Core/Shell Structured La- and Rh-Codoped SrTiO3 as a Hydrogen Evolution Photocatalyst in Z-Scheme Overall Water Splitting under Visible Light Irradiation

2014 ◽  
Vol 26 (14) ◽  
pp. 4144-4150 ◽  
Author(s):  
Qian Wang ◽  
Takashi Hisatomi ◽  
Su Su Khine Ma ◽  
Yanbo Li ◽  
Kazunari Domen
2020 ◽  
Vol 16 ◽  
Author(s):  
Yuxue Wei ◽  
Honglin Qin ◽  
Jinxin Deng ◽  
Xiaomeng Cheng ◽  
Mengdie Cai ◽  
...  

Introduction: Solar-driven photocatalytic hydrogen production from water splitting is one of the most promising solutions to satisfy the increasing demands of a rapidly developing society. CdS has emerged as a representative semiconductor photocatalyst due to its suitable band gap and band position. However, the poor stability and rapid charge recombination of CdS restrict its application for hydrogen production. The strategy of using a cocatalyst is typically recognized as an effective approach for improving the activity, stability, and selectivity of photocatalysts. In this review, recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation are summarized. In particular, the factors affecting the photocatalytic performance and new cocatalyst design, as well as the general classification of cocatalysts, are discussed, which includes a single cocatalyst containing noble-metal cocatalysts, non-noble metals, metal-complex cocatalysts, metal-free cocatalysts, and multi-cocatalysts. Finally, future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are described. Background: Photocatalytic hydrogen evolution from water splitting using photocatalyst semiconductors is one of the most promising solutions to satisfy the increasing demands of a rapidly developing society. CdS has emerged as a representative semiconductor photocatalyst due to its suitable band gap and band position. However, the poor stability and rapid charge recombination of CdS restrict its application for hydrogen production. The strategy of using a cocatalyst is typically recognized as an effective approach for improving the activity, stability, and selectivity of photocatalysts. Methods: This review summarizes the recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation. Results: Recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation are summarized. The factors affecting the photocatalytic performance and new cocatalyst design, as well as the general classification of cocatalysts, are discussed, which includes a single cocatalyst containing noble-metal cocatalysts, non-noble metals, metal-complex cocatalysts, metal-free cocatalysts, and multi-cocatalysts. Finally, future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are described. Conclusion: The state-of-the-art CdS for producing hydrogen from photocatalytic water splitting under visible light is discussed. The future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are also described.


Nanoscale ◽  
2021 ◽  
Author(s):  
Hu Liu ◽  
Mengqi Shen ◽  
Peng Zhou ◽  
Zhi Guo ◽  
Xinyang Liu ◽  
...  

Developing an efficient single component photocatalyst for overall water splitting under visible-light irradiation is extremely challenging. Herein, we report a metal-free graphitic carbon nitride (g-CxN4)-based nanosheet photocatalyst (x = 3.2,...


2017 ◽  
Vol 4 (10) ◽  
pp. 1691-1696 ◽  
Author(s):  
Mumei Han ◽  
Huibo Wang ◽  
Siqi Zhao ◽  
Lulu Hu ◽  
Hui Huang ◽  
...  

10%CoO/g-C3N4 exhibits good photocatalytic performance under visible light irradiation without any sacrificial reagents.


2009 ◽  
Vol 34 (8) ◽  
pp. 3243-3249 ◽  
Author(s):  
Sang Won Bae ◽  
Sang Min Ji ◽  
Suk Joon Hong ◽  
Ji Wook Jang ◽  
Jae Sung Lee

Nanomaterials ◽  
2016 ◽  
Vol 6 (8) ◽  
pp. 138 ◽  
Author(s):  
Qiang Zhang ◽  
Zhenyin Hai ◽  
Aoqun Jian ◽  
Hongyan Xu ◽  
Chenyang Xue ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (29) ◽  
pp. 24361-24365 ◽  
Author(s):  
Weiming Wu ◽  
Xianyang Yue ◽  
Xiao-Yuan Wu ◽  
Can-Zhong Lu

Nanocrystalline Ni12P5 was synthesized by a simple hydrothermal method. It showed high catalytic activity (10 760 μmol h−1 g−1, TOF = 9.3 h−1) and good stability (15 h) for the hydrogen evolution from water under visible light irradiation.


2019 ◽  
Vol 7 (45) ◽  
pp. 25908-25914 ◽  
Author(s):  
Yunxiong Zeng ◽  
Yingchun Xia ◽  
Wenjia Song ◽  
Shenglian Luo

Solar-driven hydrogen evolution reaction (HER) via water splitting is an attractive technology to address the growing demand for clean fuels.


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