Amine-Rich Polyelectrolyte Multilayer Nanoreactors for in Situ Gold Nanoparticle Synthesis

2008 ◽  
Vol 20 (21) ◽  
pp. 6756-6763 ◽  
Author(s):  
Khek-Khiang Chia ◽  
Robert E. Cohen ◽  
Michael F. Rubner
Author(s):  
Jorge T. Dias ◽  
Gustav Svedberg ◽  
Mats Nystrand ◽  
Helene Andersson-Svahn ◽  
Jesper Gantelius

2017 ◽  
Vol 866 ◽  
pp. 398-401
Author(s):  
Woravith Chansuvarn ◽  
Apichat Imyim

In this report, we present a new method for visual and colorimetric detection of Hg (II) ion by using in-situ composited gold nanoparticle (GNP). GNP was formed in one step at room temperature, using NaBH4 as reducing agent incorporated with 2-[5-(2-aminoethylsulfanyl)-pentylsulfanyl]-ethylamine (5-AEPE) as a stabilizer. A 5-AEPE ligand displayed an effective stabilizer for preventing the aggregation of gold nanoparticle in the absence of Hg (II) ion, showing a rose-red color. On the other hand, in the presence of Hg (II) ion, reduced Hg (0) can also deposit on the surface of gold nanoparticle, resulting solution turn to purple and blue immediately. Based on naked eye detection optimization, 125 μM Au (III), 0.6 mM 5-AEPE, 0.8 mM NaBH4 and 0.1%(v/v) Triton X-100 was achieved. By measuring at a wavelength of 680 nm, absorbance values increased linearly as two levels of concentration of Hg (II) ion range of 0.125-2.5 μM (low) and 2.5-15 μM (high). This method offer advantage of simplicity, rapidity, cost effectiveness and no requirement of any sophisticated instruments. Moreover, this method has several potential advantages as optical sensor, especially no as-prepared gold nanoparticle synthesis and shorter observation time.


2017 ◽  
Vol 41 (24) ◽  
pp. 15079-15086 ◽  
Author(s):  
Abhinav Parashar ◽  
Prachi Sachin Kedare ◽  
Sruthi Ann Alex ◽  
N. Chandrasekaran ◽  
Amitava Mukherjee

Biocatalyzed gold nanoparticle synthesis for the in situ detection of horseradish peroxidase inhibitor (phenylhydrazine) has been demonstrated.


Author(s):  
Lidija Malic ◽  
Xuefeng Zhang ◽  
Keith Morton ◽  
Matthias Geissler ◽  
Jamal Daoud ◽  
...  

2018 ◽  
Vol 130 ◽  
pp. 81-89 ◽  
Author(s):  
Colin Specht ◽  
Robert W. Cattrall ◽  
Tony G. Spassov ◽  
Maya I. Spassova ◽  
Spas D. Kolev

Author(s):  
Phuoc Van Thai ◽  
Nobuo Saito ◽  
Tsubasa Nakamura ◽  
Kazumasa Takahashi ◽  
Toru Sasaki ◽  
...  

Abstract Plasma contacting with liquid provides many charged particles and reactive species into the liquid. The difficulty in controlling or selecting each specific species has significantly limited its applications in industry. Here, we present a study on using voltage polarity to regulate the type of charged particles absorbing from plasma into liquid. Detailed understanding of the processes at the plasma-liquid interface, electrolysis due to switching in voltage polarity was investigated via a visual pH observation, measuring the concentration of H2O2 and solvated electrons. The results indicated that changing in voltage polarity strongly affects the plasma properties, chemical properties, and electrolysis process in liquid, and further in the types of reducing species for gold nanoparticle synthesis. The results also showed using a suitable frequency could improve the efficiency of absorption of H2O2from plasma into the bulk liquid and the yield in the production of gold nanoparticles. The results provide a way to select desired species from plasma into the liquid for a distinct purpose and accompanying other properties in the system of plasma contacting with liquid.


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