Kinetics of Internal Rotation of N,N-Dimethylacetamide: A Spin-Saturation Transfer Experiment

1997 ◽  
Vol 74 (8) ◽  
pp. 978 ◽  
Author(s):  
Russell L. Jarek ◽  
Robert J. Flesher ◽  
Seung Koo Shin
Keyword(s):  
Internal Rotation ◽  
Saturation Transfer ◽  
Transfer Experiment ◽  
Kinetics Of

IN VIVO ENZYME KINETICS OF ARGININE KINASE OF CARCINUS CRAB BY NMR SATURATION TRANSFER

1981 ◽  
Vol 9 (2) ◽  
pp. 282P-282P ◽  
Author(s):  
K. R. Thulborn ◽  
R. W. Briggs ◽  
G. K. Radda
Keyword(s):  
Enzyme Kinetics ◽  
Arginine Kinase ◽  
Saturation Transfer ◽  
Kinetics Of

scholarly journals Kinetics of intramolecular chemical exchange by initial growth rates of spin saturation transfer difference experiments (SSTD NMR)

2015 ◽  
Vol 51 (50) ◽  
pp. 10222-10225 ◽  
Author(s):  
M. Teresa Quirós ◽  
Jesús Angulo ◽  
María Paz Muñoz
Keyword(s):  
Kinetic Parameters ◽  
Growth Rates ◽  
Chemical Exchange ◽  
Initial Growth ◽  
Saturation Transfer ◽  
Nmr Method ◽  
Saturation Transfer Difference ◽  
Kinetics Of

Initial growth rates SSTD NMR method is a new powerful tool to obtain the kinetic parameters of intramolecular chemical exchange.

Phosphorus-31 NMR saturation-transfer study of the in situ kinetics of the mitochondrial adenine nucleotide translocase

Biochemistry ◽  
1991 ◽  
Vol 30 (34) ◽  
pp. 8351-8357 ◽  
Author(s):  
Peter T. Masiakos ◽  
Gerald D. Williams ◽  
Deborah A. Berkich ◽  
Michael B. Smith ◽  
Kathryn F. LaNoue
Keyword(s):  
Adenine Nucleotide ◽  
Adenine Nucleotide Translocase ◽  
Saturation Transfer ◽  
Kinetics Of ◽  
Transfer Study

The Kinetics of Rubberlike Elasticity

1942 ◽  
Vol 15 (3) ◽  
pp. 438-445
Author(s):  
D. D. Eley
Keyword(s):  
Viscous Flow ◽  
Internal Rotation ◽  
Similar Data ◽  
Chain Molecules ◽  
Polymer Systems ◽  
Vulcanized Rubber ◽  
Activated State ◽  
Main Effect ◽  
High Degree ◽  
Kinetics Of

Abstract 1. The treatments of relaxation phenomena in polymer systems, due to Kuhn, and Alexandrov and Lazurkin, are outlined and discussed. 2. Eyring's rate equation is used to analyze the rates of orientation of long-chain molecules in a stressed specimen of lightly vulcanized rubber. The data are compared with similar data on viscous flow in raw rubber, and it is suggested that the segment size for movement is the same in both cases. In viscous flow, the segmental movement occurs without appreciable internal rotation within the segment. In elastic orientation, however, it appears that a high degree of internal rotation within the segment accompanies the formation of the activated state. 3. The activation energy for the orientation of long chains is separated into two terms: (1) the energy required to free a segment from its neighbors, (2) the energy of activation for rotation around C—C bonds. It is suggested that the main effect of vulcanization and plasticizers is on term (3); vulcanization tends to increase this term, plasticizers to decrease it. 4. Data on the dielectric dispersion of polyvinyl chloride suggests the need for internal rotational activation in this case, as in orientation elasticity. This is in agreement with what we should qualitatively expect. Possible complications due to crystallinity in rubber at high extensions or low temperatures are briefly discussed.

scholarly journals The in vitro kinetics of mitochondrial and cytosolic creatine kinase determined by saturation transfer 31P-NMR

1996 ◽  
Vol 1274 (1-2) ◽  
pp. 59-66 ◽  
Author(s):  
Ferdi A. van Dorsten ◽  
Rolf Furter ◽  
Menno Bijkerk ◽  
Theo Wallimann ◽  
Klaas Nicolay
Keyword(s):  
Creatine Kinase ◽  
31P Nmr ◽  
Saturation Transfer ◽  
Kinetics Of ◽  
In Vitro Kinetics
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