Order−Disorder Transition and Phase Separation in the MgB2 Metallic Sublattice Induced by Al Doping

2009 ◽  
Vol 5 (7) ◽  
pp. 1858-1864 ◽  
Author(s):  
S. Brutti ◽  
G. Gigli
2010 ◽  
Vol 97-101 ◽  
pp. 475-478
Author(s):  
Hua Wang ◽  
Zhu Huang ◽  
Ji Wen Xu ◽  
Ling Yang ◽  
Ming Fang Ren

MgxZn1-xO:Al ceramics with low resistivity using ZnO, MgO and Al2O3 nano-powders as raw materials were obtained by unpressurized sintering. The influence of Mg content on structure and electric properties of MgxZn1-xO:Al ceramics were studied. The results indicate that there is a single phase of wurtzite structure of ZnO in MgxZn1-xO:Al ceramics at x ≤ 0.3, and when the value of x was 0.3, phase separation was observed. The grains become smaller and more homogeneous with increasing Mg content to above 0.3. The resistivity of MgxZn1-xO:Al ceramics obviously increases with increasing Mg concentration due to the decrease of the carrier concentration and the mobility deriving from the decrease of Al-doping efficiency. The electrical conduction of MgxZn1-xO:Al ceramics can be markedly improved by increasing the Al-doping level and the lowest resistivity of 8.3×10-4Ω•cm can be obtained when Mg/(Mg+Zn)=0.2 and Al/(Mg+Zn+Al)=0.03.


Author(s):  
P. Echlin ◽  
M. McKoon ◽  
E.S. Taylor ◽  
C.E. Thomas ◽  
K.L. Maloney ◽  
...  

Although sections of frozen salt solutions have been used as standards for x-ray microanalysis, such solutions are less useful when analysed in the bulk form. They are poor thermal and electrical conductors and severe phase separation occurs during the cooling process. Following a suggestion by Whitecross et al we have made up a series of salt solutions containing a small amount of graphite to improve the sample conductivity. In addition, we have incorporated a polymer to ensure the formation of microcrystalline ice and a consequent homogenity of salt dispersion within the frozen matrix. The mixtures have been used to standardize the analytical procedures applied to frozen hydrated bulk specimens based on the peak/background analytical method and to measure the absolute concentration of elements in developing roots.


Author(s):  
J. Tong ◽  
L. Eyring

There is increasing interest in composites containing zirconia because of their high strength, fracture toughness, and its great influence on the chemical durability in glass. For the zirconia-silica system, monolithic glasses, fibers and coatings have been obtained. There is currently a great interest in designing zirconia-toughened alumina including exploration of the processing methods and the toughening mechanism.The possibility of forming nanocrystal composites by a phase separation method has been investigated in three systems: zirconia-alumina, zirconia-silica and zirconia-titania using HREM. The morphological observations initially suggest that the formation of nanocrystal composites by a phase separation method is possible in the zirconia-alumina and zirconia-silica systems, but impossible in the zirconia-titania system. The separation-produced grain size in silica-zirconia system is around 5 nm and is more uniform than that in the alumina-zirconia system in which the sizes of the small polyhedron grains are around 10 nm. In the titania-zirconia system, there is no obvious separation as was observed in die alumina-zirconia and silica-zirconia system.


1998 ◽  
Vol 95 (2) ◽  
pp. 131-135 ◽  
Author(s):  
DOUGLAS HENDERSON DEZSO BODA KWONG-YU CHAN
Keyword(s):  

Nature ◽  
2020 ◽  
Vol 585 (7824) ◽  
pp. 191-192 ◽  
Author(s):  
Simon Alberti

1989 ◽  
Vol 50 (3) ◽  
pp. 375-385 ◽  
Author(s):  
H. Fadel ◽  
D. Guillon ◽  
A. Skoulios ◽  
F. Barbarin ◽  
M. Dugay

Sign in / Sign up

Export Citation Format

Share Document