Two-Dimensional Hexagonal Mesoporous Silica Thin Films Prepared from Block Copolymers:  Detailed Characterization and Formation Mechanism

2001 ◽  
Vol 13 (5) ◽  
pp. 1848-1856 ◽  
Author(s):  
D. Grosso ◽  
A. R. Balkenende ◽  
P. A. Albouy ◽  
A. Ayral ◽  
H. Amenitsch ◽  
...  
2009 ◽  
Vol 106 (3) ◽  
pp. 034910 ◽  
Author(s):  
Thomas Coquil ◽  
Erik K. Richman ◽  
Neal J. Hutchinson ◽  
Sarah H. Tolbert ◽  
Laurent Pilon

2004 ◽  
Vol 24 (6) ◽  
pp. 1969-1972 ◽  
Author(s):  
Andrea Bearzotti ◽  
Johnny Mio Bertolo ◽  
Plinio Innocenzi ◽  
Paolo Falcaro ◽  
Enrico Traversa

2003 ◽  
Vol 95 (1-3) ◽  
pp. 107-110 ◽  
Author(s):  
Andrea Bearzotti ◽  
Johnny Mio Bertolo ◽  
Plinio Innocenzi ◽  
Paolo Falcaro ◽  
Enrico Traversa

2005 ◽  
Vol 17 (8) ◽  
pp. 1035-1039 ◽  
Author(s):  
H. Fukumoto ◽  
S. Nagano ◽  
N. Kawatsuki ◽  
T. Seki

ACS Omega ◽  
2017 ◽  
Vol 2 (8) ◽  
pp. 4548-4555 ◽  
Author(s):  
Ane Escobar ◽  
Luis Yate ◽  
Marek Grzelczak ◽  
Heinz Amenitsch ◽  
Sergio E. Moya ◽  
...  

1996 ◽  
Vol 431 ◽  
Author(s):  
M. T. Anderson ◽  
J. E. Martin ◽  
J. G. Odinek ◽  
P. Newcomer

AbstractWe have synthesized periodic mesoporous silica thin films (PMSTF) from homogeneous solutions. To synthesize the films a thin layer of a pH = 7 micellar coating solution that contains TMOS is dip- or spin-coated onto silicon wafers, borosilicate glass, or quartz substrates. Ammonia gas is diffused into the solution and causes rapid hydrolysis and condensation of the TMOS and the formation of periodic mesoporous thin films within ∼10 seconds. The combination of homogeneous solutions and rapid product formation maximizes the concentration of desired product and provides a controlled, predictable microstructure. The films have been made continuous and crack-free by optimizing initial silica concentration and film thickness.


2009 ◽  
Vol 7 ◽  
pp. 141-144 ◽  
Author(s):  
Yu Horiuchi ◽  
Takashi Kamegawa ◽  
Kohsuke Mori ◽  
Hiromi Yamashita ◽  
Norikazu Nishiyama

Sign in / Sign up

Export Citation Format

Share Document