A computer program for simulating first-order electron spin resonance spectra

1974 ◽  
Vol 51 (3) ◽  
pp. 174 ◽  
Author(s):  
A. Campbell Ling
Keyword(s):  
Electron Spin Resonance ◽  
Computer Program ◽  
Electron Spin ◽  
First Order ◽  
Spin Resonance

An Electron Spin Resonance Study of Some Reactions of Pentafluorosulfuranyl (SF5)

1975 ◽  
Vol 53 (16) ◽  
pp. 2361-2364 ◽  
Author(s):  
John Charles Tait ◽  
James Anthony Howard
Keyword(s):  
Electron Spin Resonance ◽  
Electron Spin ◽  
Rate Constants ◽  
Arrhenius Equation ◽  
Kinetic Studies ◽  
Electron Spin Resonance Study ◽  
Order Process ◽  
First Order ◽  
Spin Resonance ◽  
Spin Resonance Study

A kinetic electron spin resonance study of the self-reaction of SF5 and a spectroscopic and kinetic e.s.r. study of the reaction of SF5 with 1,1-di-t-butylethylene are reported. This radical undergoes self-reaction by a second-order process and the rate constants are given by the Arrhenius equation log 2k1(M−1 s−1) = (10.3 ± 0.5) − (1.7 ± 0.5)/θ where θ = 2.303RT kcal mol−1. It adds to 1,1-di-t-butylethylene to give (t-Bu)2CCH2SF5 which decomposes by a first-order process with rate constants that obey the expression log k2(s−1) = (13 ± 0.4) − (10 ± 0.2)/θ. Both these rate constants are pertinent to kinetic studies of the photoinduced addition of SF5C1 to olefins.

Tube electrode and electron spin resonance. First-order kinetics

1980 ◽  
Vol 76 (0) ◽  
pp. 1391 ◽  
Author(s):  
W. John Albery ◽  
Richard G. Compton ◽  
Andrew T. Chadwick ◽  
Barry A. Coles ◽  
Jan A. Lenkait
Keyword(s):  
Electron Spin Resonance ◽  
Electron Spin ◽  
First Order ◽  
First Order Kinetics ◽  
Tube Electrode ◽  
Spin Resonance

scholarly journals Simulation of isotropic electron spin resonance spectra: a transportable basic program

1982 ◽  
Vol 60 (12) ◽  
pp. 1542-1548 ◽  
Author(s):  
Uwe M Oehler ◽  
Edward G Janzen
Keyword(s):  
Electron Spin Resonance ◽  
Computer Program ◽  
Electron Spin ◽  
Esr Spectra ◽  
Spin Trapping ◽  
Basic Program ◽  
Spin Resonance ◽  
Restricted Environment

A computer program written in BASIC is presented for the simulation of isotropic esr spectra using a microprocessor. Since BASIC is the most common microprocessor language, this program can easily be adapted to most microprocessors. Through the use of more efficient methods the capabilities of much larger FORTRAN programs, run on mainframe computers, are retained in the more restricted environment of the microprocessor. As a result, most spin trapping results can be dealt with easily. A number of sample simulations illustrate the program’s features.

Sign in / Sign up

Export Citation Format

Share Document