Free Radical Functionalization of Organic Compounds Catalyzed byN-Hydroxyphthalimide†

2007 ◽  
Vol 107 (9) ◽  
pp. 3800-3842 ◽  
Author(s):  
Francesco Recupero ◽  
Carlo Punta
Keyword(s):  
Free Radical ◽  
Organic Compounds ◽  
Radical Functionalization

ChemInform Abstract: Free-Radical Bromination of Selected Organic Compounds in Water.

ChemInform ◽  
2010 ◽  
Vol 28 (23) ◽  
pp. no-no
Author(s):  
H. SHAW ◽  
H. D. PERLMUTTER ◽  
C. GU ◽  
S. D. ARCO ◽  
T. O. QUIBUYEN
Keyword(s):  
Free Radical ◽  
Organic Compounds ◽  
Radical Bromination

The slow combustion of aluminium trimethyl

1965 ◽  
Vol 288 (1412) ◽  
pp. 123-132 ◽  
Keyword(s):  
Free Radical ◽  
Organic Compounds ◽  
Initial Rate ◽  
Inert Gases ◽  
Spontaneous Ignition ◽  
Chain Mechanism ◽  
Radical Chain ◽  
Ambient Temperatures ◽  
Slow Combustion ◽  
Rate Of Reaction

Kinetic and analytical studies of the gaseous oxidation of aluminium trimethyl at ambient temperatures and at pressures well below those required for spontaneous ignition have shown that, in contrast to the oxidations of less electron-deficient metal alkyls, no peroxides can be detected and no volatile oxygenated organic compounds are formed. Methane, traces of hydrogen and a solid methoxymethyl compound of aluminium are the only products. The initial rate of reaction is approximately proportional to the first power of the alkyl pressure and to the square of the oxygen pressure; it is little influenced by temperature or by inert gases but is lowered by an increase in surface. The observed kinetic and analytical results can be accounted for in terms of a free radical chain mechanism in which termination takes place predominantly at the walls.

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