Conducting Organic Radical Cation Salts with Organic and Organometallic Anions

2004 ◽  
Vol 104 (11) ◽  
pp. 5203-5242 ◽  
Author(s):  
Urs Geiser ◽  
John A. Schlueter
Keyword(s):  
Radical Cation ◽  
Organic Radical ◽  
Radical Cation Salts

scholarly journals New Radical Cation Salts Based on BDH-TTP Donor: Two Stable Molecular Metals with a Magnetic [ReF6]2− Anion and a Semiconductor with a [ReO4]− Anion

2021 ◽  
Vol 7 (4) ◽  
pp. 54
Author(s):  
Nataliya D. Kushch ◽  
Gennady V. Shilov ◽  
Lev I. Buravov ◽  
Eduard B. Yagubskii ◽  
Vladimir N. Zverev ◽  
...  
Keyword(s):  
Radical Cation ◽  
Low Temperatures ◽  
Ac Susceptibility ◽  
Slow Relaxation ◽  
Organic Radical ◽  
Inorganic Anion ◽  
Distinctive Features ◽  
Metallic Character ◽  
Radical Cation Salts ◽  
Partial Population

Three radical cation salts of BDH-TTP with the paramagnetic [ReF6]2− and diamagnetic [ReO4]− anions have been synthesized: κ-(BDH-TTP)4ReF6 (1), κ-(BDH-TTP)4ReF6·4.8H2O (2) and pseudo-κ″-(BDH-TTP)3(ReO4)2 (3). The crystal and band structures, as well as the conducting properties of the salts, have been studied. The structures of the three salts are layered and characterized by alternating κ-(1, 2) and κ″-(3) type organic radical cation layers with inorganic anion sheets. Similar to other κ-salts, the conducting layers in the crystals of 1 and 2 are formed by BDH-TTP dimers. The partial population of positions of Re atoms and disorder in the anionic layers of 1–3 are their distinctive features. Compounds 1 and 2 show the metallic character of conductivity down to low temperatures, while 3 is a semiconductor. The ac susceptibility of crystals 1 was investigated in order to test the possible slow relaxation of magnetization associated with the [ReF6]2− anion.

A study of the thermal expansion of isostructural organic radical cation salts κ-(BEDT-TTF)2Cu[N(CN)2]X (XBr, Cl, I)

1995 ◽  
Vol 70 (1-3) ◽  
pp. 951-952 ◽  
Author(s):  
M. Kund ◽  
H. Müller ◽  
N.D. Kushch ◽  
K. Andres ◽  
G. Saito
Keyword(s):  
Thermal Expansion ◽  
Radical Cation ◽  
Organic Radical ◽  
Radical Cation Salts

Magnetic and photoluminescent properties of three new organic radical cation salts

2015 ◽  
Vol 200 ◽  
pp. 48-53
Author(s):  
Chen Shen ◽  
Yiman Zhang ◽  
Guoping Yong
Keyword(s):  
Radical Cation ◽  
Organic Radical ◽  
Radical Cation Salts
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