Photodestruction quantum yield of adenine in aqueous solution: A physical chemistry experiment

1989 ◽  
Vol 66 (12) ◽  
pp. 1049
Author(s):  
Mercedes Rivera
Keyword(s):  
Physical Chemistry ◽  
Aqueous Solution ◽  
Quantum Yield ◽  
Chemistry Experiment

Synthesis of CdS-Capped CdSe Nanocrystals without any Poisonous Materials

2014 ◽  
Vol 981 ◽  
pp. 806-809
Author(s):  
Wu Lei Zhou ◽  
Tuo Cai ◽  
Yun Chen ◽  
Xuan Lin Chen ◽  
Yu Qiu Qu ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Quantum Yield ◽  
Aqueous Medium ◽  
Laser Irradiation ◽  
Absorption Spectroscopy ◽  
Photoluminescence Spectroscopy ◽  
Luminescence Quantum Yield ◽  
Cdse Nanocrystals ◽  
Core Shell ◽  
Photo Stability

CdS-capped CdSe nanocrystals (NCs) which show high luminescence quantum yield are synthesized without any Poisonous Materials in aqueous solution. The synthesis in an aqueous medium without any poisonous materials is attached importance to. The absorption spectroscopy and photoluminescence spectroscopy are employed to analyze the NCs. It takes 78s that the intensity decreases to the half for bare CdSe NCs, but 442s for CdSe/CdS core/shell NCs. The photo stability of CdSe NCs under 325nm laser irradiation is enhanced greatly after CdS overcoating.

Quantum Yields for the Photodegradation of Pollutants in Dilute Aqueous Solution: Phenol, 4-Chlorophenol and N-Nitrosodimethylamine

1996 ◽  
Vol 1 (2) ◽  
Author(s):  
Te-Fu L. Ho ◽  
James R. Bolton ◽  
Ewa Lipczynska-Kochany
Keyword(s):  
Aqueous Solution ◽  
Hydrogen Peroxide ◽  
Quantum Yield ◽  
High Performance ◽  
Flash Photolysis ◽  
Quantum Yields ◽  
Visible Absorption ◽  
Dilute Aqueous Solution ◽  
Uv Visible ◽  
Photolysis Of Phenol

AbstractA broadband method has been applied to determine the quantum yields for the photochemical removal of three common pollutants: phenol, 4-chlorophenol and N-nitrosodimethylamine (NDMA) in dilute aqueous solution. Flash photolysis (xenon flash lamps) was used to cause a significant amount of photolysis without photolyzing intermediates. The analysis of reactant depletion following a single flash was carried out by high- performance liquid chromatography (HPLC) or UV/visible absorption spectroscopy. The method for determining quantum-yields employed p-benzoquinone as an actinometer and was validated by determining the average (200-400 nm) quantum yield for the generation of hydroxyl radicals from the photolysis of hydrogen peroxide (0.90 ± 0.10) and the quantum yields for the photolysis of phenol (0.13 ± 0.02) and 4-chlorophenol (0.24 ± 0.04). The values determined agree very well with the literature ones obtained with monochromatic radiation. The quantum yield for the direct photolysis of NDMA was found to be 0.11 ± 0.03 at neutral pH and 0.27 ± 0.02 at pH 2-4. Under conditions where hydrogen peroxide is the principal absorber, the NDMA quantum yield is 0.32 ± 0.04, independent of pH in the range 2-8.

Analysis of the Physical Chemistry Experiment for the 12th National Undergraduate Chemistry Laboratory Tournament

Daxue Huaxue ◽  
2021 ◽  
Vol 0 (0) ◽  
pp. 2109118-0
Author(s):  
Lipeng Zhou ◽  
Xubo Zhao ◽  
Jinshuai Song ◽  
Pu Liu ◽  
Xiaomei Yang ◽  
...  
Keyword(s):  
Physical Chemistry ◽  
Chemistry Laboratory ◽  
Undergraduate Chemistry ◽  
Chemistry Experiment

Analysis of Physical Chemistry Experiment for the 11th National Undergraduate Chemistry Laboratory Tournament

Daxue Huaxue ◽  
2019 ◽  
Vol 34 (5) ◽  
pp. 88-93
Author(s):  
Shuying ZHU ◽  
◽  
Yi LI ◽  
Shuting WU ◽  
Yanqiong SUN ◽  
...  
Keyword(s):  
Physical Chemistry ◽  
Chemistry Laboratory ◽  
Undergraduate Chemistry ◽  
Chemistry Experiment
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