Triplet-Energy Control of Polycyclic Aromatic Hydrocarbons by BN Replacement: Development of Ambipolar Host Materials for Phosphorescent Organic Light-Emitting Diodes

2014 ◽  
Vol 26 (21) ◽  
pp. 6265-6271 ◽  
Author(s):  
Sigma Hashimoto ◽  
Toshiaki Ikuta ◽  
Kazushi Shiren ◽  
Soichiro Nakatsuka ◽  
Jingping Ni ◽  
...  
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
Light Emitting Diodes ◽  
Organic Light Emitting Diodes ◽  
Triplet Energy ◽  
Energy Control ◽  
Light Emitting ◽  
Organic Light ◽  
Host Materials ◽  
Polycyclic Aromatic

scholarly journals Phosphine Sulfide-Based Bipolar Host Materials for Blue Phosphorescent Organic Light-Emitting Diodes

Molecules ◽  
2021 ◽  
Vol 26 (13) ◽  
pp. 4079
Author(s):  
Gaozhan Xie ◽  
Jiangchao Wang ◽  
Yang Cao ◽  
Xudong Xue ◽  
Xiao Zhang ◽  
...  
Keyword(s):  
Power Efficiency ◽  
Light Emitting Diodes ◽  
Organic Light Emitting Diodes ◽  
Triplet Energy ◽  
One Pot ◽  
Light Emitting ◽  
Organic Light ◽  
Host Materials ◽  
Blue Phosphorescent ◽  
Phosphine Sulfide

Three phosphine sulfide-based bipolar host materials, viz CzPhPS, DCzPhPS, and TCzPhPS, were facilely prepared through a one-pot synthesis in excellent yields. The developed hosts exhibit superior thermal stabilities with the decomposition temperatures (Td) all exceeding 350 °C and the melting temperatures (Tm) over 200 °C. In addition, their triplet energy (ET) levels are estimated to be higher than 3.0 eV, illustrating that they are applicable to serve as hosts for blue phosphorescent organic light-emitting diodes (PhOLEDs). The maxima luminance, current efficiency (CE), power efficiency (PE), and external quantum efficiency (EQE) of 17223 cd m−2, 36.7 cd A−1, 37.5 lm W−1, and 17.5% are achieved for the blue PhOLEDs hosted by CzPhPS. The PhOLEDs based on DCzPhPS and TCzPhPS show inferior device performance than that of CzPhPS, which might be ascribed to the deteriorated charge transporting balance as the increased number of the constructed carbazole units in DCzPhPS and TCzPhPS molecules would enhance the hole-transporting ability of the devices to a large extent. Our study demonstrates that the bipolar hosts derived from phosphine sulfide have enormous potential applications in blue PhOLEDs, and the quantity of donors should be well controlled to exploit highly efficient phosphine sulfide-based hosts.

Molecular design and synthetic approach to C2,C3,C4-modified carbazoles: high triplet energy bipolar host materials for efficient blue phosphorescent organic light emitting diodes

2019 ◽  
Vol 55 (56) ◽  
pp. 8178-8181 ◽  
Author(s):  
Rajendra Kumar Konidena ◽  
Kyung Hyung Lee ◽  
Jun Yeob Lee
Keyword(s):  
Light Emitting Diodes ◽  
Molecular Design ◽  
Organic Light Emitting Diodes ◽  
Synthetic Approach ◽  
Triplet Energy ◽  
Light Emitting ◽  
Organic Light ◽  
Host Materials ◽  
Blue Phosphorescent

Herein, we report the first examples of the design of and synthetic approach to C3/C4 and C2/C3/C4-modified carbazole based high triplet energy bipolar host materials for blue phosphorescent organic light emitting diodes.

scholarly journals Phenanthro[9,10-d]triazole and imidazole derivatives: high triplet energy host materials for blue phosphorescent organic light emitting devices

2019 ◽  
Vol 6 (6) ◽  
pp. 1179-1186 ◽  
Author(s):  
Muazzam Idris ◽  
Caleb Coburn ◽  
Tyler Fleetham ◽  
JoAnna Milam-Guerrero ◽  
Peter I. Djurovich ◽  
...  
Keyword(s):  
Transport Properties ◽  
Light Emitting Diodes ◽  
Wide Bandgap ◽  
Organic Light Emitting Diodes ◽  
Triplet Energy ◽  
Light Emitting ◽  
Light Emitting Devices ◽  
Organic Light ◽  
Host Materials ◽  
Blue Phosphorescent

A class of wide bandgap host materials is introduced as an alternative to carbazole-based hosts to enhance the efficiency and transport properties of organic light emitting diodes (OLEDs).

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