Mechanism of Electron Transfer in Heme Proteins and Models:  The NMR Approach

2005 ◽  
Vol 105 (6) ◽  
pp. 2627-2646 ◽  
Author(s):  
Gérard Simonneaux ◽  
Arnaud Bondon
Keyword(s):  
Electron Transfer ◽  
Heme Proteins

Electron transfer between heme proteins and ceruloplasmin

1989 ◽  
Vol 159 (2) ◽  
pp. 482-487
Author(s):  
James M. Caffrey ◽  
Robert E. Shinn ◽  
Earl Frieden
Keyword(s):  
Electron Transfer ◽  
Heme Proteins

Direct electrochemistry of redox proteins or enzymes at various film electrodes and their possible applications in monitoring some pollutants

2001 ◽  
Vol 73 (12) ◽  
pp. 1979-1991 ◽  
Author(s):  
Naifei Hu
Keyword(s):  
Electron Transfer ◽  
Heme Proteins ◽  
Biological Membrane ◽  
Direct Electrochemistry ◽  
Composite Films ◽  
Amphiphilic Polymers ◽  
Protein Films ◽  
Electron Transfer Process ◽  
Redox Proteins ◽  
Solid Electrodes

Water-insoluble films modified on the surface of solid electrodes may provide a unique microenvironment for electron transfer of some redox proteins or enzymes. The film materials can be two-tail surfactants, or composites of polyion-surfactant or clay-surfactant. Both surfactant and composite films cast on surface of electrodes are self-assembled into an ordered multibilayer structure, which is very similar to the bilayer structure of biological membrane. Amphiphilic polymers can also be used for making films. Incorporated heme proteins such as myoglobin (Mb), hemoglobin (Hb), or horseradish peroxidase (HRP) in these films demonstrated reversible voltammetry. Studies of direct electrochemistry of these proteins in various films by our group are reviewed in this paper. The protein films may provide a good model for study of electron transfer process in biological systems. The electrocatalytic properties of the protein films may also be applied to monitor some pollutant substrates.

Electron Transfer Mechanisms in Heme Proteins

1989 ◽  
Vol 26 (2-3) ◽  
pp. 433-443 ◽  
Author(s):  
Michael A. Cusanovich ◽  
James T. Hazzard ◽  
Terrance E. Meyer ◽  
Gordon Tollin
Keyword(s):  
Electron Transfer ◽  
Heme Proteins ◽  
Transfer Mechanisms
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