Core/Shell Structured Noble Metal (Alloy)/Cadmium Selenide Nanocrystals

2009 ◽  
Vol 21 (14) ◽  
pp. 3039-3041 ◽  
Author(s):  
Zhi-Quan Tian ◽  
Zhi-Ling Zhang ◽  
Peng Jiang ◽  
Ming-Xi Zhang ◽  
Hai-Yan Xie ◽  
...  
2014 ◽  
Vol 2014 (26) ◽  
pp. 4254-4257 ◽  
Author(s):  
Pengyu Wang ◽  
Hiroko Tooriyama ◽  
Kazuya Yokoyama ◽  
Masataka Ohtani ◽  
Haruyasu Asahara ◽  
...  

2014 ◽  
Vol 87 (2) ◽  
pp. 43-49
Author(s):  
Takashi KANDA ◽  
Kanjiro TORIGOE ◽  
Hirobumi SHIBATA ◽  
Masahiko ABE ◽  
Hideki SAKAI

2021 ◽  
Author(s):  
Xiaoping Ma ◽  
Lili Deng ◽  
Manting Lu ◽  
Yi He ◽  
Shuai Zou ◽  
...  

Abstract Although researches on non-noble metal electrocatalysts have been made some progress recently, their performance in proton exchange membrane water electrolyzer (PEMWE) is still incomparable to that of noble-metal-based catalysts. Therefore, it is a more practical way to improve the utilization of precious metals in electrocatalysts for oxygen evolution reaction (OER) in the acidic medium. Herein, nanostructured IrCo@IrCoOx core-shell electrocatalysts composed of IrCo alloy core and IrCoOx shell were synthesized through a simple colloidally synthesis and calcination method. As expected, the hybrid IrCo-200 NPs with petal-like morphology show the best OER activities in acidic electrolytes. They deliver lower overpotential and better electrocatalytic kinetics than pristine IrCo alloy and commercial Ir/C, reaching a low overpotential (j = 10 mA/cm2) of 259 mV (vs. RHE) and a Tafel slope of 59 mV dec−1. The IrCo-200 NPs displayed robust durability with life time of about 55 h in acidic solution under a large current density of 50 mA/cm2. The enhanced electrocatalytic activity may be associated with the unique metal/amorphous metal oxide core-shell heterostructure, allowing the improved charge transferability. Moreover, the *OH-rich amorphous shell functions as the active site for OER and prevents the further dissolution of the metallic core and thus ensures high stability.


2019 ◽  
Vol 25 (20) ◽  
pp. 5113-5127 ◽  
Author(s):  
Jingjie Ge ◽  
Zhijun Li ◽  
Xun Hong ◽  
Yadong Li

2016 ◽  
Vol 8 (4) ◽  
pp. 423 ◽  
Author(s):  
AlanoodAhmed Aljohi ◽  
HananElkefafy Hassan ◽  
RakeshKumar Gupta

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