Promoting Effect of Sulfur Addition on the Catalytic Performance of Ni/MgAl2O4 Catalysts for Isobutane Dehydrogenation

ACS Catalysis ◽  
2013 ◽  
Vol 3 (12) ◽  
pp. 2992-3001 ◽  
Author(s):  
Guowei Wang ◽  
Zhe Meng ◽  
Jianwei Liu ◽  
Chunyi Li ◽  
Honghong Shan
2010 ◽  
Vol 383 (1-2) ◽  
pp. 73-78 ◽  
Author(s):  
Weiqiang Yu ◽  
Jing Zhao ◽  
Hong Ma ◽  
Hong Miao ◽  
Qi Song ◽  
...  

2013 ◽  
Vol 15 (1) ◽  
pp. 22-26 ◽  
Author(s):  
Barbara Litawa ◽  
Piotr Michorczyk ◽  
Jan Ogonowski

In this work the La2O3/CeO2 (33 mol % of La) and CaO/CeO2 (33 mol % of Ca) catalysts were prepared by the impregnation method and characterized by XRD and CO2-TPD. The catalytic properties of the catalysts were tested in the OCM process at 1073 K using the methane/oxygen mixture of the mole ratio 3.7 or 2.5 additionally containing CO2 and helium balance. It was found that in the presence of both catalysts an addition of CO2 enhances the selectivity to the ethylene and ethane and it does not have any negative influence on methane conversion. In the case of the CaO/CeO2 catalyst the promoting effect of CO2 was the highest. When the partial pressure of CO2 equals to 39 kPa the increase in selectivity from 36 to 41% was noted while the conversion of methane equal to 19.4-19.7 %.


Author(s):  
Junan Gao ◽  
Song Gao ◽  
Jun Wei ◽  
Hong Zhao ◽  
Jie Zhang

In this paper, the catalytic combustion of DMDS (dimethyl disulfide, CH3SSCH3) over bimetallic supported catalysts were investigated. It was confirmed that Cu/γ-Al2O3-CeO2 showed best catalytic performance among the five single-metal catalysts. Furthermore, six different metals were separately added into Cu/γ-Al2O3-CeO2 to investigate the promoting effect. The experiments revealed Pt as the most effective promoter and the the best catalytic performance was achieved as the adding amount of 0.3 wt%. The characterization results indicated that high activity and resistance to sulfur poisoning of Cu-Pt/γ-Al2O3-CeO2 could be attributed to the synergistic effect between Cu and Pt.


2010 ◽  
Vol 31 (2) ◽  
pp. 470-472 ◽  
Author(s):  
Hyo-Sik Kim ◽  
Jong-Wook Bae ◽  
Suk-Hwan Kang ◽  
Kyoung-Su Ha ◽  
Ki-Won Jun ◽  
...  

2010 ◽  
Vol 91 (7) ◽  
pp. 723-728 ◽  
Author(s):  
Lili Wang ◽  
Lingmei Yang ◽  
Yuanhua Zhang ◽  
Wen Ding ◽  
Shiping Chen ◽  
...  

2016 ◽  
Vol 6 (14) ◽  
pp. 5656-5667 ◽  
Author(s):  
Fufeng Cai ◽  
Guomin Xiao

In this work, the Ce-promoted Cu–Co–Al catalyst exhibited high catalytic performance and stability (100 h) for the hydrogenolysis of glycerol to 1,2-propanediol.


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