Microemulsion Liquid Crystal Templates for Highly Ordered Three-Dimensional Mesoporous Silica Monoliths with Controllable Mesopore Structures

2004 ◽  
Vol 16 (3) ◽  
pp. 384-400 ◽  
Author(s):  
S. A. El-Safty ◽  
T. Hanaoka
2007 ◽  
Vol 7 (11) ◽  
pp. 3876-3879 ◽  
Author(s):  
Chang-Kyo Shin ◽  
Rahul B. Kawthekar ◽  
Geon-Joong Kim

A route to synthesize porous materials with a bimodal macro/mesoscopic pore system has been investigated in this work. Polystyrene with sub-micrometer size was used as a template in the synthesis. The resulting mesoporous silica wall replicated inversely the morphology of polystyrene template and had highly ordered three-dimensional arrays of macro pores. Large and moldable meso/macro porous silica monoliths could be obtained in centimeter scale by using monodispersed polystyrene beads and MCM-41 sol solutions. These bimodal structured porous silicates have been used as supports for asymmetric kinetic resolution of racemic epoxides to synthesize optically pure epoxide.


2021 ◽  
Vol 125 (12) ◽  
pp. 3197-3207
Author(s):  
Johanna R. Bruckner ◽  
Jessica Bauhof ◽  
Jacqueline Gebhardt ◽  
Ann-Katrin Beurer ◽  
Yvonne Traa ◽  
...  

2004 ◽  
Author(s):  
Aneta Michalkiewicz ◽  
Malgorzata Kujawinska ◽  
Tomasz Kozacki ◽  
Xinghua Wang ◽  
Philip J. Bos

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