Polymer Films on Electrodes. 30. Electrochemistry and Scanning Electrochemical Microscopy Characterization of Benzimidazolebenzophenanthroline-Type Ladder (BBL) and Semiladder (BBB) Polymer Films

2001 ◽  
Vol 13 (9) ◽  
pp. 2824-2832 ◽  
Author(s):  
Maurizio Quinto ◽  
Samson A. Jenekhe ◽  
Allen J. Bard
Keyword(s):  
Polymer Films ◽  
Scanning Electrochemical Microscopy ◽  
Microscopy Characterization ◽  
Electrochemical Microscopy

The Alternating Current Scanning Electrochemical Microscopy Characterization of Diatom Cell Activity Affected by Paeonol

2014 ◽  
Vol 707 ◽  
pp. 113-116 ◽  
Author(s):  
Shou Huan Zhao ◽  
Ji Yong Zheng ◽  
Jing Ya Yang ◽  
Cun Guo Lin ◽  
Wei Wang ◽  
...  
Keyword(s):  
Cell Activity ◽  
Scanning Electrochemical Microscopy ◽  
Alternating Current ◽  
Electrochemical Activity ◽  
Chemical Stimulus ◽  
Cellular Activity ◽  
High Frequencies ◽  
Microscopy Characterization ◽  
Electrochemical Microscopy

The alternating current scanning electrochemical microscopy (AC-SECM) is an important method to characterize the electrochemical activity of living cells. In this paper, we apply AC-SECM to measure the electrochemical activity of diatom biofilm. We find that the diatom biofilm presents insulating effect to decrease the current, when the electrode is close to the biofilm. The alternating current impedance of diatom biofilm is overall smaller than that of the bare glass. To investigate the possible effect of chemical stimulus on cellular activity, the diatoms were immersed into paeonol solution (100 μg/mL), and AC-SECM imaging experiments were conducted when immersion time reached 20 h, 25 h and 35 h. The AC measurements performed at high frequencies show that phase angle decreases over time, which preliminarily indicates that the cellular activity of diatoms is affected by paeonol.

scholarly journals Scanning electrochemical microscopy characterization of sol-gel coatings applied on AA2024-T3 substrate for corrosion protection

2016 ◽  
Vol 111 ◽  
pp. 625-636 ◽  
Author(s):  
Diógenes J. Carbonell ◽  
Amaya García-Casas ◽  
Javier Izquierdo ◽  
Ricardo M. Souto ◽  
Juan Carlos Galván ◽  
...  
Keyword(s):  
Corrosion Protection ◽  
Sol Gel ◽  
Scanning Electrochemical Microscopy ◽  
Microscopy Characterization ◽  
Electrochemical Microscopy

scholarly journals Use of Amperometric and Potentiometric Probes in Scanning Electrochemical Microscopy for the Spatially-Resolved Monitoring of Severe Localized Corrosion Sites on Aluminum Alloy 2098-T351

Sensors ◽  
2021 ◽  
Vol 21 (4) ◽  
pp. 1132 ◽  
Author(s):  
Rejane M. P. da Silva ◽  
Javier Izquierdo ◽  
Mariana X. Milagre ◽  
Abenchara M. Betancor-Abreu ◽  
Isolda Costa ◽  
...  
Keyword(s):  
Scanning Electrochemical Microscopy ◽  
Oxygen Depletion ◽  
Localized Corrosion ◽  
Alloy Surface ◽  
Al Alloy ◽  
Spatially Resolved ◽  
Lower Oxygen ◽  
Local Ph ◽  
Electrochemical Microscopy

Amperometric and potentiometric probes were employed for the detection and characterization of reactive sites on the 2098-T351 Al-alloy (AA2098-T351) using scanning electrochemical microscopy (SECM). Firstly, the probe of concept was performed on a model Mg-Al galvanic pair system using SECM in the amperometric and potentiometric operation modes, in order to address the responsiveness of the probes for the characterization of this galvanic pair system. Next, these sensing probes were employed to characterize the 2098-T351 alloy surface immersed in a saline aqueous solution at ambient temperature. The distribution of reactive sites and the local pH changes associated with severe localized corrosion (SLC) on the alloy surface were imaged and subsequently studied. Higher hydrogen evolution, lower oxygen depletion and acidification occurred at the SLC sites developed on the 2098-T351 Al-alloy.

Characterization of Cathode/Electrolyte Interfacial Processes By Scanning Electrochemical Microscopy

2020 ◽  
Vol MA2020-02 (1) ◽  
pp. 159-159
Author(s):  
Di Huang ◽  
Chaiwat Engtrakul ◽  
Sanjini U. Nanayakkara ◽  
Hongmei Luo ◽  
Robert Tenent
Keyword(s):  
Scanning Electrochemical Microscopy ◽  
Interfacial Processes ◽  
Electrochemical Microscopy
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