Ordered Mesoporous Metal–Organic Frameworks Incorporated with Amorphous TiO2As Photocatalyst for Selective Aerobic Oxidation in Sunlight Irradiation

ACS Catalysis ◽  
2014 ◽  
Vol 4 (5) ◽  
pp. 1398-1403 ◽  
Author(s):  
Sedigheh Abedi ◽  
Ali Morsali
Keyword(s):  
Aerobic Oxidation ◽  
Metal Organic Frameworks ◽  
Sunlight Irradiation ◽  
Ordered Mesoporous ◽  
Metal Organic ◽  
Selective Aerobic Oxidation ◽  
Mesoporous Metal

Ordered Mesoporous Metal–Organic Frameworks Consisting of Metal Disulfonates

2012 ◽  
Vol 24 (12) ◽  
pp. 2253-2255 ◽  
Author(s):  
Tian-Yi Ma ◽  
Hui Li ◽  
Qing-Fang Deng ◽  
Lei Liu ◽  
Tie-Zhen Ren ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Ordered Mesoporous ◽  
Metal Organic ◽  
Mesoporous Metal

scholarly journals Cobalt-Based Metal Organic Frameworks as Solids Catalysts for Oxidation Reactions

Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 95
Author(s):  
Amarajothi Dhakshinamoorthy ◽  
Eva Montero Lanzuela ◽  
Sergio Navalon ◽  
Hermenegildo Garcia
Keyword(s):  
Aerobic Oxidation ◽  
High Surface ◽  
Metal Organic Frameworks ◽  
High Surface Area ◽  
Acid Sites ◽  
Crystalline Lattice ◽  
Oxidation Reactions ◽  
Solid Catalysts ◽  
Long Term Stability ◽  
Metal Organic

Metal organic frameworks (MOFs) are porous crystalline solids whose frameworks are constituted by metal ions/nodes with rigid organic linkers leading to the formation of materials having high surface area and pore volume. One of the unique features of MOFs is the presence of coordinatively unsaturated metal sites in their crystalline lattice that can act as Lewis acid sites promoting organic transformations, including aerobic oxidation reactions of various substrates such as hydrocarbons, alcohols, and sulfides. This review article summarizes the existing Co-based MOFs for oxidation reactions organized according to the nature of substrates like hydrocarbon, alcohol, olefin, and water. Both aerobic conditions and peroxide oxidants are discussed. Emphasis is placed on comparing the advantages of using MOFs as solid catalysts with respect to homogeneous salts in terms of product selectivity and long-term stability. The final section provides our view on future developments in this field.

Micro and mesoporous metal–organic frameworks for catalysis applications

2010 ◽  
Vol 39 (7) ◽  
pp. 1692-1694 ◽  
Author(s):  
Praveen K. Thallapally ◽  
Carlos A. Fernandez ◽  
Radha Kishan Motkuri ◽  
Satish K. Nune ◽  
Jun Liu ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Mesoporous Metal

Aerobic oxidation of thiols to disulfides using iron metal–organic frameworks as solid redox catalysts

2010 ◽  
Vol 46 (35) ◽  
pp. 6476 ◽  
Author(s):  
Amarajothi Dhakshinamoorthy ◽  
Mercedes Alvaro ◽  
Hermenegildo Garcia
Keyword(s):  
Aerobic Oxidation ◽  
Metal Organic Frameworks ◽  
Iron Metal ◽  
Redox Catalysts ◽  
Metal Organic
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