Transition-metal-mediated phosphorus-carbon bond cleavage and its relevance to homogeneous catalyst deactivation

1985 ◽  
Vol 85 (3) ◽  
pp. 171-185 ◽  
Author(s):  
Philip E. Garrou
Keyword(s):  
Transition Metal ◽  
Catalyst Deactivation ◽  
Bond Cleavage ◽  
Homogeneous Catalyst ◽  
Carbon Bond

Cobalt hydroformylation catalyst supported on a phosphinated polyphosphazene. Identification of phosphorus-carbon bond cleavage as mode of catalyst deactivation

1986 ◽  
Vol 5 (3) ◽  
pp. 460-466 ◽  
Author(s):  
Robert A. Dubois ◽  
Philip E. Garrou ◽  
Karen D. Lavin ◽  
Harry R. Allcock
Keyword(s):  
Catalyst Deactivation ◽  
Bond Cleavage ◽  
Carbon Bond

Aerobic Carbon–Carbon Bond Cleavage of Alkenes to Aldehydes Catalyzed by First-Row Transition-Metal-Substituted Polyoxometalates in the Presence of Nitrogen Dioxide

2014 ◽  
Vol 136 (31) ◽  
pp. 10941-10948 ◽  
Author(s):  
Amir Rubinstein ◽  
Pablo Jiménez-Lozanao ◽  
Jorge J. Carbó ◽  
Josep M. Poblet ◽  
Ronny Neumann
Keyword(s):  
Transition Metal ◽  
Nitrogen Dioxide ◽  
Bond Cleavage ◽  
Carbon Bond ◽  
Carbon Carbon Bond

Ambient and aerobic carbon–carbon bond cleavage toward α-ketoester synthesis by transition-metal-free photocatalysis

2019 ◽  
Vol 21 (12) ◽  
pp. 3436-3441 ◽  
Author(s):  
Qing Yu ◽  
Yating Zhang ◽  
Jie-Ping Wan
Keyword(s):  
Double Bond ◽  
Transition Metal ◽  
Rose Bengal ◽  
Bond Cleavage ◽  
Product Diversity ◽  
Carbon Bond ◽  
Metal Free ◽  
Carbon Carbon Bond ◽  
Green Led ◽  
Led Irradiation

With a low loading of Rose Bengal (1 mol%) and green LED irradiation, α-ketoesters are efficiently synthesized with excellent product diversity and selectivity via the ambient cleavage of the enaminone CC double bond.

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