Selective Oxidation of Saturated Hydrocarbons Using Au–Pd Alloy Nanoparticles Supported on Metal–Organic Frameworks

ACS Catalysis ◽  
2013 ◽  
Vol 3 (4) ◽  
pp. 647-654 ◽  
Author(s):  
Jilan Long ◽  
Hongli Liu ◽  
Shijian Wu ◽  
Shijun Liao ◽  
Yingwei Li
Keyword(s):  
Selective Oxidation ◽  
Metal Organic Frameworks ◽  
Alloy Nanoparticles ◽  
Saturated Hydrocarbons ◽  
Pd Alloy ◽  
Metal Organic

scholarly journals Metal-Organic Frameworks in Oxidation Catalysis with Hydrogen Peroxide

Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 283
Author(s):  
Oxana Kholdeeva ◽  
Nataliya Maksimchuk
Keyword(s):  
Hydrogen Peroxide ◽  
Liquid Phase ◽  
Selective Oxidation ◽  
Metal Organic Frameworks ◽  
Short Review ◽  
Catalytic Performance ◽  
Oxidation Catalysis ◽  
Catalyst Stability ◽  
Aqueous Hydrogen Peroxide ◽  
Metal Organic

In recent years, metal–organic frameworks (MOFs) have received increasing attention as selective oxidation catalysts and supports for their construction. In this short review paper, we survey recent findings concerning use of MOFs in heterogeneous liquid-phase selective oxidation catalysis with the green oxidant–aqueous hydrogen peroxide. MOFs having outstanding thermal and chemical stability, such as Cr(III)-based MIL-101, Ti(IV)-based MIL-125, Zr(IV)-based UiO-66(67), Zn(II)-based ZIF-8, and some others, will be in the main focus of this work. The effects of the metal nature and MOF structure on catalytic activity and oxidation selectivity are analyzed and the mechanisms of hydrogen peroxide activation are discussed. In some cases, we also make an attempt to analyze relationships between liquid-phase adsorption properties of MOFs and peculiarities of their catalytic performance. Attempts of using MOFs as supports for construction of single-site catalysts through their modification with heterometals will be also addressed in relation to the use of such catalysts for activation of H2O2. Special attention is given to the critical issues of catalyst stability and reusability. The scope and limitations of MOF catalysts in H2O2-based selective oxidation are discussed.

Hierarchical confine of PtZn alloy nanoparticles and single-dispersed Zn atoms on COF@MOF-derived carbon towards efficient oxygen reduction reaction

2021 ◽  
Author(s):  
Yu Guo ◽  
Shuai Yang ◽  
Qing Xu ◽  
Ping Wu ◽  
Zheng Jiang ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Metal Organic Frameworks ◽  
Reduction Reaction ◽  
Alloy Nanoparticles ◽  
Covalent Organic Frameworks ◽  
Metal Organic ◽  
Significant Attention

Covalent organic frameworks (COFs) and metal-organic frameworks (MOFs) are getting significant attention for enormous application because of their designable and controllable skeletons and porosities. The integrated materials of MOFs and...

Non-noble bimetallic CuCo nanoparticles encapsulated in the pores of metal–organic frameworks: synergetic catalysis in the hydrolysis of ammonia borane for hydrogen generation

2015 ◽  
Vol 5 (1) ◽  
pp. 525-530 ◽  
Author(s):  
Jun Li ◽  
Qi-Long Zhu ◽  
Qiang Xu
Keyword(s):  
Catalytic Activity ◽  
Hydrogen Generation ◽  
Metal Organic Frameworks ◽  
Ammonia Borane ◽  
Alloy Nanoparticles ◽  
Metal Organic ◽  
Hydrolysis Of

Non-noble bimetallic CuCo alloy nanoparticles were successfully encapsulated in the pores of MIL-101 without aggregation on the external surfaces of the host framework, which exhibit excellent catalytic activity for hydrolytic dehydrogenation of ammonia borane.

Recent advances in Metal-Organic Frameworks-based materials for photocatalytic selective oxidation

2022 ◽  
Vol 450 ◽  
pp. 214240
Author(s):  
Guilong Lu ◽  
Feng Chu ◽  
Xiubing Huang ◽  
Yaqiong Li ◽  
Kaiyan Liang ◽  
...  
Keyword(s):  
Selective Oxidation ◽  
Metal Organic Frameworks ◽  
Recent Advances ◽  
Metal Organic

Polyoxometalate-Based Metal-Organic Frameworks as Heterogeneous Catalysts for Selective Oxidation of Ethylbenzene

2010 ◽  
Vol 2010 (28) ◽  
pp. 4526-4531 ◽  
Author(s):  
Fan Yu ◽  
Pei-Qing Zheng ◽  
Yu-Xiang Long ◽  
Yan-Ping Ren ◽  
Xiang-Jian Kong ◽  
...  
Keyword(s):  
Selective Oxidation ◽  
Heterogeneous Catalysts ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Oxidation Of Ethylbenzene

Cyclohexane selective oxidation over metal–organic frameworks of MIL-101 family: superior catalytic activity and selectivity

2012 ◽  
Vol 48 (54) ◽  
pp. 6812 ◽  
Author(s):  
Nataliya V. Maksimchuk ◽  
Konstantin A. Kovalenko ◽  
Vladimir P. Fedin ◽  
Oxana A. Kholdeeva
Keyword(s):  
Catalytic Activity ◽  
Selective Oxidation ◽  
Metal Organic Frameworks ◽  
Metal Organic

Selective oxidation of cyclooctene over copper-containing metal-organic frameworks

2015 ◽  
Vol 216 ◽  
pp. 151-160 ◽  
Author(s):  
Ulrike Junghans ◽  
Christian Suttkus ◽  
Jörg Lincke ◽  
Daniel Lässig ◽  
Harald Krautscheid ◽  
...  
Keyword(s):  
Selective Oxidation ◽  
Metal Organic Frameworks ◽  
Metal Organic

Epoxidation of styrene over Fe(Cr)-MIL-101 metal–organic frameworks

RSC Advances ◽  
2014 ◽  
Vol 4 (72) ◽  
pp. 38048-38054 ◽  
Author(s):  
Jian Sun ◽  
Guangli Yu ◽  
Qisheng Huo ◽  
Qiubin Kan ◽  
Jingqi Guan
Keyword(s):  
Selective Oxidation ◽  
Heterogeneous Catalysts ◽  
Metal Organic Frameworks ◽  
Metal Organic

Fe(Cr)-MIL-101 metal–organic frameworks as efficient heterogeneous catalysts for the selective oxidation of styrene.

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