Preparation, Characterization, and Postsynthetic Modification of Metal−Organic Frameworks: Synthetic Experiments for an Undergraduate Laboratory Course in Inorganic Chemistry

2011 ◽  
Vol 88 (1) ◽  
pp. 92-94 ◽  
Author(s):  
Kenji Sumida ◽  
John Arnold
Keyword(s):  
Inorganic Chemistry ◽  
Metal Organic Frameworks ◽  
Laboratory Course ◽  
Postsynthetic Modification ◽  
Undergraduate Laboratory ◽  
Metal Organic

scholarly journals The nanoscaled metal-organic framework ICR-2 as a carrier of porphyrins for photodynamic therapy

2018 ◽  
Vol 9 ◽  
pp. 2960-2967 ◽  
Author(s):  
Jan Hynek ◽  
Sebastian Jurík ◽  
Martina Koncošová ◽  
Jaroslav Zelenka ◽  
Ivana Křížová ◽  
...  
Keyword(s):  
Inorganic Chemistry ◽  
Photodynamic Therapy ◽  
Photophysical Properties ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Biological Applications ◽  
Nanoparticle Surface ◽  
Metal Organic ◽  
Unsaturated Metal Sites ◽  
First Time

Nanosized porphyrin-containing metal-organic frameworks (MOFs) attract considerable attention as solid-state photosensitizers for biological applications. In this study, we have for the first time synthesised and characterised phosphinate-based MOF nanoparticles, nanoICR-2 (Inorganic Chemistry Rez). We demonstrate that nanoICR-2 can be decorated with anionic 5,10,15,20-tetrakis(4-R-phosphinatophenyl)porphyrins (R = methyl, isopropyl, phenyl) by utilizing unsaturated metal sites on the nanoparticle surface. The use of these porphyrins allows for superior loading of the nanoparticles when compared with commonly used 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrin. The nanoICR-2/porphyrin composites retain part of the free porphyrins photophysical properties, while the photodynamic efficacy is strongly affected by the R substituent at the porphyrin phosphinate groups. Thus, phosphinatophenylporphyrin with phenyl substituents has the strongest photodynamic efficacy due to the most efficient cellular uptake.

Postsynthetic Modification of Metal–Organic Frameworks through Nitrile Oxide–Alkyne Cycloaddition

2018 ◽  
Vol 57 (6) ◽  
pp. 3348-3359 ◽  
Author(s):  
Tobias von Zons ◽  
Luisa Brokmann ◽  
Jann Lippke ◽  
Thomas Preuße ◽  
Miriam Hülsmann ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Nitrile Oxide ◽  
Postsynthetic Modification ◽  
Metal Organic

scholarly journals Spray Drying for Making Covalent Chemistry: Postsynthetic Modification of Metal–Organic Frameworks

2017 ◽  
Vol 139 (2) ◽  
pp. 897-903 ◽  
Author(s):  
Luis Garzón-Tovar ◽  
Sabina Rodríguez-Hermida ◽  
Inhar Imaz ◽  
Daniel Maspoch
Keyword(s):  
Spray Drying ◽  
Metal Organic Frameworks ◽  
Postsynthetic Modification ◽  
Metal Organic

Postsynthetic modification of mixed-linker metal–organic frameworks for ethylene oligomerization

RSC Advances ◽  
2014 ◽  
Vol 4 (107) ◽  
pp. 62343-62346 ◽  
Author(s):  
Bing Liu ◽  
Suyun Jie ◽  
Zhiyang Bu ◽  
Bo-Geng Li
Keyword(s):  
Metal Organic Frameworks ◽  
Nickel Catalysts ◽  
Ethylene Oligomerization ◽  
Postsynthetic Modification ◽  
Metal Organic

MOFs-containing nickel catalysts have been synthesized through postsynthetic modification of mixed-linker MOFs (Zn4O(BDC)x(ABDC)3−x) and used for ethylene oligomerization.

scholarly journals Postsynthetic Modification of Metal–Organic Frameworks

2021 ◽  
Vol 60 (16) ◽  
pp. 11703-11705
Author(s):  
Seth M. Cohen ◽  
Nathaniel L. Rosi
Keyword(s):  
Metal Organic Frameworks ◽  
Postsynthetic Modification ◽  
Metal Organic

scholarly journals Postsynthetic Modification: A Versatile Approach Toward Multifunctional Metal-Organic Frameworks

2009 ◽  
Vol 48 (15) ◽  
pp. 7341-7349 ◽  
Author(s):  
Sergio J. Garibay ◽  
Zhenqiang Wang ◽  
Kristine K. Tanabe ◽  
Seth M. Cohen
Keyword(s):  
Metal Organic Frameworks ◽  
Postsynthetic Modification ◽  
Metal Organic
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