Structural Studies and Magnetic Properties of Polymeric Ladder-Type Compounds {Ln2[Ni(opba)]3}·S (Ln = Lanthanide Element; opba =o-Phenylenebis(oxamato), S = Solvent Molecules)

2000 ◽  
Vol 12 (10) ◽  
pp. 3073-3079 ◽  
Author(s):  
Myrtil L. Kahn ◽  
Pierre Lecante ◽  
Marc Verelst ◽  
Corine Mathonière ◽  
Olivier Kahn
Keyword(s):  
Magnetic Properties ◽  
Structural Studies ◽  
Lanthanide Element ◽  
Solvent Molecules

Synthesis, Characterisation and Structural Studies of [Zn(phen)3][Fe(CN)5(NO)]·2H2O·0.25MeOH and [(bipy)2(H2O)Zn(μ-NC)Fe(CN)4(NO)]·0.5H2O

2003 ◽  
Vol 58 (9) ◽  
pp. 916-921 ◽  
Author(s):  
Amitabha Datta ◽  
Samiran Mitra ◽  
Georgina Rosair
Keyword(s):  
Infrared Spectroscopy ◽  
Thermogravimetric Analysis ◽  
Octahedral Geometry ◽  
Distorted Octahedral Geometry ◽  
Structural Studies ◽  
Crystal Lattices ◽  
X Ray ◽  
X Ray Crystallography ◽  
Distorted Octahedral ◽  
Solvent Molecules

Two new bimetallic complexes [Zn(phen)3][Fe(CN)5(NO)] · 2 H2O · 0.25 MeOH, (1) and [(bipy)2(H2O)Zn(μ-NC)Fe(CN)4(NO)] · 0.5 H2O, (2), have been isolated (where phen = 1,10-phenanthroline and bipy = bipyridyl) and characterised by X-ray crystallography [as the 2 H2O · 0.25 CH3OH solvate for (1) and hemihydrate for (2)] infrared spectroscopy and thermogravimetric analysis. Substitution of phenanthroline for bipyridyl resulted in a cyano-bridged bimetallic species rather than two discrete mononuclear metal complexes. The bond angles of Fe-N-O were shown to be practically linear for both 1 [179.2(7)°] and 2 [178.3(3)°], and the Zn atoms have distorted octahedral geometry. The solvent molecules in both crystal lattices take part in forming hydrogen-bonded networks.

scholarly journals Синтез, структура и магнитные свойства многослойных наногетероструктур Fe|MgO|Cr|MgO|Fe

2021 ◽  
Vol 63 (9) ◽  
pp. 1306
Author(s):  
Е.М. Якунина ◽  
Е.А. Кравцов ◽  
Yu.N. Khaydukov ◽  
Н.О. Антропов ◽  
В.В. Проглядо
Keyword(s):  
Magnetic Properties ◽  
High Resolution ◽  
Exchange Interaction ◽  
Magnetic Moments ◽  
Ferromagnetic Material ◽  
Structural Studies ◽  
X Ray ◽  
Structural And Magnetic Properties ◽  
Metal Layers

Layered nanoheterostructures Fe | MgO | Cr | MgO | Fe is an artificial ferromagnetic material in which the exchange interaction of the magnetic moments of Fe layers through intermediate dielectric and metal layers can lead to magnetic configurations that are not realized in the well-studied Fe | MgO | Fe and Fe | Cr | Fe. In this work, we investigated the correlations of the structural and magnetic properties of layered nanoheterostructures Fe (10 nm) | MgO (1.5 nm) | Cr (t nm) | MgO (1.5 nm) | Fe (7 nm) (thickness t = 0.9 and 1.8 nm). Structural studies performed using X-ray diffractometry and high-resolution reflectometry confirmed the formation of a textured structure and revealed its well-defined layered character with sharp interlayer boundaries.

