Nano-Pt Modified Aligned Carbon Nanotube Arrays Are Efficient, Robust, High Surface Area Electrocatalysts

2008 ◽  
Vol 20 (8) ◽  
pp. 2603-2605 ◽  
Author(s):  
Yong Liu ◽  
Jun Chen ◽  
Weimin Zhang ◽  
Zifeng Ma ◽  
Gerhard F. Swiegers ◽  
...  
Carbon ◽  
2011 ◽  
Vol 49 (15) ◽  
pp. 5090-5098 ◽  
Author(s):  
Kazufumi Kobashi ◽  
Hidekazu Nishino ◽  
Takeo Yamada ◽  
Don N. Futaba ◽  
Motoo Yumura ◽  
...  

2016 ◽  
Vol 4 (38) ◽  
pp. 14586-14594 ◽  
Author(s):  
Helena Matabosch Coromina ◽  
Beatrice Adeniran ◽  
Robert Mokaya ◽  
Darren A. Walsh

The energy/power density of EDLCs containing high surface area carbon nanotube-based electrodes bridges the performance gap between conventional EDLCs and batteries.


2016 ◽  
Vol 4 (15) ◽  
pp. 5385-5389 ◽  
Author(s):  
Martina De Marco ◽  
Foivos Markoulidis ◽  
Robert Menzel ◽  
Salem M. Bawaked ◽  
Mohamed Mokhtar ◽  
...  

Spontaneously-dissolved, negatively-charged SWCNTs were cross-linked using p-diiodobenzene to produce ultralight, high surface area cryogels with high conductivity, suitable for supercapacitors application.


Author(s):  
Sungwon S. Kim ◽  
Tom T. Huang ◽  
Timothy S. Fisher ◽  
Michael R. Ladisch

Outstanding transport characteristics and high surface-to-volume ratios are several advantages that carbon nanotubes possess that make them attractive candidates for protein immobilization matrices in biosensor applications. A further advantage of using carbon nanotubes is that their structure (e.g., diameter, length, density) can potentially be controlled during synthesis. In the present study, the effects of carbon nanotube structure on enzyme immobilization onto carbon nanotube arrays are investigated. Bovine serum albumin (BSA) serves as both a blocking agent for prevention of nonspecific adsorption and as a support for anchoring bioreceptors. BSA, a globular protein having a 4 to 6 nm characteristic dimension, is stably adsorbed through mechanisms that involve hydrophobic interactions between surfaces presented by the carbon nanotubes and the spacing between the nanotubes with the protein. Protein adsorption is confirmed by fluorescence microscopy of surfaces that have been exposed to fluourescein isothiocyanate (FITC) labeled BSA. The adsorption of biotinylated BSA can be used, through a sandwich immobilization scheme, to provide an anchor for streptavidin, which in turn has at least one other adsorption site that is specific for other biotinylated proteins such as glucose oxidase that would form a biorecognition or catalytic element in a functional biosensor. Correlation between carbon nanotube structure and protein adsorption at the nano-bio interface could eventually lead to growth conditions that yield carbon nanotubes for biosensor applications with optimal protein adsorption characteristics.


2014 ◽  
Vol 172 ◽  
pp. 81-103 ◽  
Author(s):  
Natasha Shirshova ◽  
Hui Qian ◽  
Matthieu Houllé ◽  
Joachim H. G. Steinke ◽  
Anthony R. J. Kucernak ◽  
...  

This paper addresses the challenge of producing multifunctional composites that can simultaneously carry mechanical loads whilst storing (and delivering) electrical energy. The embodiment is a structural supercapacitor built around laminated structural carbon fibre (CF) fabrics. Each cell consists of two modified structural CF fabric electrodes, separated by a structural glass fibre fabric or polymer membrane, infused with a multifunctional polymeric electrolyte. Rather than using conventional activated carbon fibres, structural carbon fibres were treated to produce a mechanically robust, high surface area material, using a variety of methods, including direct etching, carbon nanotube sizing, and carbon nanotubein situgrowth. One of the most promising approaches is to integrate a porous bicontinuous monolithic carbon aerogel (CAG) throughout the matrix. This nanostructured matrix both provides a dramatic increase in active surface area of the electrodes, and has the potential to address mechanical issues associated with matrix-dominated failures. The effect of the initial reaction mixture composition is assessed for both the CAG modified carbon fibre electrodes and resulting devices. A low temperature CAG modification of carbon fibres was evaluated using poly(3,4-ethylenedioxythiophene) (PEDOT) to enhance the electrochemical performance. For the multifunctional structural electrolyte, simple crosslinked gels have been replaced with bicontinuous structural epoxy–ionic liquid hybrids that offer a much better balance between the conflicting demands of rigidity and molecular motion. The formation of both aerogel precursors and the multifunctional electrolyte are described, including the influence of key components, and the defining characteristics of the products. Working structural supercapacitor composite prototypes have been produced and characterised electrochemically. The effect of introducing the necessary multifunctional resin on the mechanical properties has also been assessed. Larger scale demonstrators have been produced including a full size car boot/trunk lid.


2009 ◽  
Vol 19 (31) ◽  
pp. 5503 ◽  
Author(s):  
Marcus A. Worsley ◽  
Joshua D. Kuntz ◽  
Peter J. Pauzauskie ◽  
Octavio Cervantes ◽  
Joseph M. Zaug ◽  
...  

2010 ◽  
Vol 03 (02) ◽  
pp. 115-118
Author(s):  
SUNG SOO KIM ◽  
JIN HOE KIM ◽  
JEONG AH YOON ◽  
MINGSHI JIN ◽  
JUNG-NAM PARK ◽  
...  

Carbon nanotube (CNT) and mesoporous TiO 2 composite (CNT/meso- TiO 2) was synthesized by a nanocasting method using CNT-implanted mesoporous silica material as the template. The CNT was successfully incorporated within a mesoporous TiO 2 particle, and the CNT/meso- TiO 2 composite obtained exhibits a high surface area and well-established mesoporosity. Moreover, the composite material exhibits much lower electric resistance than those of mesoporous TiO 2 only and physical mixture of CNT and mesoporous TiO 2, which probably due to the large interface area and strong junction between the implanted CNT and TiO 2 framework in the composite.


2015 ◽  
Vol 7 (8) ◽  
pp. 4817-4825 ◽  
Author(s):  
Yuanyuan Yao ◽  
Cheng Ma ◽  
Jitong Wang ◽  
Wenming Qiao ◽  
Licheng Ling ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document