Oxidation kinetics of carbon monoxide in supercritical water

1987 ◽  
Vol 1 (5) ◽  
pp. 417-423 ◽  
Author(s):  
Richard K. Helling ◽  
Jefferson W. Tester
Keyword(s):  
Carbon Monoxide ◽  
Supercritical Water ◽  
Oxidation Kinetics ◽  
Kinetics Of

Oxidation Kinetics of Model Compounds of Metabolic Waste in Supercritical Water

1990 ◽  
Author(s):  
Paul A. Webley ◽  
Henry R. Holgate ◽  
David M. Stevenson ◽  
Jefferson W. Tester
Keyword(s):  
Supercritical Water ◽  
Oxidation Kinetics ◽  
Model Compounds ◽  
Kinetics Of

The effect of carbon monoxide on the oxidation of propane over a glass fiber based platinum catalyst

2021 ◽  
Vol 1 (1-2) ◽  
pp. 41-46
Author(s):  
E. V. Kovalyov ◽  
E. M. Sadovskaya ◽  
V. V. Aver’yanova ◽  
B. S. Bal’zhinimaev
Keyword(s):  
Carbon Monoxide ◽  
Glass Fiber ◽  
Oxidation Kinetics ◽  
Active Sites ◽  
Detrimental Effect ◽  
Competitive Adsorption ◽  
Platinum Catalyst ◽  
Deep Oxidation ◽  
Oxidation Of Hydrocarbons ◽  
Kinetics Of

Deep oxidation of hydrocarbons over platinum catalysts underlies the majority of processes for purification of industrial waste gases. Since waste gases usually contain carbon monoxide, it is important to investigate its effect on the oxidation kinetics of hydrocarbons. This paper considers results of the study on the oxidation kinetics of propane over a glass fiber platinum catalyst in the presence or absence of CO in the reaction mixture. It was found that at low temperatures the presence of CO strongly hinders the oxidation of propane, whereas upon temperature elevation this detrimental effect is replaced by the beneficial effect of CO. As shown by numerical modeling, this bidirectional effect can be attributed to the competitive adsorption of oxygen, propane and CO on the catalyst active sites.

Impact Of Synthesis Route on the Water Oxidation Kinetics of Hematite Photoanodes

2020 ◽  
Author(s):  
Camilo A. Mesa ◽  
Ludmilla Steier ◽  
Benjamin Moss ◽  
Laia Francàs ◽  
James E. Thorne ◽  
...  
Keyword(s):  
Oxygen Vacancy ◽  
Reaction Kinetics ◽  
Water Oxidation ◽  
Oxidation Kinetics ◽  
Oxidation Reaction ◽  
Charge Accumulation ◽  
Optical Signals ◽  
Current Voltage ◽  
Voltage Performance ◽  
Kinetics Of

<p><i>Operando</i> spectroelectrochemical analysis is used to determine the water oxidation reaction kinetics for hematite photoanodes prepared using four different synthetic procedures. Whilst these photoanodes exhibit very different current / voltage performance, their underlying water oxidation kinetics are found to be almost invariant. Lower photoanode performance was found to correlate with the observation of optical signals indicative of charge accumulation in mid-gap oxygen vacancy states, indicating these states do not contribute directly to water oxidation.</p>

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