Syntheses, structures, and magnetic properties of three supramolecular isomeric Cu(ii) square grid networks: solvents effect on the ligand linkages

CrystEngComm ◽  
2020 ◽  
Vol 22 (8) ◽  
pp. 1321-1329 ◽  
Author(s):  
Gui-lei Liu ◽  
Jian-Biao Song ◽  
Qi-ming Qiu ◽  
Hui Li
Keyword(s):  
Magnetic Properties ◽  
Square Grid ◽  
Grid Networks ◽  
Solvent Molecules

Three supramolecular isomeric Cu(ii) networks with different metal fragments and ligand conformations were obtained by the adjustment of solvent molecules.

scholarly journals Synthesis, Structural Studies, and Magnetic Properties of a New Mixed-Valence Diphosphate: Zn2+5Fe3+2(P2O7)4

2019 ◽  
Vol 33 (4) ◽  
pp. 1007-1012 ◽  
Author(s):  
H. Lamsaf ◽  
E. H. Elghadraoui ◽  
R. Fausto ◽  
A. Oulmekki ◽  
B. F. O. Costa
Keyword(s):  
Magnetic Properties ◽  
Mixed Valence ◽  
Structural Studies

EFFECT OF NANOCRYSTALLIZATION ANNEALING ON MAGNETIC PROPERTIES AND MAGNETOIMPEDANCE OF CO-BASE RIBBONS

2012 ◽  
Vol 05 ◽  
pp. 841-846
Author(s):  
AMIR KEYVANARA ◽  
REZA GHOLAMIPOUR ◽  
SHAMSEDIN MIRDAMADI ◽  
FARZAD SHAHRI ◽  
HOSSEIN SEPEHRI AMIN
Keyword(s):  
Electron Microscopy ◽  
Heat Treatment ◽  
Magnetic Properties ◽  
Structural Studies ◽  
X Ray Diffraction ◽  
X Ray ◽  
Transmission Electron ◽  
Melt Spun ◽  
Melt Spun Ribbons ◽  
Nanocrystalline Phases

Melt spun ribbons of Co 64 Fe 4 Ni 2 B 19 Si 8 Cr 3 alloy have been prepared and the nanocrystallization process was carried out by the heat treatment of the as spun ribbons above the crystallization temperature. Structural studies of the samples have been performed by transmission electron microscopy and X-ray diffraction. Magnetic properties of the samples and magnetoimpedance measurements were investigated and it was revealed that magnetic properties and magnetoimpedance of the samples deteriorate by the formation of nanocrystalline phases.

Synthesis, reactivity, structural studies and magnetic properties of 4-amino-1,4-dihydro-3-methyl-1,2,4-triazole-5-thione copper complexes

1992 ◽  
pp. 3145 ◽  
Author(s):  
Marina Biagini Cingi ◽  
Francesco Bigoli ◽  
Maurizio Lanfranchi ◽  
Maria Angela Pellinghelli ◽  
Annabella Vera ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Copper Complexes ◽  
Structural Studies

Structural Studies of the Relaxed Amorphous Phase in the Fe81B14Nb5 Alloy

2013 ◽  
Vol 203-204 ◽  
pp. 380-385 ◽  
Author(s):  
Małgorzata Karolus
Keyword(s):  
Magnetic Properties ◽  
Amorphous Phase ◽  
Magnetic Permeability ◽  
Amorphous Alloys ◽  
Melt Spinning ◽  
Soft Magnetic Materials ◽  
Soft Magnetic Properties ◽  
Structural Studies ◽  
Soft Magnetic ◽  
Melt Spinning Technique

Amorphous alloys based on iron, obtained by melt spinning technique, are modern and very promising soft magnetic materials. The thermal annealing at temperatures closed to the crystallization temperature can cause an increase of magnetic permeability more than 10 times i.e. the so called enhancement of soft magnetic properties effect (ESMP). It is usually explained by formation of iron nanocrystallites in amorphous surroundings or by formation of the relaxed amorphous phase. Such a microstructure leads to averaging out of magnetic anisotropy and cause the ESMP.

Structural studies and magnetic properties of Fe/Ag superlattices

1990 ◽  
Vol 67 (9) ◽  
pp. 5388-5390 ◽  
Author(s):  
J. Q. Xiao ◽  
A. Gavrin ◽  
Gang Xiao ◽  
J. R. Childress ◽  
W. A. Bryden ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Structural Studies
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