High-Pressure In Situ NMR Methods for the Study of Reaction Kinetics in Homogeneous Catalysis

ACS Catalysis ◽  
2012 ◽  
Vol 2 (11) ◽  
pp. 2281-2289 ◽  
Author(s):  
Alexandre Torres ◽  
Nieves Molina Perez ◽  
Gillian Overend ◽  
Nicholas Hodge ◽  
Brian T. Heaton ◽  
...  
Keyword(s):  
High Pressure ◽  
Reaction Kinetics ◽  
Homogeneous Catalysis ◽  
Nmr Methods ◽  
In Situ Nmr

High pressure NMR flow cell for the in situ study of homogeneous catalysis

1998 ◽  
Vol 22 (10) ◽  
pp. 1043-1045 ◽  
Author(s):  
Jonathan A. Iggo ◽  
Darren Shirley ◽  
Nicola C. Tong
Keyword(s):  
High Pressure ◽  
Homogeneous Catalysis ◽  
Flow Cell ◽  
In Situ Study

Interaction of Hydrogen with Supported Ru Catalysts: High Pressure in Situ NMR Studies

1994 ◽  
Vol 147 (2) ◽  
pp. 455-464 ◽  
Author(s):  
S. Bhatia ◽  
F. Engelke ◽  
M. Pruski ◽  
B.C. Gerstein ◽  
T.S. King
Keyword(s):  
High Pressure ◽  
Nmr Studies ◽  
Ru Catalysts ◽  
In Situ Nmr

Single Crystal Growth of High-Pressure Phases of Ice and Salt Hydrate Far Below the Original Melting Point by Mixing Alcohol: Crystal Structure Determination of Magnesium Chloride Heptahydrate

2020 ◽  
Author(s):  
Keishiro Yamashita ◽  
Kazuki Komatsu ◽  
Hiroyuki Kagi
Keyword(s):  
Crystal Structure ◽  
High Pressure ◽  
Crystal Growth ◽  
Single Crystal ◽  
Room Temperature ◽  
Growth Technique ◽  
Salt Hydrate ◽  
X Ray

An crystal-growth technique for single crystal x-ray structure analysis of high-pressure forms of hydrogen-bonded crystals is proposed. We used alcohol mixture (methanol: ethanol = 4:1 in volumetric ratio), which is a widely used pressure transmitting medium, inhibiting the nucleation and growth of unwanted crystals. In this paper, two kinds of single crystals which have not been obtained using a conventional experimental technique were obtained using this technique: ice VI at 1.99 GPa and MgCl<sub>2</sub>·7H<sub>2</sub>O at 2.50 GPa at room temperature. Here we first report the crystal structure of MgCl2·7H2O. This technique simultaneously meets the requirement of hydrostaticity for high-pressure experiments and has feasibility for further in-situ measurements.

scholarly journals Cover Picture: A Versatile Ambient‐to‐High‐Pressure Reaction Transmission Cell for in situ/operando Infrared Spectroscopic Investigations (Chemistry ‐ Methods 7/2021)

2021 ◽  
Vol 1 (7) ◽  
pp. 305-305
Author(s):  
Jana Weiß ◽  
Christine Rautenberg ◽  
Thomas Rall ◽  
Christoph Kubis ◽  
Evgenii Kondratenko ◽  
...  
Keyword(s):  
High Pressure ◽  
Spectroscopic Investigations ◽  
Infrared Spectroscopic ◽  
High Pressure Reaction

scholarly journals A Versatile Ambient‐to‐High‐Pressure Reaction Transmission Cell for in situ/operando Infrared Spectroscopic Investigations

2021 ◽  
Vol 1 (7) ◽  
pp. 308-314
Author(s):  
Jana Weiß ◽  
Christine Rautenberg ◽  
Thomas Rall ◽  
Christoph Kubis ◽  
Evgenii Kondratenko ◽  
...  
Keyword(s):  
High Pressure ◽  
Spectroscopic Investigations ◽  
Infrared Spectroscopic ◽  
High Pressure Reaction
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