Cyclometalated Phosphine-Based Pincer Complexes:  Mechanistic Insight in Catalysis, Coordination, and Bond Activation

2003 ◽  
Vol 103 (5) ◽  
pp. 1759-1792 ◽  
Author(s):  
Milko E. van der Boom ◽  
David Milstein
Keyword(s):  
Bond Activation ◽  
Pincer Complexes ◽  
Mechanistic Insight

scholarly journals Metal–ligand cooperation by aromatization–dearomatization as a tool in single bond activation

2015 ◽  
Vol 373 (2037) ◽  
pp. 20140189 ◽  
Author(s):  
David Milstein
Keyword(s):  
Bond Activation ◽  
Short Review ◽  
Catalytic Reactions ◽  
Pincer Complexes ◽  
Chemical Bonds ◽  
Single Bond ◽  
Metal Centre ◽  
Pincer Ligand ◽  
Mechanistic Insight ◽  
Metal Ligand

Metal–ligand cooperation (MLC) plays an important role in bond activation processes, enabling many chemical and biological catalytic reactions. A recent new mode of activation of chemical bonds involves ligand aromatization–dearomatization processes in pyridine-based pincer complexes in which chemical bonds are broken reversibly across the metal centre and the pincer-ligand arm, leading to new bond-making and -breaking processes, and new catalysis. In this short review, such processes are briefly exemplified in the activation of C–H, H–H, O–H, N–H and B–H bonds, and mechanistic insight is provided. This new bond activation mode has led to the development of various catalytic reactions, mainly based on alcohols and amines, and to a stepwise approach to thermal H 2 and light-induced O 2 liberation from water.

Chelating Assistance of P–C and P–H Bond Activation at Palladium and Nickel: Straightforward Access to Diverse Pincer Complexes from a Diphosphine–Phosphine Oxide

2013 ◽  
Vol 32 (4) ◽  
pp. 1121-1128 ◽  
Author(s):  
Eric J. Derrah ◽  
Carmen Martin ◽  
Sonia Mallet-Ladeira ◽  
Karinne Miqueu ◽  
Ghenwa Bouhadir ◽  
...  
Keyword(s):  
Phosphine Oxide ◽  
Bond Activation ◽  
Pincer Complexes

Original palladium pincer complexes deriving from 1,3-bis(thiophosphinoyl)indene proligands: Csp3–H versus Csp2–H bond activation

2011 ◽  
Vol 40 (35) ◽  
pp. 8912 ◽  
Author(s):  
Noel Nebra ◽  
Jérôme Lisena ◽  
Nathalie Saffon ◽  
Laurent Maron ◽  
Blanca Martin-Vaca ◽  
...  
Keyword(s):  
Bond Activation ◽  
Pincer Complexes

Selective C−C vs C−H Bond Activation by Rhodium(I) PCP Pincer Complexes. A Computational Study

2000 ◽  
Vol 122 (29) ◽  
pp. 7095-7104 ◽  
Author(s):  
Andreas Sundermann ◽  
Olivier Uzan ◽  
David Milstein ◽  
Jan M. L. Martin
Keyword(s):  
Bond Activation ◽  
Computational Study ◽  
Pincer Complexes ◽  
Pcp Pincer

Iron Borohydride Pincer Complexes for the Efficient Hydrogenation of Ketones under Mild, Base-Free Conditions: Synthesis and Mechanistic Insight

2012 ◽  
Vol 18 (23) ◽  
pp. 7196-7209 ◽  
Author(s):  
Robert Langer ◽  
Mark A. Iron ◽  
Leonid Konstantinovski ◽  
Yael Diskin-Posner ◽  
Gregory Leitus ◽  
...  
Keyword(s):  
Pincer Complexes ◽  
Mechanistic Insight
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