Metalations With Organosodium Compounds

1957 ◽  
Vol 57 (5) ◽  
pp. 867-894 ◽  
Author(s):  
Robert A. Benkeser ◽  
Donald J. Foster ◽  
Dale M. Sauve ◽  
John F. Nobis
Keyword(s):  
Organosodium Compounds

Structures and stabilities of α-hetero-substituted organolithium and organosodium compounds. Energetic unimportance of d-orbital effects

1984 ◽  
Vol 106 (22) ◽  
pp. 6467-6475 ◽  
Author(s):  
Paul V. R. Schleyer ◽  
Timothy Clark ◽  
Alexander J. Kos ◽  
Gunther W. Spitznagel ◽  
Cornelia Rohde ◽  
...  
Keyword(s):  
Organosodium Compounds

Organosodium compounds of N-substituted benzimidazoles

1971 ◽  
Vol 7 (9) ◽  
pp. 1163-1167 ◽  
Author(s):  
B. A. Tertov ◽  
A. V. Koblik ◽  
N. I. Avdyunina
Keyword(s):  
Organosodium Compounds

13C and23Na solid-state NMR spectra of organosodium compounds

2003 ◽  
Vol 41 (5) ◽  
pp. 373-378 ◽  
Author(s):  
Steffen Jost ◽  
Harald Günther
Keyword(s):  
Solid State ◽  
Solid State Nmr ◽  
Nmr Spectra ◽  
Organosodium Compounds

Condensations by Sodium. XX. Preparation and Properties of Organosodium Compounds Derived from Butyl and Propyl Chlorides1

1941 ◽  
Vol 63 (2) ◽  
pp. 327-330 ◽  
Author(s):  
Avery A. Morton ◽  
Graham M. Richardson ◽  
A. Thomas Hallowell
Keyword(s):  
Organosodium Compounds

Alfin Catalysts and the Polymerization of Butadiene

1951 ◽  
Vol 24 (1) ◽  
pp. 35-53
Author(s):  
Avery A. Morton
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Catalytic Polymerization ◽  
Sodium Salts ◽  
Multiple Reactions ◽  
Secondary Reactions ◽  
History Of ◽  
Organosodium Compounds

Abstract Alfin catalysts are special combinations of sodium salts which cause the rapid catalytic polymerization of butadiene to polymers of unusually high molecular weight. These polymerizations show characteristics which are common to all reactions of organosodium compounds, namely, the tendency to undergo multiple reactions. The reagents are also insoluble aggregates of ions whose behavior is affected by the ions in the aggregate. The history of the discovery is reviewed. The catalytic polymerization shows no property in common with the conventional sodium process for polymerizing butadiene. The present problems center in the elimination of secondary reactions that are known to occur. The theory by which all the reactions occur, including polymerizations induced by organosodium compounds, is discussed. Progress toward the practical use of the alfin polymers is being made.

Polymerization of butadiene in presence of modified organosodium compounds

1988 ◽  
Vol 30 (8) ◽  
pp. 1716-1721 ◽  
Author(s):  
Yu.Ya. Svirkin ◽  
Yu.B. Podol'nyi ◽  
R.V. Rabovskaya ◽  
V.A. Krol' ◽  
V.N. Ryzhova ◽  
...  
Keyword(s):  
Organosodium Compounds

ChemInform Abstract: SYNTHESIS AND STRUCTURE OF CRYSTALLINE ORGANOSODIUM COMPOUNDS FROM PHOSPHORUS YLIDES

1980 ◽  
Vol 11 (24) ◽  
Author(s):  
H. SCHMIDBAUR ◽  
U. DESCHLER ◽  
B. ZIMMER-GASSER ◽  
D. NEUGEBAUER ◽  
U. SCHUBERT
Keyword(s):  
Phosphorus Ylides ◽  
Organosodium Compounds
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