Methods for calculating the pH of aqueous solutions of salts of monoprotic acids and bases

1990 ◽  
Vol 67 (6) ◽  
pp. 502 ◽  
Author(s):  
Edmund R. Malinowski
Keyword(s):  
Aqueous Solutions ◽  
Acids And Bases

scholarly journals THE CONDUCTIVITY AND IONIZATION OF SALTS, ACIDS, AND BASES IN AQUEOUS SOLUTIONS AT HIGH TEMPERATURES.

1908 ◽  
Vol 30 (3) ◽  
pp. 335-353 ◽  
Author(s):  
Arthur A. Noyes ◽  
A. C. Melcher ◽  
H. C. Cooper ◽  
G. W. Eastman ◽  
Yogoro Kato
Keyword(s):  
Aqueous Solutions ◽  
High Temperatures ◽  
Acids And Bases

scholarly journals Shifted equilibria of organic acids and bases in the aqueous surface region

2018 ◽  
Vol 20 (36) ◽  
pp. 23281-23293 ◽  
Author(s):  
Josephina Werner ◽  
Ingmar Persson ◽  
Olle Björneholm ◽  
Delphine Kawecki ◽  
Clara-Magdalena Saak ◽  
...  
Keyword(s):  
Organic Acids ◽  
Aqueous Solutions ◽  
Surface Region ◽  
Delicate Balance ◽  
Aqueous Surface ◽  
Acids And Bases

Revealing the delicate balance between protonation/deprotonation and surface/bulk partitioning of organic acids and bases in aqueous solutions.

scholarly journals Colloidal electrolytes. —Soap solutions and their constitution

1920 ◽  
Vol 97 (681) ◽  
pp. 44-65 ◽  
Keyword(s):  
Aqueous Solutions ◽  
Organic Compounds ◽  
Chromium Chloride ◽  
New Class ◽  
Acids And Bases

Colloidal electrolytes are solutions of salts in which one ion has been replaced by a heavily hydrated polyvalent micelle, carrying an equivalent sum total of electrical charges and also serving as an excellent conductor of electricity. This is the conclusion to which our investigations have led us. It will probably prove that this new class includes, under certain conditions, most organic compounds containing more than eight carbon atoms, and capable of forming ions, also solutions of the acid and alkali proteins, dyes, indicators, sulphonates, soaps, and possibly even of such compounds as chromium chloride, and of the alkaline tungstates, zincates, tellurates, and silicates. Many non-aqueous solutions may also be included in the same category, as will be shown in a later communication, and it is indeed probable that the class includes as many members as the acids and bases together.

Infrared optical constants of aqueous solutions of electrolytes. Acids and bases

1974 ◽  
Vol 78 (14) ◽  
pp. 1405-1410 ◽  
Author(s):  
Paul Rhine ◽  
Dudley Williams ◽  
G. Michael Hale ◽  
Marvin R. Querry
Keyword(s):  
Aqueous Solutions ◽  
Optical Constants ◽  
Solutions Of Electrolytes ◽  
Acids And Bases

THE HEAT OF NEUTRALIZATION OF STRONG ACIDS AND BASES IN HIGHLY DILUTE AQUEOUS SOLUTIONS

1956 ◽  
Vol 34 (12) ◽  
pp. 1677-1682 ◽  
Author(s):  
H. M. Papee ◽  
W. J. Canady ◽  
K. J. Laidler
Keyword(s):  
Aqueous Solutions ◽  
Sodium Hydroxide ◽  
Dilute Aqueous Solutions ◽  
Acids And Bases ◽  
Calorimetric Studies ◽  
Strong Acids

Heats of neutralization of sulphuric and hydrochloric acids by sodium hydroxide have been determined, using a microcalorimeter of the Tian–Calvet type. The range of concentrations employed was 5 × 10−4 N to 3 × 10−2 N, which is sufficiently low to permit an accurate extrapolation to be made down to zero concentration. The extrapolated values obtained were: for H2SO4–NaOH, 13.48 ± 0.05 kcal. per gm-equiv. and for HCl–NaOH, 13.52 ± 0.05 kcal. per gm-equiv. These values, which correspond to the process H3O+ + OH− → 2H2O, are significantly higher than the values of 13.32–13.37 kcal. obtained on the basis of previous calorimetric studies in a much higher concentration range. The present values, however, agree well with those calculated by Harned and co-workers and by Everett and Wynne-Jones from electrochemical data.

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