Effect of Composition on the Structure and Catalytic Properties of KF/Mg–La Solid Base Catalysts for Biodiesel Synthesis via Transesterification of Cottonseed Oil

2011 ◽  
Vol 25 (6) ◽  
pp. 2679-2686 ◽  
Author(s):  
Ruili Song ◽  
Dongmei Tong ◽  
Jinqiang Tang ◽  
Changwei Hu
Keyword(s):  
Catalytic Properties ◽  
Cottonseed Oil ◽  
Solid Base ◽  
Solid Base Catalysts ◽  
Base Catalysts ◽  
Biodiesel Synthesis

scholarly journals Environmentally Benign Neem Biodiesel Synthesis Using Nano-Zn-Mg-Al Hydrotalcite as Solid Base Catalysts

2014 ◽  
Vol 2014 ◽  
pp. 1-6 ◽  
Author(s):  
Karthikeyan Chelladurai ◽  
Manivannan Rajamanickam
Keyword(s):  
Methyl Esters ◽  
Catalytic Performance ◽  
Environmentally Benign ◽  
Bet Surface Area ◽  
Molar Ratio ◽  
Solid Base ◽  
Synthetic Compound ◽  
Solid Base Catalysts ◽  
Base Catalysts ◽  
Biodiesel Synthesis

Hydrotalcite, also known as aluminum-magnesium layered double hydroxide (LDH) or anionic clay, is a synthetic compound that was broadly investigated in the past decade due to its many potential applications. In this work, we present an environmentally benign process for the transesterification (methanolysis) of neem oil to fatty acid methyl esters (FAME) using Zn-Mg-Al hydrotalcites as solid base catalysts in a heterogeneous manner. The catalysts were characterized by XRD, FT-IR, TPD-CO2, and the BET surface area analysis. It is well-known that the catalytic performance of hydrotalcite is dramatically increased through the incorporation of Zn into the surface of Mg-Al hydrotalcite material. The optimized parameters, 10 : 1 methanol/oil molar ratio with 7.5 g catalysts reacted under stirring speed 450 rpm at 65°C for 4 h reaction, gave a maximum ester conversion of 90.5% for the sample with Zn-Mg-Al ratio of 3 : 3 : 1.

Mesopolymer solid base catalysts with variable basicity: preparation and catalytic properties

2009 ◽  
Vol 19 (23) ◽  
pp. 4004 ◽  
Author(s):  
Rong Xing ◽  
Haihong Wu ◽  
Xiaohong Li ◽  
Zhonglin Zhao ◽  
Yueming Liu ◽  
...  
Keyword(s):  
Catalytic Properties ◽  
Solid Base ◽  
Solid Base Catalysts ◽  
Base Catalysts ◽  
Variable Basicity

Self-condensation of propanol over solid-base catalysts

2004 ◽  
Vol 275 (1-2) ◽  
pp. 103-110 ◽  
Author(s):  
A.S. Ndou ◽  
N.J. Coville
Keyword(s):  
Solid Base ◽  
Solid Base Catalysts ◽  
Base Catalysts

Solid base catalysts obtained from hydrotalcite precursors, for Knoevenagel synthesis of cinamic acid and coumarin derivatives

2006 ◽  
Vol 308 ◽  
pp. 13-18 ◽  
Author(s):  
E. Angelescu ◽  
O.D. Pavel ◽  
R. Bîrjega ◽  
R. Zăvoianu ◽  
G. Costentin ◽  
...  
Keyword(s):  
Solid Base ◽  
Coumarin Derivatives ◽  
Solid Base Catalysts ◽  
Base Catalysts

scholarly journals Nitrogen-containing carbon nanotubes as solid base catalysts

2006 ◽  
pp. 4859 ◽  
Author(s):  
Stefan van Dommele ◽  
Krijn P. de Jong ◽  
Johannes H. Bitter
Keyword(s):  
Carbon Nanotubes ◽  
Solid Base ◽  
Solid Base Catalysts ◽  
Base Catalysts

Amine-functionalized MgAl LDH nanosheets as efficient solid base catalysts for Knoevenagel condensation

2018 ◽  
Vol 449 ◽  
pp. 31-37 ◽  
Author(s):  
Huanhuan Jia ◽  
Yuan Zhao ◽  
Panpan Niu ◽  
Ningyue Lu ◽  
Binbin Fan ◽  
...  
Keyword(s):  
Knoevenagel Condensation ◽  
Solid Base ◽  
Solid Base Catalysts ◽  
Base Catalysts ◽  
Amine Functionalized
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