, Fe(acac)3, or the premade iron-surfactant complex, was demonstrated to be promising to obtain monodisperse Fe3O4 NPs with controllable size and morphology. However, toxic and expensive precursors or tedious experimental procedures are normally required in these approaches. In this communication, we report a facile chemical top-down method to synthesize monodisperse magnetite NPs by using rust, which is mainly composed of γ-Fe2O3, as the iron source and oleic acid as the capping agent. The particle size, and hence the magnetization, of NPs can be readily controlled by adjusting the rust/oleic acid ratio and reaction temperature. This process is a green chemical approach and is easy to be reproduced and scaled up, which could be developed as an effective way to convert waste materials into high quality nanocrystals.


2006 ◽  
Vol 253 (5) ◽  
pp. 2611-2617 ◽  
Author(s):  
Ling Zhang ◽  
Rong He ◽  
Hong-Chen Gu

2015 ◽  
Vol 2015 ◽  
pp. 1-8 ◽  
Author(s):  
Gayan Priyadarshana ◽  
Nilwala Kottegoda ◽  
Atula Senaratne ◽  
Ajith de Alwis ◽  
Veranja Karunaratne

This study attempts to synthesize magnetite nanoparticles from a high purity natural iron oxide ore found in Panvila, Sri Lanka, following a novel top-down approach. Powder X-Ray diffraction, elemental analysis, and chemical analysis data confirmed the ore to be exclusively magnetite with Fe2+ : Fe3+ratio of 1 : 2. Surface modified magnetite nanoparticles were synthesized by destructuring of this ore using a top-down approach in the presence of oleic acid. These oleic acid coated nanoparticles were further dispersed in ethanol resulting in stable nanomagnetite dispersion. Interestingly, the nanoparticles demonstrated a spherical morphology with a particle size ranging from 20 to 50 nm. Magnetic force microscopic data was used to confirm the topography of the nanoparticles and to study the magnetic domain structure.


PROTEOMICS ◽  
2011 ◽  
Vol 11 (5) ◽  
pp. 890-897 ◽  
Author(s):  
Hemei Chen ◽  
Shasha Liu ◽  
Yan Li ◽  
Chunhui Deng ◽  
Xiangmin Zhang ◽  
...  

2015 ◽  
Vol 6 ◽  
Author(s):  
Teixeira Joao ◽  
Laffon Blanca ◽  
Kiliç Gözde ◽  
Fernández-Bertólez Natalia ◽  
Costa Carla ◽  
...  

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