scholarly journals Integrated Continuum Dielectric Approaches To Treat Molecular Polarizability and the Condensed Phase: Refractive Index and Implicit Solvation

2009 ◽  
Vol 5 (7) ◽  
pp. 1785-1802 ◽  
Author(s):  
Jean-François Truchon ◽  
Anthony Nicholls ◽  
Benoît Roux ◽  
Radu I. Iftimie ◽  
Christopher I. Bayly
1980 ◽  
Vol 35 (11) ◽  
pp. 1171-1177 ◽  
Author(s):  
G. Abbate ◽  
U. Bernini ◽  
E. Ragozzino ◽  
F. Somma

Abstract The temperature coefficient of the refractive index, (∂n/∂T)p, has been measured for deuterium oxide. The observed values are considered together with those previously obtained for water. The experimental data cannot be explained with the best known models of molecular polarizability, at least in the approximation generally used in these models. Therfore they are discussed on the basis of a different approximation, suggested by a well-known structural model of liquid water. It is shown that the experimental results are very well explained, in a wide range of temperature, with the hypothesis of the existence of "structural voids".


2020 ◽  
Vol 90 (6) ◽  
pp. 1001
Author(s):  
А.Ю. Попов ◽  
А.В. Тюрин ◽  
В.Г. Ткаченко ◽  
А.Я. Бекшаев ◽  
В.В. Калинчак ◽  
...  

Methods are described for recording and automated processing of the data obtained from phase-modulated speckle interferometry of optically dense (opaque to the intrinsic radiation) flames containing a condensed phase. The use of a high-speed single-frame measurement technique and special processing procedures makes it possible to determine the spatiotemporal distribution of the refractive index, based on which the flame structure can be identified. As an example, the results of investigation of the torch formed by burning a stationary medical paraffin droplet are presented.


1999 ◽  
Vol 103 (12) ◽  
pp. 1818-1821 ◽  
Author(s):  
Kristian O. Sylvester-Hvid ◽  
Per-Olof Åstrand ◽  
Mark A. Ratner ◽  
Kurt V. Mikkelsen

Author(s):  
W. E. Lee

An optical waveguide consists of a several-micron wide channel with a slightly different index of refraction than the host substrate; light can be trapped in the channel by total internal reflection.Optical waveguides can be formed from single-crystal LiNbO3 using the proton exhange technique. In this technique, polished specimens are masked with polycrystal1ine chromium in such a way as to leave 3-13 μm wide channels. These are held in benzoic acid at 249°C for 5 minutes allowing protons to exchange for lithium ions within the channels causing an increase in the refractive index of the channel and creating the waveguide. Unfortunately, optical measurements often reveal a loss in waveguiding ability up to several weeks after exchange.


Author(s):  
Walter C. McCrone

An excellent chapter on this subject by V.D. Fréchette appeared in a book edited by L.L. Hench and R.W. Gould in 1971 (1). That chapter with the references cited there provides a very complete coverage of the subject. I will add a more complete coverage of an important polarized light microscope (PLM) technique developed more recently (2). Dispersion staining is based on refractive index and its variation with wavelength (dispersion of index). A particle of, say almandite, a garnet, has refractive indices of nF = 1.789 nm, nD = 1.780 nm and nC = 1.775 nm. A Cargille refractive index liquid having nD = 1.780 nm will have nF = 1.810 and nC = 1.768 nm. Almandite grains will disappear in that liquid when observed with a beam of 589 nm light (D-line), but it will have a lower refractive index than that liquid with 486 nm light (F-line), and a higher index than that liquid with 656 nm light (C-line).


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